• Title/Summary/Keyword: Odor compounds

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Adsorption and Removal of Volatile Organic Compounds from Fabrics with β-Cyclodextrin Finish (직물의 β-cyclodextrin 가공에 따른 휘발성 유기성분의 흡착과 제거)

  • Chung, Haewon;Hwang, Nawon;Kim, Joo-Yeon;Shin, Seung-Yeop
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.1
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    • pp.113-123
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    • 2013
  • Clothes that retain and emanate body odor feel uncomfortable and unclean; subsequently, the adsorption, desorption and removal amounts of malodorous compounds from fabrics with different polarities were examined. 1-Octen-3-one, octanal and isovaleric acid, which are important malodor compounds from the body, were used as volatile organic compounds (VOC). Samples were prepared with unfinished and ${\beta}$-CD finished cotton, nylon and PET fabrics. The amounts of VOCs retained on the fabrics were measured using headspace GC-MS; in addition, the odor intensity of the samples were evaluated by 10 trained panelists. The amounts adsorbed were estimated by weight gain; however, moisture was found to have a larger effect on the increase in weight than VOCs. The polarity of the VOCs decreased in the order of isovaleric acid, octanal and 1-octen-3-one. Despite the exceptionally large amounts of octanal adsorbed on the nylon sample, the amounts of malodorous compounds adsorbed on fabrics increased with the decreasing VOC molecular weight. The unfinished PET sample adsorbed more VOCs than the unfinished-fabric samples. The odor intensity was mostly weaker in the ${\beta}$-CD finished fabrics than in the unfinished fabrics. The odor intensity of the ${\beta}$-CD finished fabrics was lower than unfinished fabrics. The amount of VOCs that remained on the soiled fabric samples after storing in air for 24 hrs decreased with the increasing VOC vapor pressure. Most VOCs were removed by washing; however, more VOCs were left on the ${\beta}$-CD finished fabrics than unfinished fabrics. The intensity of the odor from the unfinished PET and ${\beta}$-CD finished fabrics was stronger and weaker, respectively, than that of other fabrics, even when the same amounts of VOCs remained.

Odor generation pattern of swine manure according to the processing form of feed

  • Won Choi;Wooje Lee;Kiyoun Kim
    • Journal of Animal Science and Technology
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    • v.66 no.1
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    • pp.219-231
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    • 2024
  • Feed has a great influence on the composition of swine manure, which is the principal cause of odor. Therefore, the purpose of this study is to simply change the shape of pig feed and control calories to find a suitable feed form for reducing the smell of swine manure. The experiment was conducted on 15 pigs from July to August 2021, and a total of three measurements were done. Three types of feed were evaluated in this study. The analysis items related to odor of swine manure are complex odor, ammonia, sulfur-based odors, and volatile organic compounds (VOCs). In the case of complex odor, dilution multiples tended to decrease over time, except for type A feed. The concentration of ammonia in all types of feed decreased over time. Most sulfur-based odorous substances except hydrogen sulfide at the first measurement were not detected. Representatively, Decane, 2,6-Dimethylnonane, and 1-Methyl-3-propylcycolhexane were detected in VOCs generated from swine manure. The major odorous substansces in swine manure have changed from ammonia and sulfur compounds to VOCs. In order to reduce the odor caused by swine manure, it is ad-vantageous to use low-calorie feed consisting of pellet-type.

The Effect of Boiling Water on DBPs and Taste-and-Odor Compounds in Drinking Water (음용수에서 소독부산물과 이취미 유발물질의 끓임 효과)

  • Kim, Chang-Mo;Choi, In-Cheol;Chang, Hyun-Seong;Park, Hyeon;Han, Sun-Hee
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.262-267
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    • 2006
  • DBPs and T&O(taste-and-odor) compounds in drinking water is one of main source to deteriorate water quality. So, these compounds can cause adverse health effects and result in many consumer complaints aesthetically. This experiments carried out to investigate the effect of boiling water on DBPs and T&O compounds in the tap water. THMs and TCM concentration were reduced by 91.3%, 88.9% after 5 min of boiling, respectively. It is certainly, resulted from volatilization of TCM. TCAA concentration decreased when the water was boiled, too. By contrast, the concentration of DCAA was increased with duration time from boiling-point. The reduction of TCAA from the boiled water can be attributed to chemical transformation like decarboxylation. T&O compounds such as geosmin and 2-MIB was effectively removed by boiling of water, resulting in the removal efficiency of 97.1%, 94.4% after 5 min of boiling, respectively.

