• Title/Summary/Keyword: Nucleation-model

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Start-up dynamics in a CMSMPR crystallizer (CMSMPR 결정화기의 시동 특성 연구)

  • 신영준;이철수
    • 제어로봇시스템학회:학술대회논문집
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    • 1986.10a
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    • pp.200-204
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    • 1986
  • Particle size distribution in a Continuous Mixed Suspension Mixed Crystal Removal (CMSMPR) crystallizer has been analyzed using the Population Balance (PB) model. This method presents difficulties when the growth rate of crystal depends on the crystal size. Recent studies indicate that in many cases the growth rate is dependent on size when the crystal sizes are small. In this study, a Residence Time Distribution(RTD) model was proposed to take the size dependence into account together with an appropriate numerical scheme. When compared with the approximate results based on PB model, RTD model results showed improvements also a nucleation effect which is normally unimportant for steady state analysis. Start-up data for NaCl-Water-Ethanol system was compared with computed values.

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Predicting Compressive Strength of Fly Ash Mortar Considering Fly Ash Fineness (플라이 애시 미세도를 고려한 플라이 애시 모르타르의 압축 강도 예측)

  • Sun, Yang;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.90-91
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    • 2020
  • Utilization of upgraded fine fly ash in cement-based materials has been proved by many researchers as an effective method to improve compressive strength of cement based materials at early ages. The addition of fine fly ash has introduced dilution effect, enhanced pozzolanic reaction effect, nucleation effect and physical filling effect into cement-fly ash system. In this study, an integrated reaction model is adpoted to quantify the contributions from cement hydration and pozzolanic reaction to compressive strength. A modified model related to the physical filling effect is utilized to calculate the compressive strength increment considering the gradual dissolution of fly ash particles. Via combination of these two parts, a numerical model has been proposed to predict the compressive strength development of fine fly ash mortar considering fly ash fineness. The reliability of the model is validated through good agreement with the experimental results from previous articles.

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KINETIC MODELING STUDY OF A VOLOXIDATION FOR THE PRODUCTION OF U3O8 POWDER FROM A UO2 PELLET

  • Jeong, Sang-Mun;Hur, Jin-Mok;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.41 no.8
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    • pp.1073-1078
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    • 2009
  • A kinetic model for the oxidation of a $UO_2$ pellet to $U_3O_8$ powder has been suggested by considering the mass transfer and the diffusion of oxygen molecules. The kinetic parameters were estimated by a fitting of the experimental data. The activation energies for the chemical reaction and the product layer diffusion were calculated from the kinetic model. The oxidation conversion of a $UO_2$ pellet was simulated at various operating conditions. The suggested model explains the oxidation behavior of $UO_2$ well.

A probabilistic micromechanical framework for self-healing polymers containing microcapsules

  • D.W. Jin;Taegeon Kil;H.K. Lee
    • Smart Structures and Systems
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    • v.32 no.3
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    • pp.167-177
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    • 2023
  • A probabilistic micromechanical framework is proposed to quantify numerically the self-healing capabilities of polymers containing microcapsules. A two-step self-healing process is designed in this study: A probabilistic micromechanical framework based on the ensemble volume-averaging method is derived for the polymers, and a hitting probability model combined with a crack nucleation model is then utilized for encountering microcapsules and microcracks. Using this framework, a series of parametric investigations are performed to examine the influence of various model parameters (e.g., the volume fraction of microcapsules, microcapsule radius, radius ratio of microcracks to microcapsules, microcrack aspect ratio, and scale parameter) on the self-healing capabilities of the polymers. The proposed framework is also implemented into a finite element code to solve the self-healing behavior of tapered double cantilever beam specimens.

A Micromechanics based Elastic Constitutive Model for Particle-Reinforced Composites Containing Weakened Interfaces and Microcracks (계면손상과 미세균열을 고려한 입자강화 복합재료의 미세역학 탄성구성모델)

  • Lee, Haeng-Ki;Pyo, Suk-Hoon;Kim, Hyeong-Ki
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.21 no.1
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    • pp.51-58
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    • 2008
  • A constitutive model based on a combination of a micromechanics-based weakened interface elastic model (Lee and Pyo, 2007) and a crack nucleation model (Karihaloo and Fu, 1989) is proposed to predict the effective elastic behavior of particle-reinforced composites. The model specifically considers imperfect interfaces in particles and microcracks in the matrix. To exercise the proposed constitutive model and to investigate the influence of model parameters on the behavior of the composites, numerical simulations on uniaxial tension tests were conducted. Furthermore, the present prediction is compared with available experimental data in the literature to verify the accuracy of the proposed constitutive model.

