• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.85-85
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• 2006

The micellization behavior and the metal-nanoparticle formation in PDEAEMA-b-PHEGMA double hydrophilic block copolymers are investigated. The hydrophobic PDEAEMA block is pH-sensitive: at low pH it can be protonated and it becomes hydrophilic, leading to molecular solubility, whereas at higher pH micelles are formed; the behavior is studied by DLS, NMR and AFM. In these micellar nanoreactors, metal nanorystals nucleate and grow upon reduction with sizes in the range of a few nm's as observed by TEM and XRD. Similarly, metal nanocrystals can be formed within pH-sensitive microgels (${\sim}250nm$ in diameter), synthesized by emulsion copolymerization of DEAEMA, which also exhibit reversible swelling properties in water by adjusting the pH.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.478-481
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• 2002

We carried out the experiments for fabricating $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{x}$(Bi2223) superconductor thick films on Cu tapes. Cu-free (Bi,Pb)-Sr-Ca-0 powder mixtures were screen- printed on Cu tapes and heat-treated at 840-$860^{\circ}C$ for several minutes in air. Surface microstructures and phases of films were analyzed by XRD and optical microscope. The electric properties of superconducting films were examined by the four probe method. At heat-treatment temperature, the printing layers were in a partially molten state by liquid reaction between CuO in the oxidized copper tape and the precursors which were printed on Cu tapes. During the heat-treatment procedure, it is thought that Bi2223 superconducting particles nucleate at interfaces between Bi2212 phase and liquid.

• Journal of Mechanical Science and Technology
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• 제16권2호
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• pp.182-191
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• 2002

The reliable stress intensity factor analysis is required for fracture mechanics design or safety evaluation of mechanical joints at which cracks often initiate and grow. It has been reported that cracks in mechanical joints usually nucleate as corner cracks at the faying surface of joints and grow as elliptical arc through cracks. In this paper, three dimensional finite element analyses are performed for elliptical arc through cracks in mechanical joints. Thereafter stress intensity factors along elliptical crack front including two surface points are determined by the virtual crack closure technique. Virtual crack closure technique is a method to calculate stress intensity factor using the finite element analysis and can be applied to non-orthogonal mesh. As a result, the effects of clearance on the stress intensity factor are investigated and crack shape are then predicted.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집A
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• pp.304-310
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• 2001

Cracks at mechanical fastener holes usually nucleate as elliptical comer cracks at the faying surface of the mechanical joints and grow as elliptical arc through cracks after penetrating the opposite surface. In this study mode I, II and III stress intensity factors at two surface points of elliptical arc through cracks at mechanical fastener holes are analyzed by applying weight function method. The weight function method for two dimensional mixed-mode problem is extended to three dimensional one and it is verified.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1578-1583
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• 2003

LAVA-ERVC experiments have been performed to investigate the effect of insulation design features on the coolability in case of the external reactor vessel cooling (ERVC). All the 4 tests have been performed using Alumina iron thermite melt as a corium simulant. Due to the limited steam venting through the insulation, steam binding occurred inside the annulus in the KSNP case simulation. On the contrary, in the tests which were performed for simulating the APR1400 insulation design, sufficient water ingression and steam venting through the insulation lead to effective cool down of the vessel characterized by nucleate boiling. It could be found from the experimental results that modification of the insulation design allowing sufficient ventilation could increase the positive effects of the external reactor vessel cooling.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.330-336
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• 2001

Water heat transfer experiments were carried out in a uniformly heated annulus with a wide range of pressure conditions. The local heat transfer coefficients for saturated water flow boiling have been measured just before the occurrence of the critical heat flux (CHF) along the length of the heated section. The trends of the measured heat transfer coefficients were quite different from the conventional understanding for the heat transfer of saturated flow boiling. This discrepancy was explained from the nucleate boiling in the liquid film of annular flow under high heat flux conditions.

• 동력기계공학회지
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• 제14권4호
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• pp.11-16
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• 2010

The evaporation heat transfer characteristics of propane(R-290) in horizontal small diameter tubes were investigated experimentally. The test tubes have inner diameters of 1 mm and 4 mm. Local heat transfer coefficients were measured at heat fluxes of 12, $24\;kW/m^2$, mass fluxes of 150, $300\;kg/m^2s$, and evaporation temperature of $15^{\circ}C$. The experimental results showed that the evaporation heat transfer coefficient of R-290 has an effect on heat flux, mass flux, tube diameter, and vapor quality. The evaporation heat transfer of R-290 has an influenced on nucleate boiling at low quality and convective boiling at high quality. The evaporation heat transfer coefficient of R-290 increases with decreasing inner tube diameter. And the evaporation heat transfer coefficient of R-290 is about 1~3 times higher than that of R-134a.

• International Journal of Air-Conditioning and Refrigeration
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• 제9권3호
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• pp.57-62
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• 2001

Falling film heat transfer analyses with aqueous lithium bromide solution were performed to investigate the transfer characteristics of the copper tubes. Finned (knurled) tube and a smooth tube were selected as test specimens. Averaged generation fluxes of water and the heat flux were obtained. As the film flow rate of the solution increased, the generation fluxes of water decreased for both tubes due to the fact that the heat transfer resistance increased with the film thickness. The effect of the enlarged surface area at the knurled tube was supposed to be dominant at a small flow rate. The generation fluxes of water increased with the increasing degree of tube wall superheat. Nucleate boiling is supposed to occur at a wall superheat of 20K for a smooth tube, and at 10K for a knurled tube. The increased performance of the knurled tube was supposed to mainly come from the effect of the increased heating surface area.

• 설비공학논문집
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• 제15권4호
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• pp.254-260
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• 2003

The boiling characteristics for R134a are studied to clarify the hysteresis at low temperature on enhanced tubes of a flooded evaporator. Initial boiling conditions, refrigerant temperature, and inlet temperature of the chilled water are considered as the key parameters of the experiments. Unlike previous studies of the boiling heat transfer with uniform heat flux and uniform wall temperature, the wall temperature was varied along the tube. In, this study, it was found that the hysteresis of the temperature overshoot (705) at the onset of nucleate boiling initially at the inlet section of the tube. It is also concluded that the abnormal operation can be avoided during the low temperature boiling if the refrigeration system is started with LMTD larger than $3.4^{\circ}C$ at initial stage and larger than $1.0^{\circ}C$ at normal stage.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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• pp.241-246
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• 1996

An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.