• Title/Summary/Keyword: OIL

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The Study on the Thermal Oxidation of Mixed Rapeseed Oil with Coconut and Palm Oil (혼합 유채유의 가열산화에 관한 연구)

  • 현영희
    • The Korean Journal of Food And Nutrition
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    • v.15 no.4
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    • pp.342-349
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    • 2002
  • Rapeseed oil is easily oxidized due to the high contents of unsaturated fatty acid such as linoleic acid and linolenic acid. For stability of rapeseed oil oxidation, a special process is required. Two kind of simple and interesterifying mixed rapeseed oil were prepared according to add 30%, 50% and 70% of coconut oil and palm oil. Sample oils were heated at 180${\pm}$5$^{\circ}C$ for 5, 10, 15, 20, 25, 30 and 35 hours. Then the physicochemical properties such as the tendency of oxidation were investigated. The initial AV and POV of interesterifying mixed rapeseed oil were higher than those of simple mixed oil. But the tendency of oxidation were similar. While oxidation rate of similar and interesterifying mixed rapeseed oils with coconut oil and palm oil were lower about than those of rapeseed oil.

Evaluation of Dispersant Application to Stranded Oil as a Clean-up Technique at Sandy Tidal Flat (사질 조간대 표착유의 방제를 위한 유화분산제의 적용 평가)

  • Cheong, Cheong-Jo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.227-231
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    • 2008
  • The purpose of this study is to clarify the behavior of stranded crude oil and to estimate the restoration of seawater infiltration by application of dispersant as one of cleaning techniques. We made visualization of infiltration process of seawater and stranded crude oil on the sandy beach sediments by using of a model sandy beach. Major conclusions derived from this study are as follows. The seawater infiltration volume was reduced by the stranded crude oil. However, thirty percentage of the sweater infiltration into the sediments was restored by dispersant application to the penetrated oil in sandy beach. The penetration depth of stranded oil were dropped at first falling tide, but were not significantly fluctuated after that. Moreover, oil concentration was most high within the upper 2 cm. The stranded crude oil was broken into small size droplets and dispersed into the sediments by the dispersant application. Therefore, dispersant applications play an important roles in the large increase of surface area of given volume of oil, and it resulted in promoting to biological degradation process at the oil/water interface, dispersing the stranded oil into the water column and restoration of the supplement of the dissolved oxygen and nutrients to the benthic organisms.

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An Optimal Design of Gas Lift in Offshore Oil Reservoirs Considering Oil and Injected Gas Composition (해저 오일 저류층 내 오일 및 주입가스 조성에 따른 가스리프트 공법의 최적 설계)

  • Kim, Young-Min;Shin, Chang-Hoon;Lee, Jeong-Hwan
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.39-48
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    • 2018
  • This study presents optimal design of gas lift considering composition of reservoir oil and injected gas which can affect gas lift performance in offshore oil reservoir. Reservoir simulation was conducted by using reservoir models which were built in accordance with API gravity of oil. The results of simulation reveal that oil production rate is considerably increased by gas lift when the reservoir productivity decrease. As a results of response curve analysis for gas lift using well models, gas injection rate to improve the production rate increases as the API gravity of oil decreases and the specific gravity of injected gas increases. The optimal design of gas lift was carried out using multiple lift valves. Consequently, gas lift can be operated at relatively low injection pressure because of decrease in injection depth in comparison to the single lift valve design. The improved oil production rates were analyzed by coupling between reservoir model and well model. As a results of the coupling, it is expected that natural gas injection in the heavy oil reservoir is the most efficient method for improving oil production by gas lift.

Effect of n-6, n-3 Fatty Acids and Vitamin A Levels on Humoral Immunity in Rats (n-6, n-3 지방산과 비타민 A 수준이 흰쥐의 체액면역에 미치는 영향)

  • Kim Suh Hae
    • Journal of Nutrition and Health
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    • v.25 no.6
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    • pp.468-475
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    • 1992
  • This study was carried out to observe the effects of dietaryn-6, n-3 fatty acids and vitamin A levels on humoral immunity in rat. Sixty eight male Sprague-Dawley rats were fed 6 different experimental diets for 6 weeks. The diets were composed of 10% of either corn oil or fish oil with various levels of vitamin A ; deficient(12450 IU/kg diet) adequate(4000IU/kg diet) and excess(400,000 IU/kg diet) The weight of spleen from the excess vitamin A-fish oil group showed the lowest value of all the groups when spleen weight was expressed/100g body weight. The number of PFC to SRBC was not affected by dietary at type and vitamin A levels. Hemagglutination titers were significantly lower in fish oil groups compared to corn oil groups and the values of vitamin A deficient groups were lower than the ones of adequate and excess vitamin A groups. IgM contents is serum were significantly lower in fish oil groups than in corn oil groups. IgG contents were higher in fish oil groups than in corn oil groups and the highest levels was recorded in excess vitamin A-fish oil group which showed the smallest speen size. Light microscopical examination showed that spleen tissues of fish oil groups were well developed than those of the corn oil groups and vitamin A deficient and excessive groups showed poor development than the adequate groups. Therefore it is suggested that adequate amounts of vitamin A consumption is necessary for healthy individuals and fish oil intake along with excess vitamin A should be avoided in order to maintain immune function properly.

