• Title/Summary/Keyword: Off-gas

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W 도핑된 ZnO 박막을 이용한 저항 변화 메모리 특성 연구

  • Park, So-Yeon;Song, Min-Yeong;Hong, Seok-Man;Kim, Hui-Dong;An, Ho-Myeong;Kim, Tae-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.410-410
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    • 2013
  • Next-generation nonvolatile memory (NVM) has attracted increasing attention about emerging NVMs such as ferroelectric random access memory, phase-change random access memory, magnetic random access memory and resistance random access memory (RRAM). Previous studies have demonstrated that RRAM is promising because of its excellent properties, including simple structure, high speed and high density integration. Many research groups have reported a lot of metal oxides as resistive materials like TiO2, NiO, SrTiO3 and ZnO [1]. Among them, the ZnO-based film is one of the most promising materials for RRAM because of its good switching characteristics, reliability and high transparency [2]. However, in many studies about ZnO-based RRAMs, there was a problem to get lower current level for reducing the operating power dissipation and improving the device reliability such an endurance and an retention time of memory devices. Thus in this paper, we investigated that highly reproducible bipolar resistive switching characteristics of W doped ZnO RRAM device and it showed low resistive switching current level and large ON/OFF ratio. This may be caused by the interdiffusion of the W atoms in the ZnO film, whch serves as dopants, and leakage current would rise resulting in the lowering of current level [3]. In this work, a ZnO film and W doped ZnO film were fabricated on a Si substrate using RF magnetron sputtering from ZnO and W targets at room temperature with Ar gas ambient, and compared their current levels. Compared with the conventional ZnO-based RRAM, the W doped ZnO ReRAM device shows the reduction of reset current from ~$10^{-6}$ A to ~$10^{-9}$ A and large ON/OFF ratio of ~$10^3$ along with self-rectifying characteristic as shown in Fig. 1. In addition, we observed good endurance of $10^3$ times and retention time of $10^4$ s in the W doped ZnO ReRAM device. With this advantageous characteristics, W doped ZnO thin film device is a promising candidates for CMOS compatible and high-density RRAM devices.

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$\textrm{NO}_2$ Absorption and Physiological Response of Lettuce in a Semi-closed Plant Production System (부분 밀폐형 식물생산시스템에서 상추의 $\textrm{NO}_2$ 흡수 및 생육반응)

  • Jung Eek Son;Jong Seok Park
    • Journal of Bio-Environment Control
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    • v.10 no.4
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    • pp.207-212
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    • 2001
  • The environmental characteristics, absorption rate of NO$_2$, physiological response, and quality of lettuces were examined in a semi-closed plant production system consisted of human and plant modules. Leaf lettuces were transplanted to 10-cm diameter pots at 4-to 5-leaf stage, and grown in a gas-fumigated plant module. Air containing NO$_2$was circulated 10 min-ON/ 20 min-OFF between the human and plant modules by a diaphragm. At 0.13, 0.30, and 0.45 $\mu$mol.mol$^{-1}$ NO$_2$, NO$_2$ decrements in the chamber during the 10 min were 0.040, 0.109, and 0.149 $\mu$mol.mol$^{-1}$ , respectively. The NO$_2$absorption rate of the plants was estimated to be 0.078 $\mu$mol.mol$^{-1}$ .m$^{-2}$ .min$^{-1}$ at 0.45 $\mu$mol.mol$^{-1}$ NO$_2$ was less than that of the control plant at 4th and 5th days, whereas the respiration rate was the same. The lettuce grown at 0.45 $\mu$mol.mol$^{-1}$ NO$_2$ had similar leaf length, leaf area, dry and fresh weights, and quality to that grown without NO$_2$.

