• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2007년도 춘계학술대회B
• /
• pp.2232-2237
• /
• 2007

Steam reforming and catalytic reforming of $CH_4$ conversion to produce synthesis gas require both high temperatures and high pressure. Non-thermal plasma is considered to be a promising technology for the hydrogen rich gas production from methane. In this study, three phase AC GlidArc plasma system was employed to investigate the effects of gas composition, gas flow rate, catalyst reactor temperature and applied electric power on the $CH_4$ and $H_2$ yield and the product distribution. The studied system consisted of three electrode and it connected AC generate power system different voltages. In this study, air was used for the partial oxidation of methane. The results showed that increasing gas flow rate, catalyst reactor temperature, or electric power enhanced $CH_4$ conversion and $H_2$ concentration. The reference conditions were found at a $O_2$/C molar ratio of 0.45, a feed flow rate of 4.9 ${\ell}$/min, and input power of 1kW for the maximum conversions of $CH_4$ with a high selectivity of $H_2$ and a low reactor energy density.

• 한국전기전자재료학회논문지
• /
• 제17권11호
• /
• pp.1246-1251
• /
• 2004

This paper is investigated about the effect of carrier gas type and the humidity for generating hydrogen gas. The vibration of the water surface is more powerful with increasing applied voltage. In this experimental reactor which is made of multi-needle and plate, the maximum acquired hydrogen production rate is about 3500 ppm. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with water droplet by humidifier and without water droplet by humidifier, the generation of hydrogen gas is decreased in case of water droplet by humidifier. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small water molecular produced from humidifier.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
• /
• pp.215-219
• /
• 2004

This paper is investigated about the effect of carrier gas and humidity for generating hydrogen gas. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with no humidity and humidity 45[%], the generation of hydrogen gas is decreased with increasing the humidity. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small particle produced from humidifier.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2004년도 하계학술대회 논문집 B
• /
• pp.1205-1207
• /
• 2004

AC plasma power supply is used to control a ozone generator and a air pollution gas. AC plasma power supply is composed of power semiconductor switch devices and control board adapted SHE(Selected Harmonic Elimination) PWM method. AC plasma power supply with sinusoidal VVVF(variable voltage and variable frequency) is realized. Its output voltage range is from 0 [V] to 20[kV] and output frequency range is from 8[kHz] to 20[kHz]. Using proposed system, AC high voltage and high frequency discharge is tested in the DBD(dieletric barrier discharge) reactor, and the space distribution of a its non-thermal plasma is observed. In spite of the increasement of voltage and frequency, the proposed system have a stable operation characteristics. It is verified by the experimental results.

• 한국대기환경학회지
• /
• 제19권3호
• /
• pp.315-323
• /
• 2003

The goal of this study if the optimization of discharge electrode for pulsed corona discharge reactor located in thermal power plant. For this purpose, we have performed experiments of NO$_{x}$ removal rate by exchange of discharge electrode diameter and arrangement of discharge electrode in the non -thermal plasma reaction facility using a ethylene as additive. If the diameter and numbers of discharge electrode were larger, the NO$_{x}$ removal rate was higher. From these results, if we optimized the shape and installed numbers of discharge electrode at the pilot plant, we could increase the NO$_{x}$ removal rate with less amount of additive than current amount.mount.

• 한국입자에어로졸학회지
• /
• 제5권3호
• /
• pp.123-131
• /
• 2009

This paper presents simulation results of particle transport in low-pressure, low-temperature plasma environment. The size dependent transport of particles in the plasma is investigated with a two-dimensional simulation tool developed in-house for plasma chamber analysis and design. The plasma model consists of the first two and three moments of the Boltzmann equation for ion and electron fluids respectively, coupled to Poisson's equation for the self-consistent electric field. The particle transport model takes into account all important factors, such as gravitational, electrostatic, ion drag, neutral drag and Brownian forces, affecting the motion of particles in the plasma environment. The particle transport model coupled with both neutral fluid and plasma models is simulated through a Lagrangian approach tracking the individual trajectory of each particle by taking a force balance on the particle. The size dependant trap locations of particles ranging from a few nm to a few ${\mu}m$ are identified in both electropositive and electronegative plasmas. The simulation results show that particles are trapped at locations where the forces acting on them balance. While fine particles tend to be trapped in the bulk, large particles accumulate near bottom sheath boundaries and around material interfaces, such as wafer and electrode edges where a sudden change in electric field occurs. Overall, small particles form a "dome" shape around the center of the plasma reactor and are also trapped in a "ring" near the radial sheath boundaries, while larger particles accumulate only in the "ring". These simulation results are qualitatively in good agreement with experimental observation.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2001년도 추계학술대회 논문집
• /
• pp.423-424
• /
• 2001

