• 제목/요약/키워드: OIL

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EXPERIMENTAL STUDY ON THE DISSOLUTION COMPONENTS AND CORROSION PRODUCTS OF SEVERAL AMALGAMS IN ARTIFICIAL SALIVA (인공타액에서 수종 아말감의 부식시 용해성분 및 표면 부식 생성물에 관한 실험적 연구)

  • Cho, Seung-Joo;Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.1-26
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    • 1994
  • The purpose of this study was to investigate the dissolution components during corrosion of amalgams and to identify surface corrosion products in the modified Fusayama artificial saliva. Four type of amalgam alloys were used: low copper lathe cut amalgam alloy (Cavex 68), low copper spherical amalgam alloy (Caulk Spherical Alloy), high copper admixed amalgam alloy (Dispersalloy) and high copper single composition amalgam alloy (Tytin). Each amalgam alloy and Hg were triturated according to the manufacturer's direction by means of mechanical amalgamator (Capmaster, S.S.White), and then the triturated mass was inserted into the cylindrical metal mold which was 10mm in diameter and 2.0mm in height and condensed with compression of 150kg/$cm^2$ using oil pressor. The specimens were removed from the mold and stored at room temperature for 7 days and cleansed with distiled water for 30 minutes in an ultrasonic cleaner. The specimens were immersed in the modified Fusayama artificial saliva for the periods of 1 month, 3 months and 6 months. The amounts of Hg, Cu, Sn and Zn dissolved from each amalgam specimen immersed in the artificial saliva for the periods of 1 month, 3 months and 6 months were measured using Inductivity Coupled Plasma Atomic Emission Spectrometry (ICPQ-1000, Shimadzu, Japan) and amount of Ag dissolved from amalgam specimen was measured using Atomic Absorption Spectrophotometry (Atomic Absorption/Flame emission spectrophotometer M-670, Shimadzu, Japan). A surface corrosion products of specimens were analysed using Electron Spectroscopy Chemical Analyser (ESCA PHI-558, PERKIN ELMER, U.S.A.). The secondary image and back scattered image of corroded surface of specimens was observed under the SEM, and the corroded surface of specimens was analysed with the EDX. The following results were obtained. 1. The dissolution amount of Cu was the most in high copper admixed amalgam(Dispersalloy) and the least in high copper single composition amalgam(Tytin). 2. Sn and Zn were dissolved during all the experiment periods, and dissolution amounts were decreased as the time elapsed. 3. Initial surface corrosion products were ZnO and SnO. 4. Corrosion of ${\gamma}$ and ${\gamma}_2$ phase in low copper amalgams was observed and Ag-Cu eutectic alloy phase was corroded in low copper spherical amalgam(Caulk Sperical Alloy). 5. Corrosion of ${\gamma}$ and $\eta$' phase in high copper amalgams was observed and Ag-Cu eutectic alloy phase was corroded in high copper admixed amalgam(Dispersalloy). 6. Sn-Cl was produced in the subsurface of low copper amalgams and high copper admixed amalgam.

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Technical Trends of Hydrogen Manufacture, Storage and Transportation System for Fuel Cell Vehicle (연료전지자동차용 수소제조와 저장·운반기술동향)

  • Kil, Sang-Cheol;Hwang, Young-Gil
    • Resources Recycling
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    • v.25 no.1
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    • pp.48-59
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    • 2016
  • The earth has been warming due to $CO_2$ gas emissions from fossil fuel cars and a ship. So the hydrogen fuel cell vehicle(FCV) using hydrogen as a fossil fuel alternative energy is in the spotlight. Hyundai Motor Company of Korea and a car companies of the US, Japan, Germany is developing a FCV a competitive. Obtained hydrogen as a by-product of the coke plant, oil refineries, chemical plants of steel mill, coal is reacted with steam at high temperatures, methane gas, manufacture of high purity hydrogen Methane Steam Reforming and hydrogen detachable reforming method using the Pressure Swing Adsorption or Membrane Reforming technical or decomposition of water to produce electricity. Hydrogen is the electronic industry, metal and chemical industries, which are used as rocket fuel, etc. are used in factories, hospitals, home of the fuel Ene.Farm system or FCV. And a method of storing hydrogen is to store liquid hydrogen and a method for compressing normal hydrogen to the hydrogen container, by storing the latest hydride or Organic chemical hydride method is used to carry the hydrogen station. Korea is currently 13 hydrogen stations in place and in operation, plans to install a further 43 places.