Prediction of Necking in Tensile Test using Crystal Plasticity Model and Damage Model (결정소성학 모델과 손상 모델을 이용한 박판소재의 네킹 예측)

  • Kim, Jong-Bong;Hong, Seung-Hyun;Yoon, Jeong-Whan
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.8
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    • pp.818-823
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    • 2012
  • In order to predict necking behaviour of aluminium sheets, a crystal plasticity model is introduced in the finite element analysis of tensile test. Due to the computational limits of time and memory, only a small part of tensile specimen is subjected to the analysis. Grains having different orientations are subjected to numerical tensile tests and each grain is discretized by many elements. In order to predict the sudden drop of load carrying capacity after necking, a well-known Cockcroft-Latham damage model is introduced. The mismatch of grain orientation causes stress concentration at several points and damage is evolved at these points. This phenomenon is similar to void nucleation. In the same way, void growth and void coalescence behaviours are well predicted in the analysis. For the comparison of prediction capability of necking, same model is subjected to finite element analysis using uniform material properties of polycrystal with and without damage. As a result, it is shown that the crystal plasticity model can be used in prediction of necking and fracture behavior of materials accurately.

New Bubble Size Distribution Model for Cryogenic High-speed Cavitating Flow

  • Ito, Yutaka;Tomitaka, Kazuhiro;Nagasaki, Takao
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.700-710
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    • 2008
  • A Bubble size distribution model has been developed for the numerical simulation of cryogenic high-speed cavitating flow of the turbo-pumps in the liquid fuel rocket engine. The new model is based on the previous one proposed by the authors, in which the bubble number density was solved as a function of bubble size at each grid point of the calculation domain by means of Eulerian framework with respect to the bubble size coordinate. In the previous model, the growth/decay of bubbles due to pressure difference between bubble and liquid was solved exactly based on Rayleigh-Plesset equation. However, the unsteady heat transfer between liquid and bubble, which controls the evaporation/condensation rate, was approximated by a theoretical solution of unsteady heat conduction under a constant temperature difference. In the present study, the unsteady temperature field in the liquid around a bubble is also solved exactly in order to establish an accurate and efficient numerical simulation code for cavitating flows. The growth/decay of a single bubble and growth of bubbles with nucleation were successfully simulated by the proposed model.

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Theoretical Analysis on the Synthesis of Ultrafine TiO2 Particles by Combustion Reaction (연소반응을 이용한 TiO2 초미립자 제조 공정에 대한 이론적 연구)

  • Chae, Bum-San;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.17
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    • pp.241-247
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    • 1997
  • A numerical model has been proposed for a diffusion flame reactor to manufacture ultrafine $TiO_2$ powders. The model equations such as mass balance equation, the 0th, 1st, and 2nd moment equations of aerosols were considered. The phenomena such as $TiCl_4$ reaction rate, $TiO_2$ nucleation rate and the coagulation of $TiO_2$ powders were included in the aerosol dynamic equation. It is found that the $TiO_2$ particle concentration becomes higher, as the inlet $TiCl_4$ concentration and the total gas flow rate increase, and also as the flame temperature decreases. The $TiO_2$ particle size increases, as the flame temperature and the inlet $TiCl_4$ concentration increase and the total gas flow rate decreases.

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Numerical Modeling of Soot Formation in $C_2H_4$/Air Turbulent Non-premixed Flames ($C_2H_4$/Air 비예혼합 난류화염의 매연생성 모델링)

  • Kim, Tae-Hoon;Woo, Min-O;Kim, Yong-Mo
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.22-28
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    • 2010
  • The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

Numerical Modeling for Combustion and Soot Formation Processes in Turbulent Diffusion Flames

  • Kim, Hoo-Joong;Kim, Yong-Mo
    • Journal of Mechanical Science and Technology
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    • v.16 no.1
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    • pp.116-124
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    • 2002
  • In order to investigate the soot formation and oxidation processes, we employed the two variable approach and its source terms representing soot nucleation, coagulation, surface growth and oxidation. For the simulation of the taxi-symmetric turbulent reacting flows, the pressure-velocity coupling is handled by the pressure based finite volume method. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical models used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reacting flow field.