• 제목/요약/키워드: Nucleation-model

검색결과 102건 처리시간 0.026초

고분자 용액에서의 기포 형성 (Bubble Nucleation in Polymer Solutions)

  • 강성린;김기영;곽호영
    • 폴리머
    • /
    • 제28권1호
    • /
    • pp.51-58
    • /
    • 2004
  • 탄성체 (가교된 고분자) 가스가 용해된 고분자 또는 유기 용매에 용해된 고분자 용액에서 기포 생성을 예측하기 위하여 균일한 기포 생성은 고전적인 이론에서의 임계 기포의 생성이 아닌 임계 뭉치의 생성을 통하여 이루어진다는 분자 뭉치 이론을 적용하였다. 또한 탄성체나 고분자 내에서 기포가 생성하는 경우 임계 기포가 극복해야 할 탄성 에너지를 고려하였다. 대략 $10^{8}$$10^{12}$개에 달하는 분자 뭉치 이론에 의해 계산된 단위 부피당 생성된 기포 수는 실험치와 잘 일치하였다.

폴리머 용액에서의 기포 형성 (Bubble Nucleation in Polymer Solutions)

  • 강성린;김기영;곽호영
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2003년도 추계학술대회
    • /
    • pp.1228-1233
    • /
    • 2003
  • The molecular cluster model for the homogeneous bubble nucleation was extended to predict the bubble nucleation events in elastomers, polymers and polymer solutions. For the bubble nucleation in elastomers and polymers, the strain energy overcome by a critical bubble was also considered. The calculation results for the number of bubbles nucleated are in good agreement with observed ones.

  • PDF

Vapor Bubble Nucleation : A Microscopic Phenomenon

  • Kwak, Ho-Young
    • Journal of Mechanical Science and Technology
    • /
    • 제18권8호
    • /
    • pp.1271-1287
    • /
    • 2004
  • In this article, vapor bubble nucleation in liquid and the evaporation process of a liquid droplet at its superheat limit were discussed from the viewpoint of molecular clustering (molecular cluster model for bubble nucleation). For the vapor bubble formation, the energy barrier against bubble nucleation was estimated by the molecular interaction due to the London dispersion force. Bubble nucleation by quantum tunneling in liquid helium under negative pressure near the absolute zero temperature and bubble nucleation on cavity free micro heaters were also presented as the homogenous nucleation processes.

열간 유동응력 예측을 위한 물리식 기반 동적 재결정 모델 (A Physically Based Dynamic Recrystallization Model for Predicting High Temperature Flow Stress)

  • 이호원;강성훈;이영선
    • 소성∙가공
    • /
    • 제22권8호
    • /
    • pp.450-455
    • /
    • 2013
  • In the current study, a new dynamic recrystallization model for predicting high temperature flow stress is developed based on a physical model and the mean field theory. In the model, the grain aggregate is assumed as a representative volume element to describe dynamic recrystallization. The flow stress and microstructure during dynamic recrystallization were calculated using three sub-models for work hardening, for nucleation and for growth. In the case of work hardening, a single parameter dislocation density model was used to calculate change of dislocation density and stress in the grains. For modeling nucleation, the nucleation criterion developed was based on the grain boundary bulge mechanism and a constant nucleation rate was assumed. Conventional rate theory was used for describing growth. The flow stress behavior of pure copper was investigated using the model and compared with experimental findings. Simulated results by cellular automata were used for validating the model.

A Verification of Diamond Nucleation Model

  • Yugo, S.;Kimura, T.
    • The Korean Journal of Ceramics
    • /
    • 제2권4호
    • /
    • pp.181-183
    • /
    • 1996
  • We found that our initial model agrees with most of the recent reports; however, it does not agree with some of them with respect to the kinetics of nucleus formation. This disagreement stems from the question of whether or not a nucleus precursor should be treated as an embryonic cluster.

  • PDF

Modeling Heterogeneous Wall Nucleation in Flashing Flow of Initially Subcooled Water

  • Park, Jong-Woon
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
    • /
    • pp.241-246
    • /
    • 1996
  • An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.