A Study on the Formation of Hydrate Plugging due to water molecules in High Pressure and Low Temperature Gas Pipeline (고압$\cdot$저온 가스 배관에서 수분에 의한 하이드레이트 플러깅 형성)

  • Lee J. H.;Baek Y. S.;Sung W. M.
    • Journal of the Korean Institute of Gas
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    • v.6 no.1 s.17
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    • pp.38-45
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    • 2002
  • Hydrates are solid cryctallines resembling ice in appearance, which are consist of a gas molecule surrounded by a cage of water molecules. Because of containning a large amount of methane, hydrates have been considered as a future energy resource. However, the formation of hydrates in the oil and gas industries has been known as a serious problem for a long time. The formation of hydrate in pipeline is common in seasonally cold or sub-sea environments with low temperatures and high pressures. Especially, hydrate plug formation becomes a real menace to flow assurance in inadequately protected transmission lines. This study was carried out for the purpose of understanding mechanism of hydrate plugging and examining formation conditions of hydrate in high pressure gas pipeline. In this study, we measured hydrate equilibrium conditions under the various flowing conditions with the methane. The results were presented both the plugging tendency and the effect of flowing velocity.

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Fire Examples Study of Intake and Exhaust System, Alternator Tuning and Inflow of Inflammables on Exhaust Part in a Car (자동차 흡배기장치, 발전기 튜닝 및 배기측 인화성 물질 유입에 관련된 화재사례 연구)

  • Lee, Il Kwon;Kook, Chang Ho;Suh, Moon Won;You, Chang Bae;Youm, Kwang Wook;Lim, Chun Moo;Jung, Dong Hwa
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.47-51
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    • 2014
  • This paper is to analyze and study the fire examples in respect of intake and exhaust, alternator tuning and inflow of inflammables on exhaust part in a car. In the first example, the driver diverted the intake and exhaust system for tuning of a car. Stopping a car to rest for moment, the flammable styrofoam scrap go into exhaust pipe that installed with exhaust manifold newly. It certified the fact that catched fire gradually, furthermore enlarged the fire by leaking fuel. In the second example, the driver enlarged the generator performance to divert the audio system in side room., it knew the fact that the electric wiring connected with generator gave the cause of outbreak a fire by overheating. In the third example, the serviceman replaced the engine oil using funnel-shaped, he put the a bottle of plastic pat onto engine cover carelessly. Consequentially, it found the fire occurrence in the engine room. Therefore, the driver never divert the intake and exhaust and generator construction of a car abnormally. Also, repairing and inspecting a car, the serviceman have a care to not occur the fire by inflammables.

Design of Naphtha Cracker Gas Splitter Process in Petlyuk Column (납사열분해 가스분리공정에서의 Petlyuk Column 설계)

  • Lee, Ju Yeong
    • Journal of the Korean Institute of Gas
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    • v.24 no.1
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    • pp.17-22
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    • 2020
  • Light Naphtha is distillated from crude oil unit and separated into the methane, ethylene and propylene by boiling point difference in sequence. This separation is conducted using a series of binary-like columns. This separation method is known that the energy consumed in the reboiler is used to separate the heaviest components and most of this energy is discarded as vapor condensation in the overhead cooler. In this study, the first two columns of the separation process are replaced with the Petlyuk column. A structural design was exercised by the stage computation with ideal tray efficiency in equilibrium condition. Compared with the performance of a conventional system of 3-column model, The design outcome shows that the procedure is simple and efficient because the composition of the liquid component in the column tray was designed to be similar to the equilibrium distillation curve. The performance of the new process indicates that an energy saving of 12.1% is obtained and the cost savings of 44 million won per day based on gross domestic product is reduced under same total number of trays and the initial investment cost is saved.

