• 제목/요약/키워드: Nox4

검색결과 724건 처리시간 0.022초

The Experimental Investigations of Recirculated Exhaust Gas on Exhaust Emissions in a Diesel Engine

  • 김형남;배명완;박재윤
    • Journal of Mechanical Science and Technology
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    • 제15권11호
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    • pp.1588-1598
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    • 2001
  • The effects of recirculated exhaust gas on the characteristics of NOx and soot emissions under a wide range of engine loads were experimentally investigated by using a four-cycle, four-cylinder, sw irl chamber type, water-cooled diesel engine operating at three engine speeds. The purpose of this study was to develop the EGR-control system for reducing NOx and soot emissions simultaneously in diesel engines. The EGR system is used to reduce NOx emissions, and a novel diesel soot removal device with a cylinder-type scrubber for the experiment system was specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The experiments were performed at the fixed fuel injection timing of 4$^{\circ}$ ATDC regardless of experimental conditions. It was found that soot emissions in exhaust gases were reduced by 20 to 70% when the scrubber was applied in the range of the experimental conditions, and that NOx emissions decreased markedly, especially at higher loads, while soot emissions increased owing to the decrease in intake and exhaust oxygen concentrations, and the increase in equivalence ratio as the EGR rate is elevated.

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NADH oxidase(nox) 유선자의 PCR- RFLP를 이용한 돼지 intestinal spirochetes 국내분리주의 동정 (Identification of porcine intestinal spirochetes isolated from Korea by NADH oxidase gene(nox) PCR-RFLP)

  • 김태중;김명희;나영란;정석찬;이재일
    • 대한수의학회지
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    • 제44권4호
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    • pp.533-537
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    • 2004
  • In this study, we performed a PCR-RFLP analysis of NADH oxidase gene(nox) for the characterization of porcine intestinal spirochetes isolated from Korea by the comparison with Brachyspira hyodysenteriae and B. pilosicoli reference strains. Eleven strains including four reference strains, B. hyodysenteriae B204, B234, B169, B. pilosicoli P43/6/78 and seven Korean isolates were used. PCR products of 939 bp were amplified using nox-specific primers and digested with two restriction enzymes, Bfm I and Dpn II. In study using Bfm I, both strains showed no difference in fragmented size(197 and 741 bp). When use Dpn II, B. hyodysenteriae showed two bands(209 and 684 bp), however B. pilosicoli showed a single band of 896 bp. Our results indicate that nox-specific PCR-RFLP could be used as a typing method of Brachyspira species and as an epidemiological method for identifying spirochetes isolated from swine.

비예혼합 대향류 및 동축 제트화염에서 산소부화에 따른 NOx 생성특성 (NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow and Coflow Jet Flames)

  • 유병훈;황철홍;한지웅;이창언
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.169-174
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    • 2004
  • The NOx emission characteristics with oxygen enrichment in nonpremixed counterflow and coflow jet flame of $CH_4$ fuel have been investigated numerically. A small amount of nitrogen is included in oxygen-enriched combustion, in order to consider the inevitable $N_2$ contamination by air infiltration. The results show that the initial increase of NO with increasing oxygen enrichment is due to increasing temperature and residence time, while its subsequent decrease above 75% oxygen is due to decreasing the consumption rate of nitrogen. When oxygen addition exceeds 30%, Thermal NO gradually becomes the dominant production pathway and Prompt NO becomes negative pathway for net NO production rate. It is also seen that Thermal NO plays an important role in NO reduction when strain rate increase in oxygen-enriched combustion. Finally, the results of EINOx with oxygen enrichment in coflow jet flame show the similar profile with those of conterflow flame. It is confirmed that, with leakage of 1% nitrogen in the oxidizer stream, the corresponding EINOx is eight times of that emitted from regular $CH_4$/Air flame.

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희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구 (Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor)

  • 이종호;김대현;전충환;장영준
    • 대한기계학회논문집B
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    • 제28권4호
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    • pp.425-432
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    • 2004
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence(OH$\^$*/) image and its Abel inverted image to investigate the flame structure at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure and NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ∼341.8㎐, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between OH$\^$*/ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

플라즈마/후가열 장치를 이용한 NOx 저감에 에틴($C_2H_4$)이 미치는 영향에 관한 연구 (Effect of ethene($C_2H_4$) on DeNOx using Plasma/Post-Heating System)

