• 제목/요약/키워드: O3 effects

검색결과 6,458건 처리시간 0.033초

Sol-Gel법에 의한 Al2O3-ZrO2계 분말제조에 있어서 결정화 및 Seeding 효과 (Effects of Crystallization and Seeding on Characteristics of Al2O3-ZrO2 Powder Prepared by a Sol-Gel Method)

  • 오한석;홍기곤;이홍림
    • 한국세라믹학회지
    • /
    • 제25권4호
    • /
    • pp.373-379
    • /
    • 1988
  • $\alpha$-Al2O3-15m/o ZrO2 powder was prepared by a sol-gel method from boehmite and zirconium acetate. The transformation temperature of boehmite to $\alpha$-Al2O3 in the system Al2O3-ZrO2 was increased due to the coupled crystallization. On the other hand, the transformation temperature from boehmite to $\alpha$-Al2O3-15m/o ZrO2 could be prepared at 110$0^{\circ}C$ for 100min. The specific surface area of the product of $\alpha$-Al2O3-15m/o ZrO2 was 13.2$m^2$/g.

  • PDF

$YMnO_3$ 강유전 박막의 열처리 분위기가 결정화거동과 전기적 특성에 미치는 영향 (Effects of Annealing Atmosphere on Crystallization and Electrical Properties in $YMnO_3$ Ferroelectric Thin Films)

  • 윤귀영;김정석;천채일
    • 한국세라믹학회지
    • /
    • 제37권2호
    • /
    • pp.168-173
    • /
    • 2000
  • YMnO3 thin films were prepared on Pt/Ti/SiO2/Si substrate by chemical solution deposition method. The films were crystallized by heat-treatment at 85$0^{\circ}C$ for 1 hour. Effects of an annealing atmosphere(O2, Ar, vacuum) on the crystallization behavior and electridcal properties were investigated. YMnO3 thin films annealed under Ar atmosphere showed a superior crystallinity and a very strong c-aix preferred-orientation which was a polar axis. Leakage current density of the films decreased with lowering oxygen partial pressure of the annealing atmosphere. C-V and P-E ferroelectric hysteresis were observed only in the thin film heat-treated under Ar atmosphere.In order to prepare YMnO3 thin films having both low leakage current and ferroelectricity, the annealing atmsphere should be kept under a proper oxygen partial pressure which was about 1 Pa in this work. Leakage current density at 1 volt, dielectric constant($\varepsilon$r), remanent polarization(Pr), and coercive field(Ec) were 1.7$\times$10-8 A/$\textrm{cm}^2$, 25, 1.08$\mu$C/$\textrm{cm}^2$, and 100 kV/cm, respectively.

  • PDF

ZrO2(m)-Al2O3ZrO2(t)-Al2O3 세라믹스의 제조와 물리적 특성 (Fabrication and Physical Properties of ZrO2(m)-Al2O3ZrO2(t)-Al2O3 Structural Ceramics)

  • 박재성;박주태;박정량
    • 조명전기설비학회논문지
    • /
    • 제24권4호
    • /
    • pp.140-148
    • /
    • 2010
  • 단사정 $ZrO_2(ZrO_2(m))$ 또는 $Y_2O_3$를 5.35[wt%] 첨가한 정방정 $ZrO_2(ZrO_2(t))$$Al_2O_3$에 첨가하여 물리적 및 전기전도도의 영향을 연구하였다. $ZrO_2$(m)과 $ZrO_2$(t)의 첨가는 $Al_2O_3$의 소결밀도를 증가시켰다. $ZrO_2$(t)의 첨가함에 따라 비커스 경도 또한 증가했으며, 그 량이 20[wt%]에서 최대가 되었다. 시편의 경도는 소결 밀도에 의존함을 알 수 있었다. $Al_2O_3-ZrO_2$계의 경도는 $ZrO_2$(t)의 첨가에 의해 개선되었고, $ZrO_2$(m)의 첨가가 $ZrO_2$(t)의 첨가보다 $Al_2O_3-ZrO_2$계의 열충격 특성에는 더 많은 영향을 받음을 알 수 있었다. 15[wt%] 이상의 $ZrO_2$(t) 첨가에서 인가전압이 증가 함에 따라 점차로 전기전도도가 증가 하였으나, $ZrO_2$(m)의 첨가에서는 영향이 없었다.