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Flavor Components in Dried Fruit of the Chinese Matrimony Vine during Storage (저장 기간이 짧은 건조 구기자와 오래된 건조 구기자의 휘발성 성분)

  • Choi, Sung-Hee
    • Journal of Life Science
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    • v.24 no.12
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    • pp.1325-1329
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    • 2014
  • Gugija (Lycii chinese Miller) is traditionally consumed as a Chinese medicinal material in food, tea, or alcoholic beverages. Gugija has beneficial healthy components, but it produces an off-flavor during storage. This study compared the flavor components of fresh-dried Gugija and stale-dried Gugija. The flavor compounds in one fresh sample (sample 1) and one stale sample (sample 2) were extracted by the simultaneous distillation and extraction method. The concentrated aroma extracts were analyzed and identified by gas chromatography-mass spectrometry. Forty-five compounds, including 17 aldehydes, 8 alcohols, 6 terpene compounds, 4 esters, 3 ketones, and 3 pyrazines, were isolated in sample 1. Thirty-four compounds, including 12 aldehydes, 3 alcohols, 5 terpene compounds, 2 esters, 3 ketones, 3 pyrazines, and 1 acid, were isolated in sample 2. The main aroma components of sample 1 were 2-methyl butanal, 2-methyl propanol having sweet odor, and hexanal, (Z)-3-hexenol having grass odor, and phenyl acetaldehyde, benzyl alcohol having floral odor, and alkyl pyrazines having nutty odor. These compounds were decreased in sample 2, and several compounds containing isovaleric acid, which has a disagreeable, rancid-cheese odor were found newley.

Applications of Isotope Ratio Infrared Spectroscopy (IRIS) to Analysis of Stable Isotopic Compositions of Liquid Water (동위원소비 적외선 분광법(IRIS)을 이용한 물 안정동위원소 분석)

  • Jung, Youn-Young;Koh, Dong-Chan;Lee, Jeonghoon;Ko, Kyung-Seok
    • Economic and Environmental Geology
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    • v.46 no.6
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    • pp.495-508
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    • 2013
  • Recently, stable isotopes (${\delta}^{18}O$ and ${\delta}D$) of water are increasingly analyzed using laser-based technologies. These methods have advantages over Isotope Ratio Mass Spectrometry (IRMS) in that they can be used for in-situ measurements and require much less maintenance and preparation work. Two types of laser-based methods are currently available, which have different analytical principles; OA-ICOS (off-axis integrated cavity output spectroscopy) and WS-CRDS (wavelength-scanned cavity ring-down spectroscopy). In the WS-CRDS instrument, water is vaporized at controlled environment and transferred to an optical cavity by nitrogen carrier gas, and stable isotopic compositions of water vapor are measured using the degree of absorbance of specific wavelengths and the ratios of attenuation time of the laser intensity with the sensitivity of ppb to tens of ppt level. In this study, we introduce the principle of the WS-CRDS technology and the performance results including stability and comparisons with Isotope Ratio Mass Spectrometry (IRMS) and suggest possible applications of various topics in isotope hydrology.

Case Study on Optimization of Send-out Operation in Liquefied Natural Gas Receiving Terminal (LNG 터미널 송출 운전 최적화 사례 연구)

  • Park, Chansaem;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.150-155
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    • 2015
  • Recently, LNG receiving terminals have been widely constructed and expanded for an increase in LNG demand. Selection of the storage tank for send-out and estimation of send-out flow rate have significant influence to process operation and economics. In this study, a send-out flow rate of each storage tank is optimized in order to minimize the total BOG generation rate. Considering a size and characteristic of each storage tanks, BOG flow rates are estimated using a dynamic simulation with varying liquid levels in the tanks. The regression model is developed fitting BOG flow rates and tank liquid levels, which are boil off rate model to predict BOG flow rates with particular level data. The objective function and constraints including required total send-out flow rate and level limit in the tanks are formulated to optimize a send-out flow rate of each tank. This method for optimization of send-out operation is applied to the Incheon LNG receiving terminal considering two scenarios for various liquid levels and maximum and minimum required send-out flow rates. For maximum required send-out flow rate, this method achieves BOG reduction of 9% comparing with assumed conventional operation.