Impact of Market, Institution and Technology on the Location of FDI: The Case Study of Korean Samsung CDMA FDI in China (한국 대중국 해외직접투자에 대한 시장, 제도 및 기술의 입지효과 - 한국 삼성 CDMA 대중국 해외직접투자 사례연구 -)

  • Sung-Cheol Lee;Sung-Hoon Jung
    • Journal of the Korean Geographical Society
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    • v.39 no.2
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    • pp.241-255
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    • 2004
  • The main aim of this article is to identify the fundamental reason for changes in the geography of Korean foreign direct investment (FDI) in China. More specifically, the article argues that changes in the industrial sectors and the location of FDI resulted from the transition of strategies for Korean FDI in China since the late 1990s is not based on ownership specific advantages, internalization advantages and locational advantages (OIL), but on changes in site where both the needs of Korea and China are articulated, i.e. the strategy for business integration, centering on market, institution and technology. In other words, changes in the location of Korean FDI in China have been the result of changes in the Chinese market structure, institutional changes in Chinese inward FDI incentives and regulations and the accumulation of Korean technology capability since 2000. In addition, by investigating production networks in China, this article attempts to identify the relationships between changes in Korean FDI location and changes in market, institution and technology. Therefore, the empirical evidence provided by the case study of CDMA (code division multiple access) mobile communications FDI since 2000 in China is used to identify the impact of market, institution and technology on the location of Korean FDI in China.

Study on Energy Performance And Economic Evaluation of Windows System with Built-in Type Blinds (블라인드 내장형 창호시스템의 에너지 성능 및 경제성 평가에 관한 연구)

  • Joe, Won-Hwa;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.2
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    • pp.97-104
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    • 2010
  • This study evaluated the energy efficiency of a windows system using built-in blinds, with regard to their insulation performance and their blocking of solar radiation. The study took advantage of the "Physibel Voltra" program as a physical simulation of heat transfer. To simulate the "Physibel Voltra" program, I practiced a mock-up test to determine heating quality and translation condition. I analyzed the propensity to annual energy consumption, the annual quantity of heat transfer, and the annual cooling and heating cost through a computer simulation for one general household in an apartment building. In the test, it was found that compared to a general windows system, a windows system with built-in blinds reduced the annual heat transfer by 10% in cooling states and by 11% in heating states when the blind was up. When the blind was down, the windows system with built-in blinds reduced the annual heat transfer by 25% in cooling states and 30% in heating states. When a windows system with built-in blinds is compared with a general windows system, the quantity of cooling and heating loads is reduced by 283.3kw in cooling states and 76.3kw in heating states. This leads to a reduction in the required cooling and heating energy of 359.6kw per house. It is thus judged that the use of a windows system with built-in blinds is advantageous in terms of reducing greenhouse gas emissions, because the annual TOE (tons of oil equivalent) per house is reduced by 0.078TOE, while $tCO_2$ is reduced by $0.16tCO_2$. In addition, compared with a general windows system, the cost of cooling and heating loads in the system reduces the annual cooling cost by 100,000won, and the annual heating cost by 50,000won. Ultimately, this means that cooling and heating loads are cut by 150,000won per year.

Determination of Hydraulic Parameters in Unconfined Sandy Aquifer in a Laboratory Scale (실내 자유면 사질 대수층의 수리상수 결정)

  • 김정석;김동주
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.3
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    • pp.152-157
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    • 1999
  • Oil leaked from underwound storage tanks and leachate from sanitary landfills have been known as contaminant sources of the high-quality groundwater resources. The mobility of contaminants in the aquifer largely depends on the groundwater flow and the determination of associated hydraulic parameters is essential for a proper remediation of contaminated grnundwater. This study aimed at determining an optimum set of hydraulic parameters for an unconfined sandy aquifer of a laboratory scale through comparison of various methods. Results showed that the specific yield obtained from gravity drainage experiment was an average of 0.20 with minor variations in aquifer depths. and the permeabilities obtained from Dupuit approximation and slug test gave similar values of 5.33 cm/min and 5.85 cm/min but the constant head method gave 0.17 cm/min, which is much ion than the other methods. This experimental evidence reveals that the permeability of the unconfined sandy aquifer could be accurately determined by Dupuit assumption or slug tut rather than by constant head method conducted for a disturbed separate soil column.

