• Title/Summary/Keyword: Oil exchange

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A Study on the Actual Status of Heat Transfer oils in Industries for Process Safety Management (공정안전관리 사업장의 열매체유 사용실태에 관한 연구)

  • Lee, Keun Won;Lee, Joo Yeob
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.33-39
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    • 2014
  • Heat transfer oils are used in applications such as chemical plant heating systems, refinery heat exchange systems, certain gas processes, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistant to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignited easily when there is an ignition source. This study discusses the status of safety management through the actual status of the heat transfer oils to prevent fire and explosion accidents in industries for process safety management. The actual status of the heat transfer oils in process system of industries surveyed by a questionnaire developed. The results of this study can be used to help establishment of safety management to prevent fire and explosion accidents, such as the management of heat transfer oils, safe operation and maintenance in heat transfer oil processes.

Synthesis and Antiwear Properties of Ammonium Dithiocarbamate-based Ionic Liquid (I) (암모니움 디티오카바메이트계 이온성 액체의 합성 및 내마모성능 (I))

  • Baek, Seung-Yeob;Kim, Nam-Kyun;Shin, Jihoon;Chung, Keunwo;Kim, Young-Wun
    • Tribology and Lubricants
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    • v.30 no.6
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    • pp.323-329
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    • 2014
  • The friction-reducing properties of lubricants containing ionic liquids based on ammonium dithiocarbamate are studied. The ionic liquids are produced through the following two steps: the synthesis of sodium alkyl dithiocarbamates via the substitution reaction of dialkylamine and carbon disulfide and their subsequent conversion into ammonium dithiocarbamate-based ionic liquids through an ion-exchange reaction with a quaternary alkyl ammonium halide salt. The structures of the ionic liquids are characterized by NMR spectroscopy and Fourier transform infrared spectroscopy. The isolated yields of the ionic liquids, which are viscous and pale yellow, are approximately 92%. The Brookfield viscosities and pour points of the ionic liquids are determined. Further, their wear resistances are measured through the four-ball wear test and the Schwingung Reibung Ver-schleiss (oscillation, friction, wear) test. The wear scar diameter of the lubricants containing 1 wt of the quaternary alkyl ammonium dithiocarbamate-based ionic liquids (0.475-0.631 mm) is significantly lower than that of the base oil (0.825 mm), proving that the ammonium dithiocarbamate-based ionic liquids have good friction-reducing characteristics. However, these friction-reducing characteristics fade significantly after long-term storage, owing to the degradation of the ionic liquids.

Physicochemical Properties and Intestinal Bacterial Growth-Promoting Effect of Cell-Wall Polysaccharides from Cucumber Peel

  • Jun, Hyun-Il;Song, Geun-Seoup;Lee, Young-Tack;Kim, Young-Soo
    • Food Science and Biotechnology
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    • v.14 no.3
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    • pp.375-379
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    • 2005
  • Physicochemical properties, intestinal microbial growth, and inhibitory effects of alcohol-insoluble polysaccharide (AIP) extracted from cucumber peel were investigated. AIP was composed of 14.54% crude protein, 1.04% crude lipid, 13.74 % crude ash, 9.1% soluble dietary fiber, and 41.2% insoluble dietary fiber. AIP showed low bulk density (0.18 g/mL) and water-holding capacity (6.39 g/g), and high oil-holding capacity (3.96 g/g). Pectic substance fractions [water-soluble pectic substance (WSP), ethylenediaminetetraacetic acid-soluble pectic substance (ESP), and alkali-soluble pectic substances (ASP)] and hemicellulose fractions [1 M KOH-soluble hemicellulose (KHP1) and 4 M KOH-soluble hemicellulose (KHP4)] were obtained from sequential chemical fractionation of AIP. WSP showed higher total sugar contents than total uronic acid contents, whereas opposite results were observed in ESP and ASP. Molecular weight distributions of three pectic substance fractions were in order of ASP>ESP>WSP. Ion exchange chromatogram pattern of WSP was different from those of ESP and ASP. Major component of WSP was fraction eluted by 0.05 M ammonium acetate buffer, whereas that of ESP and ASP was fraction eluted by 0.2 M NaOH. WSP and ASP showed growth-promoting activities against Lactobacillus brevis, Bifidobacterium bifidum, and B. longum, whereas B. bifidum and B. longum for ESP. KHP1 and KHP4 fractions had significant growth-promoting activities against B. bifidum.

