• Title/Summary/Keyword: OH stretching

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Meta-analysis on the Effects of Exercise Therapy and Physiotherapy on Pain in Korean Patients with Chronic Low Back Pain (만성요통환자를 대상으로 운동치료 및 물리치료가 통증에 미치는 효과에 대한 메타분석)

  • Kim, Sung-Kyu;Lim, Bee-Oh
    • Korean Journal of Applied Biomechanics
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    • v.30 no.1
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    • pp.63-72
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    • 2020
  • Objective: The purpose of this study was to investigate meta-analysis on the effects of exercise therapy and physiotherapy on pain in korean patients with chronic low back pain. Method: Meta-analysis was performed on the type and method of treatment. A total of 23 experimental studies were coding into 31 individual studies, into types, methods, visual analogue scale (VAS), each pre/post value of the effect size was calculated by meta-analysis. Results: Sling exercise, stretching, thermal therapy, kinesio-taping, lumbar stabilization exercise, electrotherapy is large effect size (ES ≥ .08). In addition, big effects occurred in order of treatment period is more than 9 weeks, three times a week. Conclusion: Our results indicated that persistent treatment of chronic back pain is the most effective method of self-sufficiency rather than temporary relief.

FTIR Spectroscopic Analysis of Structural Changes of Cellulosic Fibres During Papermaking Process

  • Kim, Hyoung-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.2
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    • pp.51-58
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    • 1998
  • Structural changes of cellulosic fibres during the papermaking process were studied by analysis of FTIR spectra collected by the transmission method. The spectra were obtained from a carefully prepared handsheet, using a special infra-red (IR) cell suitable for evacuating the sample. The deconvolution technique was also applied for sharpening the FTIR spectra in the frequency range of the OH and CH stretching bands, which gave detailed information on the structural changes of cellulose. The intensity of some bands was decreased by predrying the sample as a result of the removal of adsorbed moisture. An increase in intensity of some bands in the frequency range of 3700 to $3200cm^{-1}$ was shown at a higher beating level. This increase in intensity was caused by changes in the crystal domain of cellulose resulting from the exposure of the crystalline area on the fibre surface.

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An Investigation on the Formation Characteristics of a Single Vortex Interacting with Counterflow Nonpremixed Flame (대향류 비예혼합화염과 상호작용하는 단일 와동의 생성특성에 관한 연구)

  • Yoo, Byung-Hun;Oh, Chang-Bo;Hwang, Chul-Hong;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.49-56
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    • 2002
  • A two-dimensional direct numerical simulation is performed to investigate the formation characteristics of a single vortex interacting with $CH_4/N_2$-Air counterflow nonpremixed flame. The numerical method was based on a predictor-corrector scheme for a low Mach number flow. The detailed transport properties and a 16-step augmented reduced mechanism are adopted in this calculation. The budgets of the vorticity transport equation arc examined to reveal the mechanisms leading to the formation, evolution and dissipation of a single vortex interacting with counterflow nonpremixed flame. It is found that the stretching term, which depends on the azimuthal component of vorticity, and radial velocity, mainly generates vortieitv in non-reacting and reacting flows. The viscous and baroclinic torque term destroy the vorticity in non-reacting flow. In addition, the baroclinic torque term due to density and pressure gradient generates vorticity, while viscous and the volumetric expansion terms due to density gradient destroy vorticity in reacting flow.

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Fabrication of Stretchable Transparent Electrodes

  • Oh, Jong Sik;Yeom, Geun Young
    • Applied Science and Convergence Technology
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    • v.26 no.6
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    • pp.149-156
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    • 2017
  • Recently, stretchable and transparent electrodes have received great attention owing to their potential for realizing wearable electronics. Unlike the traditional transparent electrodes represented by indium tin oxide (ITO), stretchable and transparent electrodes are able to maintain their electrical and mechanical properties even under stretching stress. Lots of research efforts have been dedicated to the development of stretchable and transparent electrodes since they represent the most important engineering platform for the production of wearable electronics. Various approaches using silver nanowires, nanostructured networks, conductive polymers, and carbon-based electrodes have been explored by many world leading research groups. In this review, present and recent advances in the fabrication methods of stretchable and transparent electrodes are discussed.