Simulation of Remote Field Scanner for Defect Evaluation of Water Wall Tube Within the Fluidized Bed Boiler (유동층보일러 수냉벽튜브 결함평가를 위한 원격자장 스캐너 시뮬레이션에 관한 연구)

  • Gil, Doo-Song;Jung, Gye-Jo;Seo, Jung-Seok;Kim, Hak-Joon;Kwon, Chan-Wool
    • KEPCO Journal on Electric Power and Energy
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    • v.6 no.2
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    • pp.145-150
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    • 2020
  • Water wall tube is one of the major factors consisting of a fluidized bed boiler and it plays very important role for the generation of electricity within the boiler. But these water wall tubes within the fluidized bed boiler are subject to the ware and corrosion caused by the high temperature gas and the flowing medium. If water leak is occurred, the secondary damage by the water leak will occur. As a result of that, the power generation efficiency decreases noticeably. Therefore, the maintenance of the water wall tube is very important. In this study, we designed a exciter sensor based on simulation and composed a remote field eddy current system for the defect evaluation of the outer water wall tube. Starting from the shape design of exciter, we conducted simulations for various design factors such as the water wall tube size, material, frequency, lift-off and so on. Based on the results, we designed the optimum exciter sensor for the water wall tube test within the fluidized bed boiler.

Separation of Volatile Compounds from Tuna Fish Oil With Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 참치유로부터 휘발성 성분의 분리)

  • Roh Hyung Seob;Youn Hyun Seok;Jung Sun Mi;Hong Yeon Ryun;Kang Kil Yoon;Chun Byung Soo
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.12-17
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    • 2005
  • Despite a wide range of fatty acids in fish oil, its the usage are very limited owing to off-flavors and volatile compounds in the oil. A way to extract and remove volatile compounds was performed at a semi-flow extractor by using supercritical carbon dioxide $(SC-CO_2)$. Samples of the oil were treated at the conditions which ranged from $30\;to\;80^{\circ}C$ and from 80 to 200 bar with 10 mL/min flow rate of carbon dioxide. In the oil the volatile compounds were analyzed by gas chromatography. Before extraction with $SC-CO_2$ the oil sample was detected over 129 peaks but 99 compounds were identified. The results demonstrated that at $40^{\circ}C$ and 200 bar extraction condition the volatile compounds in the tuna fish oil were removed, except for 14 compounds identified after extraction and other $SC-CO_2$ extraction conditions reached to high reduction of the volatile compounds.

Fabrication of Polymeric Blend Membranes Using PBEM-POEM Comb Copolymer and Poly(ethylene glycol) for CO2 Capture (PBEM-POEM 공중합체와 Poly(ethylene glycol)의 폴리머 블렌드를 이용한 이산화탄소 분리막 제조)

  • Moon, Seung Jae;Min, Hyo Jun;Kim, Na Un;Kim, Jong Hak
    • Membrane Journal
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    • v.29 no.4
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    • pp.223-230
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    • 2019
  • In this paper, we develop a polymeric blend membrane based on $CO_2$-philic poly(2-[3-(2H-benzotriazol-2-yl)-4-hydroxyphenyl] ethyl methacrylate)-poly(oxyethylene methacrylate) (PBEM-POEM) comb copolymer, which was synthesized by facile free radical polymerization. The PBEM-POEM (PBE) comb copolymer was blended with a commercial oligomer, low-molecular-weight poly(ethylene glycol) (PEG, $M_w=200gmol^{-1}$) with various ratios to prepare $CO_2/N_2$ separation membranes. From the result of $CO_2/N_2$ separation test of the PBE/PEG blend membranes with the various PEG contents, we could conclude that with increasing PEG content, the $CO_2/N_2$ selectivity significantly increased while the CO2 permeability decreased showing trade-off relationship. However, when comparing the performance of the PBE/PEG (9 : 1) with the PBE/PEG (7 : 3) membrane, the $CO_2$ permeance decreased by only 8.3%, while the $N_2$ permeance decreased by 69.1%. Therefore, the $CO_2/N_2$ selectivity dramatically increased from 33.8 to 100.3. This could be because the POEM chains, which account for 80% of the PBE copolymer, favorably interact with PEG and lead to a more compact chain structure, which was confirmed by FT-IR, XRD and SEM analysis. The PBE/PEG (7 : 3) blend membrane had the most optimal gas separation performance, showing a $CO_2$ permeance of 170.5 GPU and $CO_2/N_2$ selectivity of 100.3.