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The Effect of Soybean Oil and Waste Chicken Oil Mixing Ratio on Biodiesel Characteristics (대두유와 폐계유의 혼합비가 바이오디젤 특성에 미치는 영향)

  • Kwack, Jong Won;Kim, Tae Han
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.261-267
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    • 2017
  • The interest in biodiesel is increasing rapidly. As a result, the price of vegetable oil that is used as a raw material for biodiesel is skyrocketing. Studies of biodiesel using animal waste as a means of solving these problems are underway. Biodiesel produced from animal fat contains considerably more saturated fatty acids than that produced from vegetable oil. In addition, it has a high cetane number and a high heating value. On the other hand, the fluidity decreases at lower temperatures because of the large amount of saturated fatty acids. For the biodiesel production, waste chicken oil and soybean oil were first purified. The raw materials were mixed at various ratios from 1:9 to 9:1. The methanol / oil molar ratio was also changed from 7 mol to 15 mol. The entire reaction time was one hour. The results showed that the optimal mixing ratio of soybean oil to waste chicken oil was 3:7, and the optimal methanol / oil molar ratio was 13. Moreover, the BD yield was 90.2%, the FAME content was 96.6%, and the LAME content was 4.1%. This result satisfied the Korea Industrial Standard (KSM2413).

Analysis of Free Fatty Acid Formation and Oxidative Rancidity for Deep Flying Oil Produced by Traditional and Modified Fryers (전통식과 개량식 튀김기에 대한 튀김기름의 유리지방산 생성 및 산패도 측정 비교)

  • Choi, Il-Sook;Choi, Soo-Keun;Lee, Young-Soon
    • Culinary science and hospitality research
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    • v.17 no.4
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    • pp.316-325
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    • 2011
  • The property of deep frying oil is one of die important factors in fried food quality. The purpose of this study is to identify die quality of deep frying oil in continuous usages for 4 days by two types of fryers: traditional and modified fryers. After frying polk cutlets, die flying oil was kept not only for several physical analyses such as color, viscosity, and water content but also for quality analyses of flying oil such as free fatty acid, double bond changes and oxidative rancidity formation. The fried oil by a traditional flyer was significantly increased in die physical values of color and viscosity than that by a modified fryer. In die acid value, the fried oil by a traditional fryer was significantly increased in free fatty acid than that by a modified fryer while die iodine value was significantly decreased in die fried oil by a traditional fryer when compared to control oil and fried oil by a modified fryer. In die peroxide value as an indicator of primary oxidation products, die fried oil by both fryers was significantly increased till die second day but decreased in die value after die third day because of unstable hydroperoxides' decomposition. In die p-anicidine value as an indicator of secondary oxidation products, die fried oil in a traditional fryer was significantly increased in die value than that in a modified fry.

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Wax Appearance Temperature Measurement of Opaque Oil for Flow Assurance in Subsea Petroleum Production System (해저 석유 생산시스템 내 유동안정성 확보를 위한 불투명 오일의 왁스생성온도 측정법)

  • Lim, Jong-Se;Back, Seung-Young;Kang, Pan-Sang;Yul, Seung-Ryul;Kim, Hyo-Sang;Park, Ji-Hong
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.1
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    • pp.185-194
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    • 2012
  • Deepwater oil is becoming more attractive because most onshore and shallow water oil is developing or developed. With the on-going trend to deepwater oil developments, flow assurance problems which prevent oil flow from reservoir to processing facilities are becoming an issue because deposited material can be occurred in case oil is exposed to very different environment from reservoir. Wax deposition which is one of flow assurance problems can be a major technical and economic issue because it is very sensitive to temperature. In order to predict and mitigate wax problems, the precise measurement of wax appearance temperature (WAT) which is the starting temperature of wax precipitation is very important. Various methods have been suggested for WAT measurement of opaque oil because there is no standard method for opaque oil. In this study, the WAT of opaque oil samples was measured using viscosity measurement method, differential scanning calorimetry, filter plugging method, and pressurized filter plugging method. Wax deposition test and high temperature gas chromatography analysis were applied to verify measured WAT. As a result of study, the WAT of opaque oils was successfully measured and verified. If WAT measurement methods of opaque oil related to oil characteristics is systematized using the results of this study, it can be a valuable tool for WAT measurement of opaque oil and flow assurance related to wax deposition.