Development of an Optimal Model for Forecasting Overseas Construction Orders (해외건설수주액 예측을 위한 최적모형 개발)

  • Lee, Kwangwon;Jo, Woonghyeon
    • Korean Journal of Construction Engineering and Management
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    • v.21 no.4
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    • pp.30-37
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    • 2020
  • The purpose of this study is to compare and contrast the amount of overseas construction orders of South Korea and China by using various time series models that measure the overseas construction orders. Based on the analysis we propose better specification (model selection) with much more predictive power and prove the universality of the model developed by applying our findings with respect to the prediction power of overseas construction orders from other countries viewpoints (verification of generalization). The input variables include Dubai crude oil and exchange rates by country from 1981 to 2019. The VAR model is proposed based on the prediction power test, with respect to MAPE, RMSE, and MAE between the estimates and actual measurements from 2016 to 2019. We also conclude the results of the prediction of overseas construction orders time series of China are again consistent with the actual numbers. These analyses suggest the possibility of developing a comprehensive model that predict the potential construction orders of other countries.

Electrochemical Characterization of Animal Tissue-Immobilized Carbon Paste Biosensor Bound with Chloroprene Rubber (클로로프렌 고무로 결합된 동물조직 고정 탄소반죽 전극의 전기화학적 특성)

  • Rhyu, Keun-Bae
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.114-118
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    • 2011
  • Even though the carbon paste electrode bound with mineral oil is useful for research about the characteristics of enzymes, it remains far from practical uses because the lack of mechanical hardness limits its practical use. When the rubber liquefied in toluene was used as a binder of carbon powder in lab, it is confirmed that the mechanical robustness of the electrode is guaranteed. In order to confirm whether it shows quantitative electrochemical behaviors or not, its kinetic parameters, e.g. the symmetry factor (${\alpha}=0.28$), the exchange current density ($i_0=4.06{\mu}A/cm^2$), the capacity of the double layer ($C_d=2.11{\times}10^{-3}F$), the Michaelis constant ($K_M=2.45{\times}10^{-3}M$), and the time constant (${\tau}_B=0.077sec$) were investigated. Our experimental observations prove that the chloroprene rubber is a promising binder for the practical use of a carbon paste electrode.

Autoencoder factor augmented heterogeneous autoregressive model (오토인코더를 이용한 요인 강화 HAR 모형)

  • Park, Minsu;Baek, Changryong
    • The Korean Journal of Applied Statistics
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    • v.35 no.1
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    • pp.49-62
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    • 2022
  • Realized volatility is well known to have long memory, strong association with other global financial markets and interdependences among macroeconomic indices such as exchange rate, oil price and interest rates. This paper proposes autoencoder factor-augmented heterogeneous autoregressive (AE-FAHAR) model for realized volatility forecasting. AE-FAHAR incorporates long memory using HAR structure, and exogenous variables into few factors summarized by autoencoder. Autoencoder requires intensive calculation due to its nonlinear structure, however, it is more suitable to summarize complex, possibly nonstationary high-dimensional time series. Our AE-FAHAR model is shown to have smaller out-of-sample forecasting error in empirical analysis. We also discuss pre-training, ensemble in autoencoder to reduce computational cost and estimation errors.

Evaluation of interest rate-linked DLSs

  • Kim, Manduk;Song, Seongjoo
    • Communications for Statistical Applications and Methods
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    • v.29 no.1
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    • pp.85-101
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    • 2022
  • Derivative-linked securities (DLS) is a type of derivatives that offer an agreed return when the underlying asset price moves within a specified range by the maturity date. The underlying assets of DLS are diverse such as interest rates, exchange rates, crude oil, or gold. A German 10-year bond rate-linked DLS and a USD-GBP CMS rate-linked DLS have recently become a social issue in Korea due to a huge loss to investors. In this regard, this paper accounts for the payoff structure of these products and evaluates their prices and fair coupon rates as well as risk measures such as Value-at-Risk (VaR) and Tail-Value-at-Risk (TVaR). We would like to examine how risky these products were and whether or not their coupon rates were appropriate. We use Hull-White Model as the stochastic model for the underlying assets and Monte Carlo (MC) methods to obtain numerical results. The no-arbitrage prices of the German 10-year bond rate-linked DLS and the USD-GBP CMS rate-linked DLS at the center of the social issue turned out to be 0.9662% and 0.9355% of the original investment, respectively. Considering that Korea government bond rate for 2018 is about 2%, these values are quite low. The fair coupon rates that make the prices of DLS equal to the original investment are computed as 4.76% for the German 10-year bond rate-linked DLS and 7% for the USD-GBP CMS rate-linked DLS. Their actual coupon rates were 1.4% and 3.5%. The 95% VaR and TVaR of the loss for German 10-year bond rate-linked DLS are 37.30% and 64.45%, and those of the loss for USD-GBP CMS rate-linked DLS are 73.98% and 87.43% of the initial investment. Summing up the numerical results obtained, we could see that the DLS products of our interest were indeed quite unfavorable to individual investors.