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A Field Study on the Enhancement of Landfarming Performance Using Oil-degradable Microbes Adapted to Various Temperature Range (생장 온도 범위별 최적의 유류분해 미생물을 이용한 토양경작 정화기술의 효율성 제고에 관한 현장 적용성 연구)

  • Yu, Jae-Bong;Kim, Jeong-Ho;Kim, Guk-Jin;Oh, Seung-Taek;Lee, Cheol-Hyo;Park, I-Kyong;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.14 no.5
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    • pp.10-17
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    • 2009
  • Bioremediation has been applied as a proven technology in remediation of TPH contaminated soil. However, the efficiency of biodegradation is dependent on temperature as microbial activity is depressed at lower temperature ranges ($30^{\circ}C{\sim}80^{\circ}C$). The objective of this study was to develop microbes with enhanced activities at the stated temperature conditions and to evaluate the remediation effectiveness of these microbes in TPH contaminated soil. Experiments were conducted to isolate hydrocarbon degradable microbial consortia cultured under different temperature conditions. It was found that there were 5 strains of mesophilic ($30^{\circ}C$) and 3 strains of psychrophilic ($80^{\circ}C$) microbes. The TPH concentration was reduced from 4,044 mg/kg to 1,084 mg/kg, (73.2%) in 10 days by using mesophilic microbial consortia and from 5,427 mg/kg to 1,756 (67.6%) in 50 days with psychrophilic microbial consortia in laboratory cultures under controlled conditions. This rate determination excluded physical degradation such as venting and dilution. A field study was then performed to examine the feasibility of applying these microbes in the land-farming process. In this case, 87.1% of the 2,560 mg/kg TPH contaminated soil was degraded in 56 days. The biodegradation rate coefficient (k) was $0.0374\;day^{-1}$. Findings of this study provide viable options for applying microbes for bioremediation of TPH in lower temperature conditions.

Study on Analysis of manufacturing technique and Materials used for Lacquerware artifacts with focus on Joseon Dynasty Records, Uigwe (조선왕실 의궤를 통해 본 옻칠 공예품 제작 방법 및 사용 재료 연구)

  • Kim, Jin Ok
    • 보존과학연구
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    • s.32
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    • pp.53-60
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    • 2011
  • The aim of this study is to investigate the traditional manufacturing technique of lacquering by comparing and analyzing materials used for wooden lacquerware artifacts with focus on the Joseon dynasty Eugye, and to apply the manufacturing technique to the conservation treatment of the lacquerware. artifacts. This study conducted the documentary survey focusing on "Yongjo Jeongsun Queen Consort Garye Dogam Eugye",and "Jeongjo Gukjang Dogam Eugye." The royal lacquering is roughly classified into three categories-scarlet lacquering, quality black lacquering, and terra rosa lacquering- according to materials used for lacquerware. The bean flour was mostly used for under lacquering of the articles which was offered to the king and in case of other articles, bean flour was used mixed with bone ashes. In some cases, burned pine soot was added to under lacquering. Japanese scarlet lacquering was applied by mixing maechil-main coat, in inverted commas- with Japenese scarlet after lacquering jeonchil-base coat, in inverted commas-. In case of Chinese scarlet lacquering, part of terra rosa was used mixed with red clay. For quality black lacquering, basically jeonchil and maechil were used, but sometimes part of burned pine soot was added. In addition, terra rosa lacquering was applied by basically using terra rosa mixed with red clay. Lastly, gloss was given by using perilla oil. It is expected that the traditional materials and technique examined through both documentary and relic research will contribute to advanced result of the conservation treatment of wooden lacqueringware artifacts.

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