Effects of Ozone and Soil Salinity, Singly and in Combination, on Growth, Yield and Leaf Gas Exchange Rates of Two Bangladeshi Wheat Cultivars

  • Kamal, Mohammed Zia Uddin;Yamaguchi, Masahiro;Azuchi, Fumika;Kinose, Yoshiyuki;Wada, Yoshiharu;Funada, Ryo;Izuta, Takeshi
    • Asian Journal of Atmospheric Environment
    • /
    • 제9권2호
    • /
    • pp.173-186
    • /
    • 2015
  • In Bangladesh, increases in the tropospheric ozone ($O_3$) concentration and in soil salinization may lead to crop damage. To clarify the effects of $O_3$ and/or soil salinity on Bangladeshi wheat cultivars, BAW1059 (salt-tolerant) and Shatabdi (salt-sensitive) were exposed to 70-day treatments with $O_3$ (charcoal-filtered air (CF), $1.0{\times}O_3$, and $1.5{\times}O_3$) and different levels of soil salinity (0, 4, and $8dS\;m^{-1}$). In both cultivars, the whole-plant dry mass and grain yield were significantly reduced by exposure to $O_3$. Increased soil salinity caused significant reductions in whole-plant growth and yield in Shatabdi, but the reductions were negligible in BAW1059. No significant interactions between $O_3$ and salinity were detected for growth, yield, and leaf gas exchange parameters in both cultivars. We concluded that the effects of $O_3$ are not ameliorated by soil salinity in two Bangladeshi wheat cultivars, regardless of their salinity tolerance.

랫드 각막에서 bFGF(basic Fibroblast Growth Factor)로 유발시킨 신생혈관에 대한 $AS_2O_3$의 혈관신생 억제 효과 (Antiangiogenic Effect of $AS_2O_3$ on the New Vessels Induced by bFGF in the Rat Cornea)

  • 김용수;서강문
    • 한국임상수의학회지
    • /
    • 제18권4호
    • /
    • pp.324-328
    • /
    • 2001
  • This study was performed to evaluate the effects of $AS_2O_3$ upon antiangiogenesis in rat cornea, to examine it\`s possible application as an anticancer drug and to provide basic data for further studies of antiangiogenetic mechanism of $AS_2O_3$ . Angiogenesis was induced by cornea micropocket assay, as previously described. Sixteen of forty-eight eyes of Sprague-Dawley rats were randomly assigned to one of three groups, namely, only a bFGF group(control group), and a group treated by $AS_2O_3$ ($AS_2O_3$ group). After pellet implantation, we measured the number of new vessels, vessel length and clock hour of neovascularization, and area of neovascularization was determined using a mathematical formula. New vessels growing began at day 3, number of vessels in $AS_2O_3$ group were significantly more less than those in control group (p<0.05). The length of vessels of $AS_2O_3$ group was significantly shorter than that of control group after day 3(p<0.05). The clock hours of all group were slowly increased at all days but $AS_2O_3$ group was inhibited more than control group. Neovascularization areas of $AS_2O_3$ group were more significantly inhibited than those of control group (p<0.05). This study showed that $AS_2O_3$ had powerful antiangiogenetic effects and it would be useful in the choice of anticancer drug.

  • PDF

하소공정과 $ZrO_2$ 첨가량이 $BaTiO_3$의 전기적 특성에 미치는 영향 (Effects of Calcination Process and $ZrO_2$ Addition on the Electrical Properties of $BaTiO_3$ Ceramics)

  • 차진이;박재관;오태성;김윤호
    • 한국세라믹학회지
    • /
    • 제28권11호
    • /
    • pp.935-941
    • /
    • 1991
  • Effects of calcination process and ZrO2 addition on the electrical properties of [(Ba0.82Sr0.08Ca0.1)O]m(Ti1-$\chi$Zr$\chi$)O2 ceramics have been investigated. With the variation of A/B-site ratio m of the dielectric formulations, sintering behavior and the resistivity after sintering in a reducing atmosphere have been affected by the calcination process. When the dielectric formulations of m=1.01 were sintered in a reducing atmosphere, the room-temperature resitivity of 109 {{{{ OMEGA }}.cm was obtained for samples processed with two-step calcination, which was much lower than 1012 {{{{ OMEGA }}.cm of samples calcined once. It was confirmed that high resistivity of Ca-doped BaTiO3 ceramics, after sintering in a reducing atmosphere, is maintained by acceptor-like behavior of CaTi" which is formed by Ca substitution to Ti-site. It was also found out that the critical amount of B-site Ca substitution for reduction inhibition of BaTiO3 is around 0.005 mol. With the increasing amount of ZrO2 addition to dielectric formulations, Curie peak was depressed and Curie temperature was lowered due to the enhanced diffuse phase transition.tion.

