• Title/Summary/Keyword: Non-linear wave

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Stoichiometry and Stability of Complexes Formed between 18-Crown-6 as well as Digenzo-18-Crown-6 Ligands and a Few Metal Ions in Some Non-aqueous Binary Systems Using Square Wave Polarography

  • A. Nezhadali, Gh. Rounaghi;M. Chamasaz
    • Bulletin of the Korean Chemical Society
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    • v.21 no.7
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    • pp.685-689
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    • 2000
  • The complexation reaction between Pb2+,TI and Cd2+ions and macrocyclic ligands, 18-crown-6 ( 18C6) and dibenzo- 18-crown-6 (DB 18C6), was studied in dimethylsulfoxide (DMSO)-nitromethane (NM) and dimethyl-formamide (DMF)-nitromethane binary system s by square wave polarography (SWP) technique. The stoichiometry and stability of the complexes were determined by monitoring the shifts in half-waves or peak potentials of the polarographic waves of metal ions against the Iigand concentration. In most cases, the stability constants of complexes increase with increasing amounts of the nitromethane in mixed binary solvents used in this study. The complexes formed between 18C6 and DB18C6 and these metal cations in all cases had a stoichiometry of 1 : 1. The results obtained show that there is an inverse relationship between the formation constant of complexes and the donor number of solvents based on a Gatmann donocity scale and the stability constants show a high sensitivity to the composition of the mixed solvent systems. A linear behavior was observed for variation of log Kf of I8C6 complexes vs the composition of the mixed solvent systems in NM/DMSO and NM/DMF,but a non-linear behavior was observed in the case of DB 18C6 complexes in these binary systems. In most of the systems investigated, the Pb2+ cation forms a more stable complex with the 18C6 than other two cations and the order of selectivity of this Iigand for cations is: Pb2+ > TI+,Cd2+.

Atrial Fibrillation Detection Algorithm through Non-Linear Analysis of Irregular RR Interval Rhythm (불규칙 RR 간격 리듬의 비선형적 특성 분석을 통한 심방세동 검출 알고리즘)

  • Cho, Ik-Sung;Kwon, Hyeog-Soong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.12
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    • pp.2655-2663
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    • 2011
  • Several algorithms have been developed to detect AF which rely either on the form of P waves or the based on the time frequency domain analysis of RR variability. However, locating the P wave fiducial point is very difficult because of the low amplitude of the P wave and the corruption by noise. Also, the time frequency domain analysis of RR variability has disadvantage to get the details of irregular RR interval rhythm. In this study, we describe an atrial fibrillation detection algorithm through non-linear analysis of irregular RR interval rhythm based on the variability, randomness and complexity. We employ a new statistical techniques root mean squares of successive differences(RMSSD), turning points ratio(TPR) and sample entropy(SpEn). The detection algorithm was tested using the optimal threshold on two databases, namely the MIT-BIH Atrial Fibrillation Database and the Arrhythmia Database. We have achieved a high sensitivity(Se:94.5%), specificity(Sp:96.2%) and Se(89.8%), Sp(89.62%) respectively.

Development of an Optimum Hull Form for a Container Ship with Minimum Wave Resistance (최소 조파저항을 가지는 컨테이너선의 선형최적화 기법에 대한 연구)

  • 최희종;서광철;김방은;전호환
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.4
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    • pp.8-15
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    • 2003
  • This paper presents the method for developing an optimum hull form with minimum wave resistance using SQP(sequential quadratic programming) as an optimization technique. The wave resistance is evaluated by a Rankine source panel method with non-linear free surface conditions and the ITTC 1957 friction line is used to predict the frictional resistance coefficient. The geometry of the hull surface is represented and modified using B-spline surface patches. The optimization method is applied to Series 60 hull and KCS(KRISO 3600 TEU Container Ship). The obtained results prove that the method is appropriate for preliminary hull form design.

Evaluation of Concrete Strength Using Compression Wave Velocity (압축파 속도를 이용한 콘크리트의 강도 평가)

  • 이회근;이광명;김동수;김지상
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.697-702
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    • 1999
  • Among several non-destructive testing methods, ultrasonic pulse velocity method has been widely used for the evaluation of concrete strength. However, this method might not provide accurate estimated results since factors influencing the relationship between strength and wave velocity is not considered. In this study, the evaluation methods of concrete strength using compression wave velocities measured by either ultrasonic pulse velocity method or impact-resonance method are proposed. A basic equation is obtained by the linear regression with velocity vs. strength data at a specific age and then, ageing factor is employed in the equation to consider the difference of the increasing rate between wave velocity and strength. Strengths predicted by the proposed equation agree well with test results.

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Novel Smart Polymeric Composites for Thermistors and Electromagnetic Wave Shielding Effectiveness from TiC Loaded Styrene-Butadiene Rubber

  • Sung, Yong-Kiel;Farid EI-Tantawy
    • Macromolecular Research
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    • v.10 no.6
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    • pp.345-358
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    • 2002
  • The electrical conductivity during vulcanization process was measured as a function of time for the system of TiC loaded styrene-butadiene rubber (SBR) composites. The phenomenon of negative and positive temperature coefficients of conductivity and its conduction mechanism were also studied for the SBR polymeric composites. The current-voltage characteristics of the polymeric composites were non-linear in high voltage and showed a switching effect. The effects of temperature on the thermal conductivity and effective dielectric constant were measured. The measured parameters were found to be dependent on TiC concentration. The electromagnetic wave shielding (EMS) of the SBR-TiC polymeric composite was also examined. The SBR filled with TiC could be expected to be promising novel smart polymeric composites for self-electrical heating, temperature sensor, time delay switching, and electro-magnetic wave shielding effectiveness.