A Study on the Distribution Characteristics of Sulfur Compounds in Ambient air using Continuous Monitoring Method in Incheon Area

  • Seo, Seok-Jun;Lim, Yong-Jae;Hong, You-deok;Park, Geon-Young
    • Journal of Integrative Natural Science
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    • v.8 no.2
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    • pp.128-134
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    • 2015
  • This paper focuses on the applicability of a continuous monitoring method on trace sulfur compounds in the ambient air by TD and GC/PFPD. The target compounds for monitoring include H2S(hydrogen sulfide), Methyl mercaptan, Dimethyl Sulfide, and Dimethyl disulfide. The result of QA/QC on monitoring instruments satisfies all the standards of Odor Measurement and Analysis Method, showing that the reproductivity of the compounds by concentration is within 10%, linearity is above 0.98 of a correlation efficient, method detection limit is 0.16 ppb by MM standard, and recovery rate is over 70%. Monitoring was conducted for two years from March 2006 to February 2008. As a result of the monitoring, the average concentration of H2S was 0.08 ppb, with the maximum concentration at 16.15 ppb. The result indicates that it is reasonable to do continuous monitoring as there appears a spontaneous event of high concentration by the condition of the site during monitoring odor-causing substances. Therefore, it is suggested that the continuous monitoring method used in this paper is appropriate to identify the characteristics of sudden occurrence and concentration variations of sulfur compounds.

Masking Effect of Chlorine on Algae-related Taste and Odor in Drinking Water Supplies (염소의 상수원 내 조류 이취미 Masking 효과)

  • Kim, Young-il;Lee, Yu-Jeong;Shin, Heung-Sup;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.227-232
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    • 2008
  • The masking effect of chlorine on algae-related taste and odor(T&O) compounds has long been an important issue for water suppliers. In this study, masking experiments with chlorine were performed on two kinds of treated water and one of raw water. After adding chlorine(0 to 0.8 mg/L) to water samples, odor intensity was evaluated by a newly developed sensory method(2-out-of-5 odor test) for three days along with the measurement of residual chlorine concentration. Even though the relationship between the residual chlorine concentration and odor reported by the sensory analysts was not always coincident, it was proved that residual chlorine more than a certain concentration could completely mask both added geosmin and naturally occurring T&O compounds. For the sand-filtered water spiked with 10 ng/L of geosmin, 0.12-0.18 mg/L of residual chlorine was necessary to achieve complete masking. In the case of GAC-filtered water, 10 ng/L of spiked geosmin was completely masked by 0.15-0.1 mg/L of residual chlorine. Combined ozone and GAC was not enough to treat raw water spiked with 300 ng/L of geosmin. In this experiment, sensory analysts were able to detect earthy or musty odors from the treated water. From a masking experiment with raw water taken from the Daechung Reservoir, it was found that fishy odor was more difficult to mask with chlorine than earthy odor. As the chlorine residual declined, the analysts began to notice the original odor and the fishy odor was noticed earlier than the earthy odor.

Study on the Characteristics of Odor Emitted from Swine Facilities (양돈시설에서 발생하는 악취특성에 관한 연구)

  • Kim, Jae Hyuck;Yoo, Kyung Seun;Oh, Je Beom;Jung, Ju Young
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.7
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    • pp.439-444
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    • 2012
  • We studied the characteristics of odor emitted from 40 swine facilities across the country under various conditions like rearing densities, management style, ventilation system and swine manure handling characteristics, based on the olfactory and analytical evaluation. Odor concentrations (D/T) measured from swine facilities were respectively an average 4,055 D/T at liquid manure storage tanks on aeration, an average 913 D/T at slurry manure storage, an average 506 D/T at finishing swine facilities and an average 201 D/T at composting facilities. The higher rearing densities and slurry accumulation volume in finishing swine house, the more odor concentration (D/T) was increased. But The odor concentration (D/T) in finishing swine house did not show significant difference according to application of microbial additives. 9 odor compounds ($NH_3$, $H_2S$, MM, DMS, DMDS, PA, n-BA, n-VA, i-VA) were detected at swine facilities and the main odor compounds were volatile sulfur compounds such as $H_2S$, MM and volatile fatty acids compounds such as n-BA, n-VA, i-VA. 97.5% of swine farms surveyed in this study is located within 300 m of residential area and it is easy to bring odor complaints.

A Study on Odor and Taste from Nam River (남강의 수중보에서 발생하는 이취미 물질에 관한 연구)

  • 이춘식;박현건
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.399-403
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    • 2002
  • This study was designed to analyse the odor from Nam river. The characteristic odor in the water occurred from geosmin and phenol, p-cresol and indol were detected from sediment/water samples. The others were detected as alcohols and fat acid compounds. Algae causing odor and taste were identified as Oscillatoria sp. and Synedra acus. 15 species of phytoplankton, a zooplankton, an eelworm and chironomus were identified in water/sediment sample.