  • PDF

Effects of $Y_2O_3$ Addition on the Microstructure and Electrical Property of $TiO_2$-excess $BaTiO_3$

  • Kim, Jong-Han;Han, Young-Ho
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
    • /
    • pp.1095-1096
    • /
    • 2006
  • When $Y_2O_3$ was added to Ti-excess $BaTiO_3$ ((Ba+Y)/Ti =1), the area occupied by $Y^{3+}$ ion was confirmed by its microstructure development, electrical conductivity behavior and lattice constant. Grain growth inhibition was observed when the content of donor dopant exceeded a critical value ($x{\approx}.0.01$) in $BaTiO_3+x(0.5Y_2O_3+TiO_2)$ system. A donor-doped behavior was observed at various Y contents ($0.2\sim3.0$ mol% Y) when $Y_2O_3$ was added to $TiO_2$-excess $BaTiO_3$. As Y content was increased, (002) and (200) peaks shifted to higher angles and the lattice constant (a and c axis) decreased gradually.

  • PDF

(Sr.Pb)TiO$_3$계 세라믹의 유전특성에 미치는 Bi$_2$O$_3$.3TiO$_2$의 영향 (Effects of Bi$_2$O$_3$.3TiO$_2$ on the Dielectric Properties of Ceramics in the system (Sr.Pb)TiO$_3$)

  • 최운식;김충혁;홍진웅;김재환;이준웅
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1990년도 추계학술대회 논문집
    • /
    • pp.68-70
    • /
    • 1990
  • (1-X)(Sr$\_$7/9/Pb$\_$2/9/)$\_$(1-y)/(Ca$\_$1/5/Mg$\_$4/5/)$\_$y/TiO$_3$+X(BiO$_2$O$_3$$.$3TiO$_2$) (y=0.145, 0$\leq$X$\leq$0.08) ceramics were fabricated by the mixed oxide method. The sintering temperature and time were 1180∼1230[$^{\circ}C$], 2[hr], respectly. The grain size were grown with increasing the contents of Bi$_2$O$_3$$.$3TiO$_2$, but decreased more and less in the specimens which had more than 0.04[mol].

Silver Thiosulfate 처리가 토마토의 오존피해경감에 미치는 효과 (Effectiveness of Silver Thiosulfate Treatment in Reducing Ozone Injury to Tomato Plants)

  • 구자형;원동찬;김태일
    • 한국대기환경학회지
    • /
    • 제8권1호
    • /
    • pp.7-12
    • /
    • 1992
  • This study was conducted to determine the effectiveness of silver thiosulfate(STS) in reducing $O_3$ injury to tomato plants(Lycopersicon esculentm Mill. 'Pink Glory'). Two days prior to $O_3$ fumigation, plants were given a foliar spray of STS solution at concentrations of 0, 0.2, 0.4, 0.6 mM contained with 0.05% Tween-20. STS concentrations below 0.6 mM were significantly effective in providing protection aginst $O_3$ exposure(16 h at 0.3 ppm). STS reduced leaf injury rate, defoliation of cotyledons, ethylene production and degree of epinasty induced by $O_3$ injury. STS slightly increased ethylene production in non-$O_3$-fumigated plants, but changes of chlorophyll content and transpiration rate on a whole plant basis were not observed. In $O_3$-fumigated plants, STS treatment reduced chlorophyll destruction but did not affect transpiration rate. STS treatment seemed not to affect peroxidase(POD) and superoxide dismutase (SOD) activity in non-fumigated plants but reduced increasing activity of POD by $O_3$ fumigation. However, such an effect as above was not found in SOD activity. Even though enzymatic protection effects were not confirmed, the fact that reduction of acute injury rate was attained for 16 h fumigation indicates that the phytoprotective effects of STS are not necessarily related to blocking the action of strees-induced-ethylene as an anti-ethylene agent.

  • PDF