• Title/Summary/Keyword: OH Chemiluminescence

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Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Lee, Jong-Ho;Kim, Dae-Hyun;Jeon, Hung-Hwan;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.4
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    • pp.425-432
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    • 2004
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence(OH$\^$*/) image and its Abel inverted image to investigate the flame structure at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure and NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ∼341.8㎐, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between OH$\^$*/ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

Effect of Oxygen Enriched Air on the Combustion Characteristics in a Coaxial Non-Premixed Jet (II) - Flame Structure and Temperature Distribution - (산소부화공기가 동축 비예혼합 제트의 연소특성에 미치는 영향 (II) - 화염의 구조와 온도분포 -)

  • Kwark, Ji-Hyun;Jeon, Chung-Hwan;Jang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.2
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    • pp.223-229
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    • 2004
  • Combustion using oxygen enriched air is known as a technology which can increase thermal efficiency due to increase of the flame temperature. Flame shapes, schlieren photos, OH radical chemiluminescence and local flame temperature were examined as a function of OEC(Oxygen Enriched Concentration) in a coaxial non-premixed jet. With increase of OEC, flame length and width decreased, but its brightness increased significantly, and the size of vortices in the flame also increased. Especially, the reaction around the flame surface became active. The strong OH intensity appeared to be made and moved from middle stream to upper one with increase of OEC, which shows combustion reaction in the upper stream becomes more dominant In addition, the temperature distributions of the flames showed similar tendency with OH radical intensities. A flame with high temperature and strong stability was obtained with increasing OEC of the coflow.

Scavenging Effects of Tea Catechins on Superoxide and Hydroxy Radical

  • Park, Jaeil;Chen, Liuji;Yang, Xianqiang;Shen, Shengrong;Wang, Yuefei;Ho, Ryu-Beung
    • Journal of Life Science
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    • v.12 no.2
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    • pp.75-79
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    • 2002
  • Tea catechins, the most important compounds in tea polyphenols, can efficiently scavenge superoxide anion free-radical ($O_2$.), hydroxyl radical. (.OH) The mechanism of scavenging active oxygen free radicals was investigated by ESR spin trapping technique and Chemiluminescence. Results showed that various tea catechins constitute an antioxidant cycle in accordance with the decreasing order of the first reductive potential, and produce the effect of cooperative strength each other. Esterificated catechins could scavenge active oxygen free radicals more effectively than the non-esterificated ones. When.OH and $O_2$.- were scavenged by (-)-epigallocatechin gallate [(-)- EGCG], the stoichiometric factors were 6, and the rate constants of scavenging reaction reached $7.71{\times}10^6$ and $3.52{\times}10^{11}$ L $mmol^{-1}s^{-1}$, respectively. In the mean time, tea catechins could scavenge superoxide anion fiee radical ($O_2$-.) and hydroxyl radical (.OH) in a dose dependent manner. But at higher concentration or pH value, tea catechins can induce the prooxidant.

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Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.356-361
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    • 2003
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence ($OH{\ast}$) image and its Abel inversion image at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure. Also NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ${\sim}341.8$ Hz, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between $OH{\ast}$ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

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The Study of Effects of Variable Parameters on Flame Structure and NOx Emission in Methane/Air Laminar Partially Premixed Flames (메탄/공기 층류 부분 예혼합화염에서 예혼합 정도에 따른 화염구조와 질소산화물의 배출에 미치는 영향에 관한 연구)

  • Oh, Jeong-Seog;Jeong, Yong-Ki;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.362-367
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    • 2003
  • It is shown that the effect of variable parameters on flame structures and NOx emissions in the laminar partially premixed methane-air flames with a co-axial Bunsen burner. Objectives of this paper is to understand the effects of flow variables on NOx emissions and the flame structure with OH chemiluminescence, including reconstructed image by abel inversion processing at each conditions. A fuel flowrate of 200 [cc/min] was fixed and the amount of air was varied from 400 to 1200 [cc/min]. The experimental variables were equivalence ratio(${\Phi}$ fuel split percentage(${\sigma}$ and inner tube recess(x/D). Flow conditions were ranged from $1.36{\sim}4.76$(equivalence ratio), $50{\sim}100$(fuel split percentage) and $0{\sim}20$(inner tube recess). NOx analyzer and ICCD camera with a OH filter were used as a main experimental apparatus. In addition, Abel inversion, which is a kind of tomography and valuable to estimate a two-dimensional structure of co-axial flames from cubical information, was employed for combustion diagnostics. Results from this study indicate that the main effects depend on equivalence ratio and next sigma, x/D for NOx production and OH formation. Throughout Abel inversion, we could affirm the maximum position and the tendency of OH radical intensity by variants at five axial heights above the burner exit.

