• Bulletin of the Korean Chemical Society
• /
• 제34권10호
• /
• pp.2989-2994
• /
• 2013

The solvolysis rate constants of 3,4- (1) and 3,5-dimethoxybenzoyl (2) chlorides were measured in various pure and binary solvents at $25.0^{\circ}C$, and studied by application of the extended Grunwald-Winstein (G-W) equation, kinetic solvent isotope effect in methanolysis and activation parameters. The solvolysis of 1 was interpreted as the unimolecular pathway due to a predominant resonance effect from para-methoxy substituent like 4-methoxybenzoyl chloride (3), while that of 2 was evaluated as the dual mechanism, with unimolecular or bimolecular reaction pathway according to the character of solvent systems (high electrophilic/nucleophilic) chosen, caused by the inductive effect by two meta-methoxy substituents, no resonance one. In the solvolyses of 1 and 2 with two $-OCH_3$ groups, the resonance effect of para-methoxy substituent is more important to decide the mechanism than the inductive effect with other corresponding evidences.

• Journal of electromagnetic engineering and science
• /
• 제10권4호
• /
• pp.244-249
• /
• 2010

Recent development of magnetic resonance imaging (MRI) equipment enables interventional radiology (IVR) as diagnosis and treatment under MRI usage. In this paper, a new methodology for magnetic resonance (MR) scanner to apply not only diagnostic equipment but for treatment one is discussed. The temperature measuring procedure under MR is to measure phase shift of $T_1$, which is the longitudinal relaxation time of proton, for the position inside a sample material with the application of pulsed RF for heating inside the sample as artificial dielectrics. The result shows the possibility to apply MR as temperature measuring equipment and as a heating equipment for applying such as hyperthermia heating modality.

• 한국자기공명학회논문지
• /
• 제25권4호
• /
• pp.51-57
• /
• 2021

We study optical quantum transition line widths in relation to magnetic field dependence properties of the electrons confined in an infinite square well potential system between z = 0 and z = L_z in the z - direction. We consider two systems-one is subject to right circularly oscillating external fields and the other is subject to left circularly oscillatory external fields. Our results indicate that the line widths of right circularly oscillating external fields is larger than the line widths of left, while the opposite result is obtained for the line widths.

• Investigative Magnetic Resonance Imaging
• /
• 제24권2호
• /
• pp.67-75
• /
• 2020

When a patient takes an MRI scan, the patient has a risk of unexpected injuries due to the intensive electromagnetic (EM) field. Among the injuries, the tissue heating by the time-varying EM field is one of the main issues. Since an implanted artificial structure with a conductive material aggravates the heating effect, lots of studies have been conducted to investigate the effect around the implants. In this review article, a mechanism of RF heating around the implants and related studies are comprehensively investigated.

• 한국소음진동공학회논문집
• /
• 제17권9호
• /
• pp.847-852
• /
• 2007

Design aspects of a bearing casing system of a power plant are mainly focused on the strength and weight of itself to have a more stable system. Since the rotor speed often passes through the critical speed region when the operation begins, the relation between the rotating frequency of the rotor and natural frequency of the casing is very important for a prevention of resonance. However, harmonic components above the rotating frequency have often been overlooked the design for the resonance avoidance. In this paper, it is revealed that resonance vibration is generated when the natural frequency of a bearing casing is close to the one of harmonics of basic rotating frequency(1x), and as a consequence, sensing qualify of seismoprobes attached to the bearing casing structure can be seriously damaged. In order to reduce the resonance vibration, some stiffeners are added to the casing structures. Significant reduction in the magnitude of vibration corresponding to 2x harmonic of basic rotating frequency is observed from both FE analysis and experiment.

• Journal of Magnetics
• /
• 제22권2호
• /
• pp.188-195
• /
• 2017

The ferromagnetic resonance and other magnetic properties dependence on $Ni^{2+}/Fe^{3+}$ ratio and crystallite size were investigated for nano nickel ferrite ($NiFe_2O_4$). The crystallite size was controlled by controlling the nickel content in the starting material solution. The XRD and TEM were utilized to measure the crystallite size through Scherrer formula and particle size respectively. The most frequent particle sizes were lower than crystallite size, which ranged from 16.5 to 44.65 nm. The general behavior of M-H loop shapes and parameters showed superparamagnetic one. The saturation magnetization had a maximum value at $Ni^{2+}/Fe^{3+}$ molar ratio equal to 0.186. The FMR signals showed, generally, broad linewidths, where the maximum width and minimum resonance field were for the sample of the lowest crystalline size. Furthermore, FMR resonance field shows linear dependence on crystalline size. The fitting relation was estimated to express this linear dependency on the base of behavior coincidence between particle size and the inverse of saturation magnetization. The given interpretations to understand the intercept and the slope meanings of the fitted relation were based on Larmor equation, and inhomogeneous in the anisotropy constant.