플라즈마를 이용한 가스상 오염물질 처리에 대한 연구는 일부 선진국에서 1970년대부터 시작되어 현재는 상용화 연구가 활발히 진행되고 있으며, 국내에서도 1990년대 중반부터 화력발전소에서 배출되는 연소가스 중의 유해성분을 처리하기 위한 연구를 필두로 최근에는 휘발성 유기화합물(VOCs) 분해관련 연구 등 상당한 연구가 수행되고 있다. 저온 플라즈마 공정은 전기적 방전 특성을 이용하므로 스트리머코로나 형성영역인 반응기와 전원공급장치 사이의 기계적ㆍ전기적 매칭(matching)이 중요한 과제이다. (중략)

• 대한환경공학회지
• /
• 제22권12호
• /
• pp.2247-2254
• /
• 2000

본 연구는 저온 플라즈마 탈질 기술의 전력소모량 절감과 처리율 향상을 모색하고자 저온 플라즈마 조건에서 NOx와 반응제의 반응 특성을 고찰하였다. 실험은 $20Nm^3/hr$의 실제 배가스와 wire-plate type 플라즈마 반응기를 이용하여 진행되었으며, 반응제로는 파라핀계와 올레핀계 탄화수소 및 $NH_3$를 사용하였다. 저온 플라즈마 조건에서 올레핀계 탄화수소는 파라핀계 탄화수소에 비하여 NO의 산화에 탁월한 효과를 보여 다량의 $NO_2$를 생성할 뿐만 아니라 미량의 CO도 생성하였다. 또한 NOx의 초기농도가 높아지면 NO의 산화율은 감소할 뿐만 아니라 올레핀계 탄화수소의 소모량도 두드러진 증가를 보였다. 한편 $NH_3$은 저온 플라즈마 조건에서 NO와의 환원반응이 촉진되지 않았지만 올레핀계 탄화수소에 의하여 산화된 $NO_2$의 제거에는 효과적인 경향을 보였다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 하계학술대회 논문집 E
• /
• pp.2182-2185
• /
• 1999

In this experimental study we propose the double dielectric barrier discharge(DDBD) reactor to produce as high an electric field as possible. DDBD reactor is designed to remove $NO_x$ at atmospheric pressures from the moving pollution source such as diesel automobile DDBD reactor consisted of two cylinder glass tubes arranged so that the gas flow was directed between the two tubes. Inside of the inner tube was filled with small metal beads and outside of the inner tube was wounded with stainless wire to form the electrode. The outer tube was surrounded by an aluminum foil In this reactor there are three electrodes, i.e. metal bead(C), helical wire(I) and aluminum foil(0). By using DDBD reactor we will report some interesting results of treatment of the gas which is the dilute mixtures of NO in N2. And then we compared thee results with the results of cylinder-wire(CW) which is one of popularly used reactor in non-thermal plasma applications.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
• /
• pp.69-76
• /
• 1997

Industrial-scale pulse corona process to remove $SO_2$ and $NO_x$ simultaneously from combustion flue gas has been studied. The pilot plant built in the present study treats 2,000 $Nm^3$/hr of flue gas from a boiler. The geometry of the pulse corona reactor is similar to that of an electrostatic precipitator commonly used in industry, A thyratron switch and magnetic pulse compressors, which can generate up to 130 kV of peak pulse voltage and up to 30 kW of average pulse power, have been used to produce pulsed corona. The removal efficiencies of $S0_2$ and $NO_x$ with the present process are maximum of 95 % and 85 %, respectively. Electrical power consumption to produce the pulsed corona, which has been one of the major difficulties to apply this process to industry, has been evaluated in the present study. The results showed that the power consumption can be reduced significantly by simultaneous addition of hydrocarbon injection and heterogeneous phase reactions to the process.