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Effect of Kamidaebo-tang on Murine Peritoneal Macrophages (가미대보탕이 생쥐의 복강 Macrophages에 미치는 영향)

  • Song Jung Mo;Oh Chan Ho;So June No;Kim Dae Keun;Eun Jae Soon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.5
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    • pp.1020-1024
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    • 2002
  • The purpose of this research was to investigate the effects of Kamidaebo-tang water extract (KDT) on murine peritoneal macrophages. KDT (50 or 250 mg/kg) was administerd p.o. once a day for 7 days to mice. KDT increased the production of tumor necrosis factor-α and nitric oxide from murine peritoneal macrophages, but decreased the production of interleukin-1β. Also, KDT enhanced the production of lucigenin chemiluminescence from peritoneal macrophages. These results suggest that KDT enhances the non-specific immune response via increase of tumor necrosis factor-α and nitric oxide and phagocytic activity from peritoneal macrophages.

A Study on Response Characteristics of Jet-diffusion Flame and Premixed Flame with Various Velocity Perturbations (제트확산화염과 예혼합화염의 다양한 속도 섭동에 대한 응답 특성)

  • Ahn, Myunggeun;Kim, Taesung;Kim, Heuydong;Yoon, Youngbin
    • Journal of the Korean Society of Combustion
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    • v.22 no.2
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    • pp.19-26
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    • 2017
  • An experimental study investigates the flame response characteristics of jet-diffusion flame and premixed flame. The experiment was conducted while varying the amplitude. Flame lengths were quantified for OH chemiluminescence measurement and compared with the result of the flame transfer function. Flame length and flame velocity perturbation were normalized and compared with the result of the flame transfer function. The comparison results appear that velocity perturbation and flame length oscillation of premixed flame show linear behaviors on the other hand jet-diffusion flame, amplitudes are more thant 0.20, shows nonlinear behaviors of flame velocity perturbation and flame length oscillation.

Experimental Study on the Characteristics of Lifted Flames in Laminar Coflow Jets of Propane (층류 프로판 동축류 제트에서 부상화염의 특성에 관한 실험적 연구)

  • Lee, J.;Won, S.H.;Jin, S.H.;Chung, S.H.
    • Journal of the Korean Society of Combustion
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    • v.7 no.3
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    • pp.37-46
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    • 2002
  • Characteristics of lifted flames in axisymmetric laminar coflow jets have been investigated experimentally. Approximate solutions for velocity and concentration accounting virtual origins have been proposed for coflow jets to analyze the behavior of liftoff height. From the measurement of Rayleigh intensity for probing the concentration field of propane, the validity of the approximate solutions was substantiated. From the images of OH PLIF and CH chemiluminescence and the Rayleigh concentration measurement, it has been shown that the positions of maximum luminosity in direct photography coincide with the tribrachial points, which were located along the stoichiometric contour. The liftoff height in coflow jets was found to increase highly nonlinearly with jet velocity and was sensitive to coflow velocity.

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Effect of Glycyrrhizin on Lymphocytes Subpopulation Change of L1210 cells-transplanted Mice (글리시르히진이 L1210세포를 이식한 생쥐의 Lymphocytes Subpopulation 변화에 미치는 영향)

  • Eun, Jae-Soon;Yum, Jung-Yul;Jeon, Hoon;Oh, Chan-Ho
    • YAKHAK HOEJI
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    • v.44 no.6
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    • pp.566-571
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    • 2000
  • We have previously observed that glycyrrhizin(GL) inhibits the proliferation of transplanted-L1210 cells via the production of nitric oxide from peritoneal macrophages. In the present study, we examined the effect of GL on Iymphocytes subpopulation change of L1210 cells-transplanted mice. GL increased the population of $CD4^-CD8^+$ cells of thymocytes in L1210 cells-transplanted mice and the lucigenin chemiluminescence of human polymorphonuclear cells. These results suggest that the proliferation of transplanted-L1210 cells is partly inhibited by an enhancement of cytotoxic T cells population and phagocytic activity in GL-administered mice.

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An Experimental Study on the Combustion Characteristics with Hydrogen Enrichment in a Dump Combustor (수소 혼합에 따른 덤프 연소기내의 연소 특성에 관한 실험적 연구)

  • Kim, Dae-Hee;Hong, Jung-Goo;Shin, Hyun-Dong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2977-2983
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    • 2008
  • The combustion characteristics of a partially premixed flame in a dump combustor were studied to determine the effects of hydrogen enrichment in propane. Bluff-body was used for flame stabilization. Fuel mixtures containing a hydrogen mole fraction ranging from 0.1 to 0.5 were burnt at ambient pressure within a quartz chamber. Tests were carried out keeping the total reactant flow rate by adjusting the fuel and air flow rates. The fluctuations of pressure were measured by piezoelectric pressure sensor. The instantaneous flame structure and OH chemiluminescence images were described by High-speed Intensified Charged Coupled Device (HICCD) camera and Intensified Charged Coupled Device (ICCD) camera. The present results show that hydrogen enrichment in fuel changed the location of primary reaction zone from inner recirculation zone to turbulent shear layer and pressure signal. The reason is that chemical aspects take precedence over flow aspects in the hydrogen-enriched flame.

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