• 대한치과보철학회지
• /
• 제41권3호
• /
• pp.271-287
• /
• 2003

Statement of problem: Resonance frequency analysis (RFA) has been increasingly served as a non-invasive and objective method for clinical monitoring of implant stability. Many clinical studies must be required for standardized baseline data using RFA. Purpose: This study was performed to evaluate RFA value changes in two stage surgery group and one stage surgery group in patients. Material and method: Forty-seven mandibles in consecutively implant installed patients were selected for this study and 141 fixtures were installed. Ninety-three fixtures were double threaded, machined surface design ($Br{\aa}anemark^{(R)}$ MK III, Nobel Biocare AB, Goteborg, Sweden) and 48 fixtures were root form, threaded, HA-coated surface one ($Replace^{TM}$, Steri-Oss/Nobel Biocare AB, USA). Among those, each 10 fixture was installed in one stage group patients. ISQ values were measured using $Osstell^{TM}$ (Integration Diagnostics Ltd. Sweden) during fixture installation, at healing abutment connection and in the loading period for two stage surgery group patients and during at each 4, 6, 8, 10, 12week and in the loading phase for one stage surgery group patients and evaluated the changes according to the time and fixture type. Results: In two stage surgery group, mean and SO of ISQ values of machined surface implants were $76.85{\pm}3.74,\;75.76{\pm}5.04,\;75.73{\pm}4.41$ and those of HA-coated surface implant were $75.05{\pm}6.23,\;77.58{\pm}5.23,\;78.32{\pm}4.29$ during fixtures installation, at healing abutment connection and in the loading period, respectively. In one-stage surgery group, the ISQ values of machined surface and HA-coated surface implants decreased until 4 or 6 week and maintained at plateau for 1-3 week and increased to the loading period. Conclusions: Machined and HA-coated surface implants showed minimal ISQ changes with time if they were installed at the sites showing at least intact cortical plate and good bone qualities. And HA-coated implants had a tendency to show somewhat increased ISQ values with time.

• Journal of Biosystems Engineering
• /
• 제28권3호
• /
• pp.253-260
• /
• 2003

In this study, the feasibility of magnetic resonance techniques for nondestructive internal quality evaluation of Korean red ginseng was examined. Relaxation time constants were measured using various grades of red ginsengs. Solid state magnetic resonance imaging technique was applied to image dried red ginsengs which have low moisture contents (about 13%). A 7 tesla magnetic resonance imaging system operating at a proton resonant frequency of 300 ㎒ was used for acquiring MR images of dried Korean red ginseng. The comparison test of cross cut digital images and magnetic resonance images of heaven grade, good grade with cavity inside, and good grade with white part inside red ginseng suggested the feasibility of the internal quality evaluation of Korean red ginsengs using MRI techniques. A good grade red ginseng included abnormal tissues such as cavities or white parts inside was observed by the signal intensity of MR image based on magnetic resonance properties of proton nucleus. Analysis on an one dimensional profile of acquired MR image of Korean red ginseng showed easy discrimination of normal and abnormal tissues. MR techniques suggested ways to detect internal defects of red ginsengs effectively.

• 한국소음진동공학회논문집
• /
• 제26권1호
• /
• pp.13-19
• /
• 2016

The flow-excited Helmholtz resonance phenomenon was investigated numerically using Reynolds averaged Navier-Stokes approach. The fundamental cause of the Helmholtz resonance phenomenon is known as shedding of a single discrete vortex from orifice edge that travels during one period of the oscillation. In this study, serrated deflector, which is biomimetic design of the owl's feather, is used to split a single vortex into small vortices. Rectangular deflector and serrated deflector are compared with numerical results of pressure and streamline inside the cavity. Consequently, the serration breaks the shedding period of vortex core and eliminates the resonance. Also, it changes the flow pattern in according to the location of different serration height. By making inflows and outflows occur simultaneously in spanwise direction in the cavity, the period of Helmholtz resonance disappears. Comparing between rectangular deflector and serrated deflector, the serrated deflector can deal with the Helmholtz resonance more effectively.

• 한국해양공학회지
• /
• 제16권2호
• /
• pp.27-31
• /
• 2002

The purpose of this study is to investigate the variation of resonance that is possible caused by construction of new port in a practical sea area between the existing port and the new one. The research of amplification that of the sea area was accomplished for the variation of resonance. In this study, long period wave that is observed continuously in the practical sea area was analyzed, and then secondary undulation was reproduced by numerical analysis. As a result of numerical analysis, the first mode resonant periods in the existing port is 640sec, and in the new one is 500sec. On the other hand, we know there is long period wave of 500sec from analyzation of field datas. Because that period this period is the resonant period in the new port. There is also the possibility of secondary undulation cause of resonant.