Dispersion Characteristics of Odorous Elements from Nambu Wastewater Treatment Plant and a Nearby Streams in Busan (부산시 남부하수처리시설과 인근 하천에서 발생하는 악취물질 확산 특성)

  • Mun, Seong-Man;Lee, Hyung-Don;Cho, Sang-Won;Kang, Dong-Hyo;Park, Hae-Sik;Oh, Kwang-Joong
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.953-962
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    • 2011
  • The covered stream of cities are considered an odor source. Also, the public do not want a wastewater treatment plant(WWTP) near their properties due to the emission of odor emanating from such sources, although they play an important role in urban development. The purpose of this study is to analyze the pattern distribution of the odorous compounds from the Nambu WWTP and Youngho stream in Busan. odor sampled four times were analyzed by instrumental analysis method and indirect olfactory method. The kinds of offensive odorous compounds examined are acetaldehyde, propion aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and ammonia. Also, Concentration of air pollutants has been calculated by ISCST3 models. At the result of this study, The Nambu WWTP releases sulfur compounds. And the major odorous were hydrogen sulfide (1,475 ppb) and acetaldehyde (95 ppb) at Youngho stream. The stink which residents feel will point out the Nambu WWTP mainly if the odor is removed with the improvement of a Youngho stream. Accordingly, we should pay more attention to appropriate components to processes in odor reducing plan at Nambu WWTP.

Characteristic of Odorous Compounds Emitted from Livestock Waste Treatment Facilities Combined Methane Fermentation and Composting Process (메탄발효와 퇴비화 공정이 연계된 가축분뇨 처리시설에서 발생되는 악취물질 특성 조사)

  • Ko, Han Jong;Kim, Ki Youn;Kim, Hyeon Tae;Ko, Moon Seok;Higuchi, Takasi;Umeda, Mikio
    • Journal of Animal Science and Technology
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    • v.50 no.3
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    • pp.391-400
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    • 2008
  • Odor management is significantly concerned with sustainable livestock production because odor nuisance is a primary cause for complaint to neighbors. This study was conducted to measure the concentration of odorous compounds, odor intensity, and odor offensiveness at unit process in animal waste treatment facility combined composting and methane fermentation process by an instrumental analysis and direct olfactory method. Ammonia, sulfur-containing compounds, and volatile fatty acid were analyzed at each process units and boundary area in summer and winter, respectively. Higher concentration of odorants occurred in the summer than in the winter due to high ambient temperature. The maximum concentration of odorants was detected in composting pile when mixed manure was being turned followed by inlet, curing, outlet, and screen & packing process. Highest concentration of detected odorous compounds was ammonia ranging from 3.4 to 224.7 ppm. Among the sulfur-containing compounds measured, hydrogen sulfide was a maximum level of 2.3 ppm and most of them exceeded reported odor detection thresholds. Acetic acid was the largest proportion of VFA generated, reaching a maximum of 51 to 89%, followed by propionic and butyric acid at 1.9 to 35% and 1.8 to 15%, respectively. Malodor assessment by a human panel appeared a similar tendency in instrumental analysis data. Odor quotient for predicting major odor-causing compounds was calculated by dividing concentrations measured in process units by odor detection thresholds. In the composting process, hydrogen sulfide, ammonia, dimethyl sulfide, and methyl mercaptan were deeply associated with odor-causing compounds, while the major malodor compounds in the inlet process were methyl mercaptan, hydrogen sulfide, and butyric acid.

Emissions of Odor, Ammonia, Hydrogen Sulfide, and Volatile Organic Compounds from Shallow-Pit Pig Nursery Rooms

  • Kafle, Gopi Krishna;Chen, Lide
    • Journal of Biosystems Engineering
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    • v.39 no.2
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    • pp.76-86
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    • 2014
  • Purpose: The objective of this study was to measure emissions of gases (ammonia ($NH_3$), hydrogen sulfide ($H_2S$) and carbon dioxide ($CO_2$)), volatile organic compounds (VOC) and odor from two shallow pit pig nursery rooms. Gas and odor reduction practices for swine operations based on the literature were also discussed. Methods: This study was conducted for 60 days at a commercial swine nursery facility which consisted of four identical rooms with mechanical ventilations. Two rooms (room 1 (R1) and room 2 (R2)) with different pig numbers and ventilation rates were used in this study. The pig manure from both the R1 and R2 were characterized. Indoor/outdoor temperatures, ventilation rates/duration, $NH_3$, $H_2S$, $CO_2$, and VOC concentrations of the ventilation air were measured periodically (3-5 times/week). Odor concentrations of the ventilations were measured two times on two days. Three different types of gas and odor reduction practices (diet control, chemical method, and biological method) were discussed in this study. Results: The volatile solids to total solids ratio (VS/TS) and crude protein (CP) value of pig manure indicated the pig manure had high potential for gas and odor emissions. The $NH_3$, $H_2S$, $CO_2$ and VOC concentrations were measured in the ranges of 1.0-13.3, 0.1-5.7, 1600-3000 and 0.0-1.83 ppm, respectively. The $NH_3$ concentrations were found significantly higher than $H_2S$ concentrations for both rooms. The odor concentrations were measured in the range of $2853-4432OU_E/m^3$. There was significant difference in odor concentrations between the two rooms which was due to difference in pig numbers and ventilation duration. The literature studies showed that simultaneous use of dietary control and biofiltration practices will be more effective and environmentally friendly for gas and odor reductions from pig barns. Conclusions: The gas and odor concentrations measured in the ventilation air from the pig rooms indicate an acute need for using gas and odor mitigation technologies. Adopting diet control and biofiltration practices simultaneously could be the best option for mitigating gas and odor emissions from pig barns.