Characteristics on the Removal of Emulsified Vegetable Oil in Wastewater using Bio logical Fluidized Bed (생물학적(生物學的) 유동층(流動層)을 이용(利用)한 수중(水中)의 식물성유(植物性油) 제거특성(除去特性))

  • Kim, Hwan Gi;Park, Ro Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.3
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    • pp.127-136
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    • 1990
  • In this paper, the experimental study was carried out for the removal of olive oil in wastewater by the use of Biological Fluidized Bed(BFB) with the reticulated polypropylene sheets as media. The nonbiodegradable olive oil, one of the animal and vegitable oil, was used bacause of the relative simplicity of constitution. Biological degraciability and removal characteristics of emulsified olive oil were studied by batch and continuous experiments respectively. From the results of batch experiments, it was observed that the emulsified olive oli used in BFB reactor was absorbed by media and sludge in about 12 hours, and degradation of the absorbed olive oli was mostly completed for 24 hours. The functional relationship of Michaelis-Menten's Enzyme reaction equation exists between oil concentration and maximum specific rate of olive oil. From the continuous experiments for the removal of olive oil using BFB reactor, it was proved that the substrate removal rate coefficient $k=0.004d^{-1}$, which is the first order kinetics. It was apperared that oxygen utlization coefficients for synthesis(a') and endogeneous respiration(b') of microorganisms in the reactor are respectively 0.85mg $O_2/mg$ $COD_{cr}$ and 0.011mg $O_2/mg$ BVS. day.

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The Antioxidative Activities of Spices Extracts on Edible Soybean Oil (식용대두유에 대한 향신료 추출물의 항산화작용)

  • Ji, Cheong-Il;Byun, Han-Seok;Kang, Jin-Hoon;Lee, Tae-Gee;Kim, Seon-Bong;Park, Yeung-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.5
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    • pp.551-556
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    • 1992
  • To develop natural antioxidant from spices and control thermal oxidation of edible soybean oil, the available antioxidative compounds of various spices were extracted with edible soybean oil. The storage stability of the oil mixed with purified sardine oil and soybean oil containing that extracts at $37^{\circ}C$ were investigated. Furthermore the antioxidative activity of petroleum ether soluble fractions(PESF) obtained from rosemary on the thermal oxidation of edible soybean oil during heating at $180^{\circ}C$ were also investigated. By mixing with refined sardine oil and soybean oil extracts of rosemary, sage of herb spices and mace of seed spices, the oxidative stabilities were remarkably increased. The thermal oxidation of edible soybean oil was also supressed by the addition of 1.0%(w/w) of PESF obtained from rosemary. Rosemary extract exhibited higher antioxidative activity on thermal oxidation of edible soybean oil than butylated hydroxytoluene.

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Oil Absorptive Properties of Polypropylene Knit Fabric Treated with Oleophilic Acrylic Resin (친유성 아크릴 수지로 처리된 폴리프로필렌 편직물의 유흡착 성질)

  • Jeong, Hwa-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.528-535
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    • 2016
  • Two types of oleophilic acrylic prepolymers were prepared by the solution copolymerization of either ethyl acrylate (EA) or lauryl acrylate (LA) with hydroxy ethyl acrylate (HEA). For the formation of oil-absorbent materials, a mixed solution of the prepolymer and hexamethylene diisocyanate (HDI) as a cross-linker in toluene was applied to polypropylene knit velvet fabric through the conventional pad-dry-cure procedure. The gel fraction of the crosslinked resin, EA-HEA-HDI, increased with increasing feed ratio of HEA to total acrylate or HDI concentration. The oil absorbancy and retention ratio of the prepared materials were compared according to the add-on ratio of resin to fabric, and were assessed with n-decane, toluene, soybean oil, lubricant and bunker C oil as test oils. The optimal oil absorbancy of the materials were observed at around 6% of the add-on ratio for all these oils except for soybean oil. On the other hand, the oil retention ratio increased as the add-on ratio increased. Futhermore, heavier and more viscous oil generally showed higher oil retention ratios. In addition, the oil absorbancy of the materials treated with LA-HEA-HDI resin was higher than that treated with EA-HEA-HDI resin, which showed that the acrylic resins are more absorptive with increasing length of their side alkyl chain.