• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.89-96
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• 2023

In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO₂ content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.2
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• pp.28-36
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• 2019

The adhered mortars in recycled aggregate may lower the performance of the concrete, such as by reducing in strength and durability, and cracking. In the present study, the effects of nylon fiber (NF) on the mechanical and durable properties of 100% ordinary portland cement (OPC) and 50% ground granulated blast furnace slag (GGBFS) concretes incorporating recycled coarse aggregate (RA) were experimentally investigated. Concrete was produced by adding 0 and $0.6kg/m^3$ of NF and then cured in water for the predetermined period. Measurements of compressive and split tensile strength, water permeable pore and total charge passed through concrete were carried out, and the corresponding test results were compared with those of concrete incorporating crushed coarse aggregate (CA). In addition, the microstructures of 28-day concretes were observed by using SEM technique. Test results revealed that the RA concrete showed lower performance than CA concrete because of the adhered mortars in RA. However, it was obvious that the addition of NF in RA concrete was much effective in enhancing the performance of the concretes due to the bridge effect from NF. In particular, the application of NF2 (19 mm) exhibited a somewhat beneficial effect compared with concrete incorporating NF1 with respect to mechanical properties, especially for RA concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.307-315
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• 2023

In this study, mortar test specimens were produced by varying the mixing ratio of CO₂ reaction hardening cement (CSC) and general cement (OPC), and the mechanical and carbonation characteristics were evaluated by controlling the primary curing temperature and secondary curing CO₂ pressure. Under all curing conditions, it was observed that the higher the CSC ratio in the binder, the lower the mechanical properties. Specifically, a first curing temperature of 60 ℃ yielded higher mechanical properties compared to the case of 20 ℃, and a greater carbonation penetration depth was also observed. At a first curing temperature of 60 ℃, it was noted that the curing pressure and bending strength during the second CO₂ curing were inversely proportional, while the compressive strength showed a proportional relationship. This phenomenon is believed to be due to excessive carbonation, which reduces mechanical properties, and the fact that flexural strength is more sensitive to these properties compared to compressive strength. However, based on the evaluation of the limited curing conditions, it is evident that future test conditions need to be expanded and reviewed more thoroughly.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.185-191
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• 2017

The objective of this paper is to investigate the effect of waste refractory powder(WRP) and desulfurization gypsum(FGD) as activators on the flow properties and the strength development of high volume blast furnace slag mortar incorporating illite(BSM) having adsorption and deodorization. To fabricate the BSMs with 60% of W/B, blast furnace slag are incorporated with 45% and 65%, respectively. WRP and FGD are substituted from 5 to 10%. Test results indicate that the flow is decreased with increase of WRP and FGD, while increase of WRP and FGD enhance the compressive strength due to accelerated reaction of blast furnace slag, The use of illite results in a decrease of compressive strength. pH has increasing tendency until 7days, while it has reduction. In this paper, optimal dosages of WRP and FGD are believed to be around 5% each.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.60-65
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• 2014

Recently, lots of researches on alkali-activated slag (AAS) concrete have been carried out to resolve the environmental issues such as recycling by-products and global warming. AAS concrete would have high strength and high level of durability. On the other hand, it is known that large amount of shrinkage occurred in AAS concrete due to rapid alkaline reaction in the early age, and however, the related studies about autogenous shrinkage of high strength AAS mortar are relatively rare. In this study, fresh mortar properties such as flow and setting time, compressive strength and autogenous shrinkage of AAS mortar with W/B=0.40 to 0.50, were measured. AAS mortar was activated with sodium silicate (Ms=1.0) with 5, 6 and 7 % of $Na_2O$. Test results revealed that AAS morar shows larger autogenous shrinkage than OPC mortar and the lower W/B of AAS mortar, the greater autogenous shrinkage. Therefore, the application of appropriate curing and the use of shrinkage reduction admixture would be needed to reduce autogenous shrinkage of AAS mortar.