Measurement of Zero Dispersion Wavelength in an Optical Fiber Using the Oscillatory Behavior of Four-Wave Mixing Efficiency

  • Kim, Dong-Hwan;Kim, Sang-Hyuck;Jo, Jae-Cheol;Choi, Sang-Sam
    • Journal of the Optical Society of Korea
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    • v.5 no.1
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    • pp.20-24
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    • 2001
  • Non-destructive measurement of zero-dispersion wavelength variation in a dispersion shifted fiber by four-wave mixing technique is carried out. The oscillatory behavior of the four-wave mixing efficiency is utilized for the measurement of the linear dispersion slope and zero-dispersion wavelength. A simple formula useful for engineering estimation of the characteristics of fiber four-wave mixing efficiency is presented.

Transient wave propagation in piezoelectric hollow spheres subjected to thermal shock and electric excitation

  • Dai, H.L.;Wang, X.
    • Structural Engineering and Mechanics
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    • v.19 no.4
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    • pp.441-457
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    • 2005
  • An analytical method is presented to solve the problem of transient wave propagation in a transversely isotropic piezoelectric hollow sphere subjected to thermal shock and electric excitation. Exact expressions for the transient responses of displacements, stresses, electric displacement and electric potentials in the piezoelectric hollow sphere are obtained by means of Hankel transform, Laplace transform, and inverse transforms. Using Hermite non-linear interpolation method solves Volterra integral equation of the second kind involved in the exact expression, which is caused by interaction between thermo-elastic field and thermo-electric field. Thus, an analytical solution for the problem of transient wave propagation in a transversely isotropic piezoelectric hollow sphere is obtained. Finally, some numerical results are carried out, and may be used as a reference to solve other transient coupled problems of thermo-electro-elasticity.

High-speed angular-scan pulse-echo ultrasonic propagation imager for in situ non-destructive evaluation

  • Abbas, Syed H.;Lee, Jung-Ryul
    • Smart Structures and Systems
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    • v.22 no.2
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    • pp.223-230
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    • 2018
  • This study examines a non-contact laser scanning-based ultrasound system, called an angular scan pulse-echo ultrasonic propagation imager (A-PE-UPI), that uses coincided laser beams for ultrasonic sensing and generation. A laser Doppler vibrometer is used for sensing, while a diode pumped solid state (DPSS) Q-switched laser is used for generation of thermoelastic waves. A high-speed raster scanning of up to 10-kHz is achieved using a galvano-motorized mirror scanner that allows for coincided sensing and for the generation beam to perform two-dimensional scanning without causing any harm to the surface under inspection. This process allows for the visualization of longitudinal wave propagation through-the-thickness. A pulse-echo ultrasonic wave propagation imaging algorithm (PE-UWPI) is used for on-the-fly damage visualization of the structure. The presented system is very effective for high-speed, localized, non-contact, and non-destructive inspection of aerospace structures. The system is tested on an aluminum honeycomb sandwich with disbonds and a carbon fiber-reinforced plastic (CFRP) honeycomb sandwich with a layer overlap. Inspection is performed at a 10-kHz scanning speed that takes 16 seconds to scan a $100{\times}100mm^2$ area with a scan interval of 0.25 mm. Finally, a comparison is presented between angular-scanning and a linear-scanning-based pulse-echo UPI system. The results show that the proposed system can successfully visualize defects in the inspected specimens.

Study on the Development of an Optimal Hull Form

  • Cho Hee-Jong;Lee Gyoung-Woo;Youn Soon-Dong;Chun Ho-Hwan
    • Journal of Navigation and Port Research
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    • v.29 no.7
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    • pp.603-609
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    • 2005
  • This paper presents the method for developing an optimum hull form with minimum wave resistance using SQP( sequential quadratic programming) as an optimization technique. The wave resistance is evaluated by a Rankine source panel method with non-linear free surface conditions and the ITTC 1957 friction line is used to predict the frictional resistance coefficient. The geometry of the hull surface is represented and modified using NURBS(Non-Uniform Rational B-Spline) surface patches. To verify the validity of the developed program the numerical calculations for Wigley hull and Series 60 Cb=0.6 hull are performed and the results obtained after the numerical calculations are compared with the initial hulls.

Instability Analysis of Natural Convection Flow along Isothermal Vertical Cylindrical Surfaces (등온 수직 원통표면을 연하여 흐르는 자연대류 유동의 파형 불안정성)

  • 유정열;윤준원;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.1
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    • pp.161-169
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    • 1989
  • A stability problem on wave instability of natural convection flow along isothermal vertical cylindrical surfaces has been formulated, accounting for the non-parallelism of the basic flow and thermal fields. Then the problem is solved numerically under the simplifying assumption of the parallelism of the basic flow quantities. It is shown that the flow corresponding to the same characteristic boundary layer thickness becomes more stable as the value of the curvature parameter increases. The stability characteristics for Pr=0.7 appear to be more sensitive to the curvature parameter than those for Pr=7.