  • 정상호;이형상;박광서;전배혁;전광민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제24회 KOSCO SYMPOSIUM 논문집
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    • pp.157-162
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    • 2002
  • The characteristics of DeNOx conversion process by plasma/post-heating system with the simulated gas containing ethene is investigated experimentally. Without plasma treatment, $NO-NO_2$ conversion doesn't occur by $400^{\circ}C$ in a mixture of $N_2/O_2$ with a trace gas of ethene. But $NO-NO_2$ conversion occurs as temperature increases above $400^{\circ}C$. The NO can, however, be converted to $NO_2$ at lower temperatures by treating the gas mixture with non-thermal plasma. The $NO-NO_2$ conversion enhances further by passing the plasma treated gas through the post-heating furnace. Results show that 20%${\sim}50%$ more conversion of NO to $NO_2$ is observed when the temperatures of the post-heating furnace are maintained at $300^{\circ}C$ or $400^{\circ}C$. The additional $NO-NO_2$ conversion by post-heating is due to the reaction of ethene with the byproducts or radicals generated from the plasma reaction.

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고농도 $NO_x$ 감지용 $In_2O_3$ 후막가스센서의 Al, Ru 및 $SnO_2$ 첨가에 의한 특성 향상 (Gas Sensing Characteristics of Catalyst-added $In_2O_3$ Thick Film for Detecting $NO_x$ of High Concentration)

  • 박종현;김동현;이종영;김광호
    • 한국세라믹학회지
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    • 제36권12호
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    • pp.1322-1326
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    • 1999
  • In2O3 thick film gas sensor for detecting NOx gas of high concentration was fabricated by a screen printing technique. This work focussed on investigation of the change of sensitivity to NOx gas with firing temperatures of sensing layer and on improvement of the sensitivity by adding catalysts such as Al,. Ru, and SnO2 The cross sensitivites of sensor to CO, H2, CH4 and i-C4H10 gases were also examined under NO2 gas concentration of 200ppm Pure In2O3 gas sensor prepared at a firing temperature of 50$0^{\circ}C$ showed a maximum sensitivity to NOx gas at the operating temperature of 40$0^{\circ}C$ Al(0.004 wt%)-In2O3 sensor largely improved the sensitivities to both NO2 and NO gas and showed a superior selectivity compared with other gas sensors.

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냉간 시동 조건에서의 SCR 경유자동차의 NOx 전환 효율 (NOx Conversion Efficiency of SCR Diesel Vehicle Under Cold Start Condition)

  • 이동인;유영수;박준홍;전문수;차준표
    • 한국분무공학회지
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    • 제23권4호
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    • pp.244-253
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    • 2018
  • Recently, The ministry of Environment in korea have introduced Euro-6d temp which was strengthened at the same time as Europe. Small Light-duty passenger vehicles need the SCR system of after-treatment to meet enhanced emission regulations. However, SCR system has a low conversion efficiency in a low temperature less than 200 degree. In this study, the NOx conversion efficiency of SCR system was analyzed by installing a NOx sensors and a temperature sensors in a diesel vehicle. Also, in order to analyze the effect of the cold-start, the test was performed on the same RDE route and compared with the test of hot-start. As a result, SCR system has characteristics of low conversion efficiency under cold-start conditions.

Porphyromonas gingivalis 감염된 구강상피세포에서 NADPH oxidase와 항산화단백의 발현 (Induction of NADPH oxidases and antioxidant proteins by Porphyromonas gingivalis in KB cells)