FT-IR Spectroscopic Characterization of Oxidized and Reduced Titania

  • Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.396-399
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    • 1990
  • Fourier transform infrared spectroscopy has been applied to the characterization of titania surface. The bands due to surface OH groups were observed to be more intense in the reduced titania than in the oxidized titania. The IR spectra of CO adsorbed on titania exhibited two C-O stretching bands, namely at 2187 and 2209 cm$^{-1}$. The intensities were stronger in the oxidized titania.The 2187 cm$^{-1}$-peak was attributed to CO coordinated to $Ti^{4+}_{5c}$ (subscriptindicates the coordination number of the coordinatively unsaturated cation by oxygen ions), while the 2209 cm-1-peak due to the $Ti^{4+}_{4c}{\cdots}$CO complex.

Synthesis and Properties of Organosilicon Polymers Containing 3,4-Benzo-1-silacyclopentene Derivatives

  • 박영태;박상욱;김호창;이광
    • Bulletin of the Korean Chemical Society
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    • v.19 no.3
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    • pp.328-332
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    • 1998
  • Anionic ring-opening polymerization of 3,4-[(dimethylsilyl)isopropyl]benzo-1,1-dimethyl-1-silacyclopentene in the presence of n-butyllithium and HMPA in THF at - 78 ℃ afforded poly[3,4-(dimethylsilylisopropyl)benzo-1,1-dimethyl-1-silapentene]. The characteristic Si-H stretching frequency in the IR is observed at 2100 cm-1. The polycarbosilane has been modified by chloroplatinic acid catalyzed addition of styrene to the polycarbosilane SiH units. Molecular weights and thermal properties of the polymers were compared. The sol-gel polymerization of 3,4-[(dimethoxysilyl)isopropyl]benzo-1,1-dimethoxy-1-silacyclopentene in the presence of aqueous HCl or NaOH in THF resulted in a cross-linked polysiloxane. The xerogel has a low surface area of 13-14 m2/g and is stable up to about 400 ℃ with only 5% weight loss under a nitrogen atmosphere.

Geochemistry of Mn Scales Formed in Groundwater in the Damyang Area (담양 지역 음용 지하수에 형성된 망간 스케일에 대한 지구화학)

  • Park, Cheon-Young;Kim, Seoung-Ku;Shin, In-Hyun;Ahan, Kun-Sang;Kim, Young-In
    • Journal of the Korean earth science society
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    • v.27 no.3
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    • pp.313-327
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    • 2006
  • This study investigated the geochernical characteristics of Mn scale formed in groundwater wells at the Damyang area. The composition of Mn scale consists mainly of MnO and $SiO_2$. The content of Mn ranges from56.61wt.% to 68.69wt.%, and $SiO_2$ content ranges from 1.56wt.% to 10.45wt.%. The contents of Mo and Ba in Mn scale increased with increased depth; whereas, the content of Zn and Pb decreased with increased depth. Birnessite, quartz and feldspars were identified in Mn scales using x-ray powder diffraction studies. The IR absorption bands for Mn scales show major absorption band due to OH stretching, adsorbed molecular water, and birnessite stretching, respectively. In the SEM and EDS analysis, the Mn scale consists of botryoidal, spherical, spherulite, and empty straw structure. Those structure may be precipitated simply due to oversaturation with concentrated Mn content or may be formed through biogenic precipitation by Lepthothrix discophora. Under microanalysis using EDS on those structure surface of Mn scales, the Mn atomic percent range from 28 to 44, and such elements revealed the presence of Si, K, Na, Ca, Cl, Cu, Zn, and Ba.