• Journal of the Korean Ceramic Society
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• v.44 no.1 s.296
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• pp.43-51
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• 2007

Fluidity, setting time, hydration heat, bond water ratio, compressive strength, SEM and BET of OPC were measured by adding 1.0 wt% KCl and replacing 20 wt% mineral admixture in order to examine effects of blast furnace slag (BFS), limestone powder (LSP), and fly ash (FA) on fluidity and strength development of the cement contained much chloride. In general, the cement contained much chloride was high in heat of hydration, short in its setting time, low in its fluidity and low in its strength at 28 days due to the rapid hydration in its initial stage. As a result of the experiment, it has been demonstrated that fluidity became improved but the compressive strength at 28 days was decreased as replaced LSP to the cement contained much chloride. the fluidity and compressive strength at 28 days was improved as replaced BFS, the initial compressive strength development was improved due to the activation of initial reaction by KCl. Fluidity, initial compressive strength and late compressive strength at 28 days of cement contained much chloride replaced 5 wt% LSP and 15 wt% BFS concurrently was better than OPC, but the hydration heat was lower.

• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.27-34
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• 2020

In the industry, due to the carbon dioxide gas produced during cement production is increasing, research on recycling by-products has been actively conducted. In the industrial by-products, the high calcium fly ash(HCFA) produced by the blast-furnace in the circulating fluidized bed combustion method has a high ratio of CaO and CaSO4. In view of this, the purpose of this is to use high calcium fly ash(HCFA) as a stimulant in blast furnace slag powder and use it as a cement substitute. As a result, it is judged that the substitution ratio of HCFA should be 15% or less. In addition, although durability and strength are relatively lower than of OPC, it is considered that it can be utilized as an environmentally building material.

• Journal of the Korea Institute of Building Construction
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• v.18 no.2
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• pp.109-115
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• 2018

Since the current method of SCW cement milk pouring method uses one to one ratio of cement milk with OPC, there are some problems such as drying shrinkage, increased cost, difficulty of controlling mix proportions for various conditions of applied soil, and precipitation of $Cr^{6+}$ due to the excessively used cement. Specifically, in aspect of sustainability issues of cement manufacturing, the consumption of cement should be reduced. Hence, in this research, as a replacement of cement for SCW method, blast furnace slag with sulfate or alkali as a stimulant, and expansive admixture were used. By using blast furnace slag as a hardening composite of SCW, there are many advantages such as free controllable mix proportions, rapid setting time with less mud occurrence, less cost with less energy for mixing, constant strength development, and less precipitation of $Cr^{6+}$. Regarding the alternative composites for SCW, in this research, durability and chloride resistance were evaluated.

• Journal of the Korea Concrete Institute
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• v.25 no.5
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• pp.565-572
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• 2013

Hydration and physical characteristics of chemically-bonded phosphate ceramic (CBPC) binder based on dead-burned Mg-O with six different blends are investigated for efficient repair construction material by retarding set phase with $H_3BO_3$. The test specimen of the blender with silica fume shows higher compressive strength after 75 days. The CBPC with silica fume results in higher modulus of rupture that others. The test specimens of CBPC eludes lower calcium ion than that of OPC (Ordinay Portland Cement). The X-ray diffraction pattern shows that hydration results in the formation of magnesium hydroxide, M-S-H gel and $MgCO_3$ for the specimen with silica fumes. Combination with calcium for MgO is not desirable due to no formation of chemical bond between two components. Based on the experimental program, the mixture of MgO and silica fume shows efficient performance in strength and durability.

• Journal of the Korea Institute of Building Construction
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• v.17 no.5
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• pp.419-427
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• 2017

In order to examine the possibility of practical use of aluminate cement concrete at low-temperature environment with insulation method, an experimental studies on flowability, setting time, freezing temperature, size variation and compressive strength of the mortar at low-temperature were conducted. Compressive strength was increased in use of CSA, aluminate cement with gypsum. Workability and physical properties were improved by using aluminate cement and gypsum. In addition, freezing resistance and physical properties were improved by applying the insulation curing method. Especially, when alumina cement and gypsum were used together, the insulation curing method was more effective in improving the compressive strength.