Developed Vacuum Film Packaging Method Maintains Quality of Enoki Mushrooms (Flammulina velutipes) during Simulated Vessel Export to Vietnam (팽이버섯의 베트남 모의수출 중 진공포장방법 개선을 통한 품질 유지 효과)

  • Choi, Ji Weon;Lim, Sooyeon;Lee, Ji Hyun;Eum, Hyang Lan;Lee, Jung-Soo;Park, Hye Sung;Im, Ji-Hoon;Do, Kyung Ran
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.133-142
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    • 2022
  • Korean enoki mushrooms are exported to Southeast Asia and the United States, where there are complaints due to quality deterioration during the distribution process. In this study, we evaluated the efficacy of vacuum film packaging on quality maintenance in Korean enoki mushrooms during simulated vessel export to Vietnam using selected film, which was developed with vacuum packaging machine and oxygen absorber. We selected two MA film, one was 2-layerd 30 ㎛ CPP film (control) and the other was 3-layered 30 ㎛ CPP film (treatment) which is optimized film of higher gas and moisture permeability. The Korean enoki mushrooms were packaged with these two films using PAC-2000 or PAC-3000 vacuum packaging machine which was improved vacuuming of higher speed. Packed mushrooms were stored at 1℃ for 2 weeks and distributed at 20℃ for 2 days or 8℃ for 6 days. The efficiency of the film packaging was analyzed by vacuum maintaining index, and overall the quality characteristics such as off odor, color, cap cleavage, stem elongations and sensory evaluation were evaluated during storage and distribution. Results suggest that postharvest loss of fresh enoki mushroom could be reduced by packaging mushroom with 3-layered 30 ㎛ CPP films packaged using PAC-3000 machine during simulated vessel export to Vietnam due to vacuum maintaining. Oxygen absorber promoted off-odor at 20℃ distribution temperature, and did not affect storability at 1℃ storage compared to treated group without oxygen absorber treatment.

Scale Effect Analysis of LNG Cargo Containment System Using a Thermal Resistance Network Model (열저항 네트워크 모델을 이용한 LNG 화물창 Scale Effect 분석)

  • Hwalong You;Taehoon Kim;Changhyun Kim;Minchang Kim;Myungbae Kim;Yong-Shik Han;Le-Duy Nguyen;Kyungyul Chung;Byung-Il Choi;Kyu Hyung Do
    • Journal of the Society of Naval Architects of Korea
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    • v.60 no.4
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    • pp.222-230
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    • 2023
  • In the present work, the scale effect on the Boil-Off Rate (BOR) was investigated based on an analytical method to systematically evaluate the thermal performance of a Liquefied Natural Gas (LNG) Cargo Containment System (CCS). A two-dimensional thermal resistance network model was developed to accurately estimate the heat ingress into the CCS from the outside. The analysis was performed for the KC-1 LNG membrane tank under the IGC and USCG design conditions. The ballast compartment of both the LNG tank and cofferdam was divided into six sections and a thermal resistance network model was made for each section. To check the validity of the developed model, the analysis results were compared with those from existing literature. It was shown that the BOR values under the IGC and USCG design conditions were agreed well with previous numerical results with a maximum error of 1.03% and 0.60%, respectively. A SDR, the scale factor of the LNG CCS was introduced and the BOR, air temperature of the ballast compartment, and the surface temperature of the inner hull were obtained to examine the influence of the SDR on the thermal performance. Finally, a correlation for the BOR was proposed, which could be expressed as a simple formula inversely proportional to the SDR. The proposed correlation could be utilized for predicting the BOR of a full-scale LNG tank based on the BOR measurement data of lab-scale model tanks.