Characteristics of Kenaf Fibers Treated by Alkali (알칼리 처리에 따른 케나프 섬유의 특성 변화 연구)

  • Yoo, Hye-Ja;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.8
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    • pp.982-990
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    • 2011
  • Kenaf fiber can be obtained by decortications of the kenaf plant stem. The properties of the kenaf fiber treated by alkali (NaOH) were investigated by spectrocolorimeter, SEM, X-ray diffractometer, FT-IR and TGA. The kenaf fibers treated by alkali became darker and their Munsell color values changed from Y (yellow) to YR (yellowred) according to an increased NaOH concentration. SEM observation of the kenaf fibers showed that their crimps were developed and their surfaces were cleaned by the removal of protruding ends and impurities after alkali treatments. In the x-ray diffraction analysis, the structures of the fibers were found in the form of cellulose I when treated with a 0-16% alkali concentration and cellulose II when treated with over 20%. It was also confirmed that the crystallinity was lowered according to an increased NaOH concentration. The change of fiber compositions was investigated in FT-IR analysis. Strong band of $1,738cm^{-1}$ and asymmetrical stretching strong bands of $1,630-1,600cm^{-1}$ in spectrum (which represent pectin) were not found in the samples because the pectin was removed by the alkali treatment. Weak bands of $1,728-1,730cm^{-1}$ and peaks of $1,245-1,259cm^{-1}$ (which represent hemicellulose) and peaks of $1,592cm^{-1}$, $1,504cm^{-1}$, $1,462cm^{-1}$ and $1,429cm^{-1}$ (which are related to lignin) were not found or reduced in the samples treated with a concentration over 20%. TGA indicated that the kenaf fiber had the better hydrophilic properties by alkali treatment. The higher Tmax in TGA and the higher thermal stability when treated by alkali with the higher concentration. The fibers treated with an alkali concentration over 30% did not show any changes in Tmax.

Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice II. Effects of Paper Sludge Application on the Seasonal Variations of Humus in Paddy Soil (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響) II. 토양중(土壤中) 부식형태(腐植形態)에 미치는 슬러지의 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik
    • Korean Journal of Environmental Agriculture
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    • v.5 no.1
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    • pp.1-10
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    • 1986
  • To investigate the effects of paper sludge on the seasonal variations of soil humus, paper sludges were applied to the pots at the rates of 600㎏/10a which was either preadjusted C/N ratio to 30 : 1 or not adjusted. The effects were compared with those of control. 1) The contents of ether soluble materials, resins, water soluble polysaccharides, hemicellulose, cellulose, ligno-protein, humic acid and fulvic acid were higher in the sludge treated soil than in the control, furthermore, the content of ligno-protein had positive correlation with that of organic nitrogen in soil. 2) Optical density of UV and visible spectra of humic acid obtained from all the treated soil was decreased with increasing wavelength. In functional groups of humic acid, phenolic-OH/alcoholic-OH ratio was slightly higher in the sludge treated soil than in the control. The types of humic acid in all treated soil were P and Rp types. 3) The infrared spectra of humic acid extracted from the soil were characterized by main absorption bands in the regions of $3, 400cm^{-1}$(H-bonded OH), $2,900cm^{-1}$ (aliphatic C-H stretching), $1,630cm^{-1}$ (aromatic C=C and/or H-bonded C=O) and $1,050cm^{-1}$ (Si-O of silicate impurity).

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Process Development of Constant Curvature Extrusion for Aluminum Alloy (알루미늄 합금의 일정 곡률 압출공정 개발)

  • Joe, Y.J.;Lee, S.K.;Oh, K.H.;Park, S.W.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.16 no.7
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    • pp.555-560
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    • 2007
  • This paper shows some achievements at bending of extruded aluminum profiles during the extrusion process. The conventional process for the production of bent profiles involves a successive extrusion, stretching, and bending of the profiles. Conventional bending methods can not meet demands far precision and cost-effective production in some cases, due to cross sectional deformation, irregular decrease of tube wall thickness and a complication of the process design. An estimation of spring-back required for precision of the bending radius can not always be achieved by the over bending of the profile. Since the profile is hot during the bending process, the spring-back phenomenon can be avoided. This means that an additional bending process is not necessary. Consequently, flexible bending can be achieved with cost reduction and quality improvement. Experimental tests were completed to study the relationship between curvature radius of profile and position of guide on the extrusion for vehicle bumper. A7108 is applied as a billet material in order to increase strength. The overall correlation between the experimental and numerical results is good. It is therefore concluded that the present method provides an efficient means for the constant curvature extrusion process.