Development of Eco-Efficiency Indicators for Yeosu Industrial Park (여수산업단지의 생태효율성지표 개발에 관한 연구)

  • Kim, Jung-In;Yun, Chang-Han;Yoon, Hyung-Sun
    • Clean Technology
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    • v.16 no.3
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    • pp.229-237
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    • 2010
  • The industrial ecology indicators(IEI) for Yeosu Industrial Park were developed using eco-efficiency indicator(EEI). The key factors for the creation of IEI were two parts. One part is the value of the products which is selected as the total production value, the amount of ethylene production, the amount of light oil production instead of the total sales volume for Yeosu Industrial Park, since the currency exchange and the price of raw materials varied every year. The other part is the environmental burden. The electric consumption, the industrial water consumption, and the amount of discharged waste water are all officially opened to the public, were used in the calculation. Based on the value for the year of 2004, the IEI value for 2006 became worse to 0.954, but, was expected to be 1.153, a 15% improvement, for 2015 if the current EIP project is successfully performed.

Impact of Environmentally-friendly Organic Agro-Materials on Chemical Properties of Remediated Soils (친환경 유기농자재 처리에 따른 정화토양의 개선 효과)

  • Kim, Dong-Jin;Ahn, Byung-Koo;Lee, Jin-Ho
    • Korean Journal of Organic Agriculture
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    • v.21 no.4
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    • pp.753-767
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    • 2013
  • Soil contamination has continuously increased worldwide, thus the remediation for the contaminated soils has risen steadily. However, the consideration of ecological safety for the remediated soils and their agricultural uses has been very limited. Therefore, this study was to investigate the influences of selected environmentally-friendly agricultural materials, organic by-product fertilizer (OF), charcoal (CC), and biochar (BC), as soil conditioners for improving poor chemical properties of fuel-oil removed soil by land farming technique. Two different remediated soils, remediated soil A (RSA) and remediated soil B (RSB), were selected. Soil texture of both RSA and RSB was sandy loam. The chemical properties of RSA and RSB were as follows: soil pHs of 8.5 and 8.7, soil organic matter contents of 7.4 and 5.5g $kg^{-1}$, total nitrogen contents of 0.26 and 0.10g $kg^{-1}$, available phosphorus concentrations of 7.2 and 4.4mg $kg^{-1}$, and exchangeable calcium concentrations of 14.8 and $11.7cmol_c$ $kg^{-1}$, respectively. Results of the properties were not reached for the optimal values for cultivating crops that were recommended by National Academy of Agricultural Science at Rural Development Administration in Korea. However, after applying OF, CC, and BC, the chemical properties of soils were selectively improved, which were that soil organic matter content and available phosphorus concentration increased, whereas the soil pH were not changed. In particular, the chemical properties were positively changed more with the application of 5.0% biochar. Thus, continuous management of the remediated soils with applying the eco-friendly agricultural materials can improve the quality of reme-diated soils.

Design and Implementation of a Power-Saving Management System using Intelligent Scheduler based on RFID/USN Technology (RFID/USN 기술 기반의 지능형 스케줄러를 이용한 절전관리 시스템 설계 및 구현)

  • Jeong, Kyu-Seuck;Choi, Sung-Chul;Jeong, Woo-Jeong;Kim, Tae-Ho;Kim, Jong-Heon;Seo, Dong-Min;Park, Yong-Hun;Yoo, Jae-Soo
    • The Journal of the Korea Contents Association
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    • v.9 no.12
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    • pp.64-76
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    • 2009
  • Recently, the ubiquitous environment and the practical technology associated with it become more popular topic along with the rapid development of wireless technologies. The necessity of the automated system based on the ubiquitous environment has been increasing when the concept of the ubiquitous is integrated into the fields of existing IT. Also, the necessity of formulating a power-saving plan on large buildings and public institutions is gathering strength because of a raise in exchange rates and high oil prices. In this paper, to efficiently manage the power consumption of the electronic machine such as electric lights, electric heaters, and air conditioners in a building, power-saving manage- ment system using RFID/USN technologies is proposed. Proposed system controls the electric machine and monitor it's condition by RFID and collects the real time information about the surrounding and the power consumption of the electric machine by USN. Especially, proposed system analyzes the real time information and supports the intelligent scheduler with the best power-saving. Finally, this paper shows the difference between proposed system and existing system and establishes thereality of our system through experiments in variety environments.