  • 김민정;정현주;박병주;박해령;이태훈
    • Journal of Periodontal and Implant Science
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    • 제36권4호
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    • pp.863-878
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    • 2006
  • Porphyromonas gingivalis는 치주질환을 야기하는 독성세균으로서, 구강상피세포에 p. gingivalis가 감염되었을 때, 세포형태에 변화를 초래함으로 인해 방어기작이 작동하게 된다. 치주질환과 관련되어 생성된 활성 산소종의 소거에 관여하는 항산화성분은 p. gingivalis 이 감염된 구강상피세포에서 그 분포와 발현수준이 달라지리라 예상된다. 따라서 이번 연구에서는 구강상피세포(KB 세포)에 p. gingivalis가 감염되었을 때 야기되는 활성산소종과 이를 소거하는 역할을 하는 항산화단백들의 역할들을 규명하고자 하였다. 활성산소종 형성을 조절하는 NADPH oxidase 중 NOX4와 Rac1 전사체는 구강상피세포에서 p. gingivalis세균에 의해 증가하였으며 $gp91^{phox}$, Rac2, $p47^{phox}$$p67^{phox}$는 세균에 의한 변화가 관찰되지 않았다. 반면에 $p40^{phox}$ 전사체는 감소하는 경향을 보였다. NOX1 전사체는 p. gingivalis 처리 30분 후 감소하였다가 60분 후에는 다시 증가하는 양상을 보였다. 같은 시간에 NOX 활성화 단백인 NOXA1은 감소하고, NOX 구성단백질인 NOXO1은 증가하는 경향을 보였다. p. gingivalis가 감염된 구강상피세포를 방어하는 항산화단백 발현수준을 평가한 결과, SOD1, 2, 3 모두 p. gingivalis 처리시간에 따라 증가하는 양상을 보였다. GPx 발현 양상도 SOD와 유사하게 나타났다. $H_2O_2$를 소거하는 Prx는 감염된 KB 세포에서 Prx4와 Prx5가 4-6배 증가하는 것을 알 수 있었다. 반면 endocytosis 과정 중 $H_2O_2$ 생산은 변화되지 않았다. 이번 연구의 결과, p. gingivalis의 감염은 KB 세포의 NOX4와 Rac1의 NADPH oxidase 발현을 증가시켰으며, NOX1은 NOXA1과 NOXO1의 조절에 의해 영향을 받음을 알 수 있었다. 또한 항산화기작으로는 SOD, GPx, Prx가 증가하였는데, 이것은 Prx4와 Prx5가 중요한 역할을 할 것을 시사하였다.

복합발전 가스터빈 연소기용 저선회 노즐의 연료 분사 위치에 따른 배기배출 및 연소진동 특성 (Emissions and Combustion Dynamics with Fuel Injection Position for Low-swirl Nozzles of Gas Turbine Combustor)

  • 황정재;이원준;김민국;김한석
    • 한국가스학회지
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    • 제26권6호
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    • pp.37-44
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    • 2022
  • 본 연구에서는 SN(Swirl Number)는 같지만 코어부와 스월러부의 질량유량비(m)가 다른 저선회 노즐 2종을 설계하여 상압 연소성능 시험을 수행하였다. 각 노즐에 대해 단열화염온도에 따른 연소성능 실험을 수행하였고 화염구조 특성, NOx 배출 특성, 연소진동 모드를 파악하였다. 화염구조가 크게 차이가 있었지만 CO 배츨 특성은 유사하였고 NOx 배출 특성도 화염구조보다는 연소진동과 더 큰 관련성이 있음을 보였다. 연료노즐의 위치를 변경하여 대류지연시간을 조절하면서 연소진동 및 NOx 배출 특성을 파악하였는데 대류지연시간이 연소진동 주기의 (3+4n)/4±1/4 (n=0,1,2,...) 영역에 들어올 때 진소진동이 강하게 나타나고 반대의 경우는 연소진동이 아주 약하게 발생함을 확인하였다.

기존 선박의 디젤발전기용 SCR 시스템 설치에 관한 연구 (A Study on the Installation of SCR System for Generator Diesel Engine of Existing Ship)

  • 류영현;김홍렬;조규백;김홍석;남정길
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권4호
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    • pp.412-417
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    • 2015
  • IMO MEPC에서는 해양환경 보호를 위해서 선박으로부터 배출되는 배기가스 규제를 날로 점점 강화하고 있다. 특히, 2016년부터 건조되어 국제항해를 하는 모든 신조 선박에 대한 질소산화물(NOx) 배출량은 Tier-III 규제를 만족하게 되어 있다. 본 연구에서는 선박용으로 개발된 NOx 저감용 SCR(선택적 환원 촉매) 시스템을 기존 선박의 디젤발전기에 설치하여 NOx 저감성능을 파악하고자 하였다. 본 연구를 위하여 목포해양대학교 실습선 새누리호 디젤발전기의 배기 파이프라인을 개조 공사하여 요소 SCR 시스템을 설치하였으며, 요소 용액(40%) 분사 방법은 수동 모드와 PLC를 통한 자동 모드로 나누어 두 가지 방법으로 실험을 하였다. 수동 모드 방법을 통하여 암모니아 슬립 발생구간을 찾을 수 있었으며, 엔진부하별(25, 35 및 50%)로 최적의 요소 분사량을 조절할 수 있었다. 부하를 Down-Up(25%에서 50%로 올리면서) 시보다도 Up-Down(50%에서 25%로 내리면서) 시에 NOx 저감성능이 더 좋음을 알 수 있었으며, 본 바나듐계 촉매가 사용된 SCR 시스템을 기존 선박의 디젤발전기에 설치하여 질소산화물이 80% 이상 절감됨을 확인할 수 있었다.