  • PDF

Modeling of Defects Nucleation in the Inhomogeneous Liquid Crystal Director Field

  • Lee Gi-Dong;Kim Jae Chang
    • Journal of the Optical Society of Korea
    • /
    • 제9권2호
    • /
    • pp.74-78
    • /
    • 2005
  • With the fast Q-tensor method, which can model the defect dynamics in a liquid crystal director field, the nucleation and dynamical behavior of defects is modeled. In order to model the defect, hormeotropic aligned liquid crystal cell with step inhomogeneous electrode which has a height of $1\;{\mu}m$ is used. From the simulation, we can observe the nucleation and line of the defect from surface inhomogeneity and the experiment is performed for confirmation. The experimental result is compared with numerical modeling in order to verify the simulation of the defect nucleation.

액정 디스플레이 소자 내에서의 불균일한 표면에 의한 결점의 발생과 모델링 (Numerical modeling of defects nucleation in the liquid crystal devices with inhomogeneous surface)

  • 이기동;강봉순
    • 한국정보통신학회논문지
    • /
    • 제9권8호
    • /
    • pp.1793-1798
    • /
    • 2005
  • 액정 디스플레이 소자의 디렉터 내에서 결점을 모델링 할 수 있는 fast Q-텐서법을 이용하여 불균일한 표면에서 발생할 수 있는 결점의 발생과 움직임에 대한 모델링을 하였다. 결점을 모델링하기 위하여 $1{\mu}m$ 단차의 전극을 가진 수직배향셀을 이용하였다. 모델링을 통하여 단차에서 발생하는 액정 디렉터 내에서의 결점의 발생과 결점선을 확인할 수 있었으며 이러한 결과는 실험을 통하여 확인하였다.

Unequal Activation Volumes of Wall-motion and Nucleation Process in Co/Pt Multilayers

  • Cho, Yoon-Chul;Choe, Sug-Bong;Shin, Sung-Chul
    • Journal of Magnetics
    • /
    • 제5권4호
    • /
    • pp.116-119
    • /
    • 2000
  • Magnetic field dependence of magnetization reversal in Co/Pt multilayers was quantitatively investigated. Serial samples of Co/Pt multilayers were prepared by dc-magnetron sputtering under various Ar pressures. Magnetization reversal was monitored by magnetization viscosity measurement and direct domain observation using a magneto-optical microscope system, and the wall-motion speed V and the nucleation rate R were determined using a domain reversal model based on time-resolved domain reversal patterns. Both V and R were found to be exponentially dependent on the applied reversing field. From the exponential dependencies, the activation volumes for wall motion and nucleation could be determined, based on a thermally activated relaxation model, and the wall-motion activation volume was found to be slightly larger than the nucleation activation volume.

  • PDF

전착법으로 제작한 Ni(OH)2 나노 시트의 핵 형성과 성장 거동에 미치는 헥사-메틸렌테트라민(HMT)의 영향 (Effect of Hexa-methylenetetramine (HMT) on Nucleation and Growth Behaviors of Ni(OH)2 Nanosheets Produced by Electrodeposition)

  • 김동연;손인준;최문현
    • 한국표면공학회지
    • /
    • 제54권1호
    • /
    • pp.37-42
    • /
    • 2021
  • Electrodeposition is a synthetic method that allows fine control of the nucleation and growth factors of metals and is a suitable method for studying the nucleation and growth of Ni(OH)2. Hexa-methylenetetramine (HMT) helps to form Ni(OH)2 nanosheets by increasing the OH- of the nickel precursor solution and helps to improve the electrochemical properties of the electrode. In this study, the structural properties of Ni(OH)2 nanosheets according to the HMT concentration change using electrodeposition were studied. As the concentration of HMT increased, the size and thickness of the Ni(OH)2 nanosheet adsorbed on the surface increased and porosity increased. Also, the Scharifker-Hills nucleation theory model and experimental data were compared. In conclusion, the nanosheet shape of the HMT 7.5 mM sample electrodeposited with -0.85 V vs. Ag/AgCl grew most uniformly, and the best result was obtained as an electrode material for a pseudocapacitor.