• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.52-57
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• 2023

This study is a basic research for the development of high performance flexible electrode material. To enhance its electrochemical property, CuO nanoparticles (CuO NPs) were introduced and dispersed on surface of CNT fiber through electrochemical deposition method. The CNT fiber/CuO NPs electrode was fabricated and applied to electrochemical non-enzymatic glucose sensor. Surface morphology and elemental composition of the CNT fiber/CuO NPs electrode was characterized by scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDS). And its electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fiber/CuO NPs electrode exhibited the good sensing performance for glucose detection such as high sensitivity, wide linear range, low detection limit and good selectivity due to synergetic effect of CNT fiber and CuO NPs. Based on the unique property of CNT fiber, CuO NPs were provide large surface area, enhanced electrocatalytic activity, efficient electron transport property. Therefore, it is expected to develop high performance flexible electrode materials using various nanomaterials.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.669-673
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• 2001

The objective of this paper is to predict and evaluate the sealing performance of the thermoplastic rubber component in the proto-design stage. The large strain and large deformation properties of rubber are modeled by strain energy function and the related material constants are calculated from the test data. The viscoelastic property of the rubber is also considered using the coefficients in a Prony series representation of a viscoelastic modulus ken the compression stress relaxation test. The results show that the current design of cap mount system has 2-different stiffness caused by the cap-mount contact and the viscoelastic property of rubber plays an important role in time dependent deformation.

• 제어로봇시스템학회:학술대회논문집
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• 1998.10a
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• pp.468-473
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• 1998

A mathematical model was developed for a continuous re-actor in which free radical polymerization of methyl methacrylate (MMA) occurred. Elementary reactions considered in this study were initiation, propagation, termination, and chain transfers to monomer and solvent. The reactor model took into account the density change of the reactor contents and the gel effect. A control system was designed for a continuous reactor using extended Kalman filter (EKF) based non-linear model predictive controller (NLMPC) to control the conversion and the weight average molecular weight of the polymer product. Control input variables were the jacket inlet temperature and the feed flow rate. For the purpose of validation of the control strategy, on-line digital control experiments were conducted with densitometer and viscometer for the measurement of the polymer properties. Despite the com-plex and nonlinear features of the polymerization reaction system, the EKF based NLMPC performed quite satisfactorily for the property control of the continuous polymerization reactor.

• Bulletin of the Korean Chemical Society
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• v.34 no.1
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• pp.128-132
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• 2013

L-Arginine semi-oxalate (LASO) single crystal has been grown by solution growth technique at room temperature. The crystal structure and lattice parameters were determined for the grown crystal by single crystal X-ray diffraction studies. Photoluminescence studies confirm the violet fluorescence emission peak at 395 nm. Optical constants like band gap, refractive index, reflectance, extinction coefficient and electric susceptibility were determined from UV-VIS-NIR spectrum. The dielectric constant, dielectric loss and ac conductivity of the compound were calculated at different temperatures and frequencies to analyze the electrical properties. The solid state parameters such as plasma energy, Penn gap, Fermi energy and polarizability were calculated to analyze second harmonic generation (SHG). Nonlinear optical property was discussed to confirm the SHG efficiency of the grown crystal.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.187-188
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• 2002

Rubber has large differences in elastic characteristics from the other solid materials such as metals. Firstly, the rubber exhibits considerably large elastic compliance. Second is highly non-linear elasticity in which the compliance decreases with increase in strain. The main objective in this research is to reveal the dependence of rubber friction upon these elastic characteristics of the rubber in detail. A super elastic FEM analysis is carried out with using an elastic property of practical rubber. From the calculated result, it is cleared that the rubber makes large real contacting area easier than the metals.

• Journal of Mechanical Science and Technology
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• v.18 no.12
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• pp.2225-2235
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• 2004

An observatory termed 'Steel Swing' has been developed, where a 15000 kg pendulum is hanged from a stiff steel frame. A building element can be tested after inserted between the pendulum and the frame. Free vibration, forced vibration tests and earthquake monitoring were performed on an exposed-type steel column base. The response records monitored during natural earthquakes were used to identify the vibration property of the specimen. Identified system gain was approximated by a theoretical gain of linear SDOF system, and the response calculated based on such a linear system agrees with the monitored response fairly well. This research technique can be applied to check the behaviors of new materials and new details of connections and the safety of non-structural elements as well.

• Journal of the Korean Mathematical Society
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• v.54 no.5
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• pp.1573-1594
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• 2017

This paper deals with the existence and energy estimates of solutions for a class of degenerate nonlocal problems involving sub-linear nonlinearities, while the nonlinear part of the problem admits some hypotheses on the behavior at origin or perturbation property. In particular, for a precise localization of the parameter, the existence of a non-zero solution is established requiring the sublinearity of nonlinear part at origin and infinity. We also consider the existence of solutions for our problem under algebraic conditions with the classical Ambrosetti-Rabinowitz. In what follows, by combining two algebraic conditions on the nonlinear term which guarantees the existence of two solutions as well as applying the mountain pass theorem given by Pucci and Serrin, we establish the existence of the third solution for our problem. Moreover, concrete examples of applications are provided.

• Journal of Sensor Science and Technology
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• v.33 no.3
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• pp.119-124
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• 2024

Effective fire sensing is important to protect lives and property from the disaster. In this paper, we present an intelligent visual sensing method for detecting fires based on machine learning techniques. The proposed method involves a two-step process. In the first step, fire and non-fire images are used to train a convolutional neural network (CNN), and in the next step, feature vectors consisting of 256 values obtained from the CNN are used for the learning of a support vector machine (SVM). Linear and nonlinear SVMs with different parameters are intensively tested. We found that the proposed hybrid method using an SVM with a linear kernel effectively increased the recall rate of fire image detection without compromising detection accuracy when an imbalanced dataset was used for learning. This is a major contribution of this study because recall is important, particularly in the sensing of disaster situations such as fires. In our experiments, the proposed system exhibited an accuracy of 96.9% and a recall rate of 92.9% for test image data.

• Polymer(Korea)
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• v.39 no.1
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• pp.13-22
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• 2015

A new methacrylate copolymer that includes chalcone as a side group, poly(4-methacryloyloxyphenyl-4'-methoxystyryl ketone-co-styrene) was synthesized by free radical copolymerization. FTIR and $^1H$ NMR spectroscopic techniques were used to characterize the homopolymers and copolymers. The copolymerizations were carried out to high conversions. Copolymer compositions were established by $^1H$ NMR spectra analysis. The monomer reactivity ratios for copolymer system were determined by the linearized Kelen $T{\ddot{u}}d{\ddot{o}}s$, and Extended Kelen $T{\ddot{u}}d{\ddot{o}}s$ methods and a non-linear least squares method. The molecular weights and polydispersity index of copolymers were measured by using the gel permeation chromatography (GPC). The effect of copolymer compositions on their thermal behavior were studied by differential scanning calorimetry and thermogravimetric analysis methods. The optical properties of the resulting copolymer were also investigated.

• Geotechnical Engineering
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• v.13 no.3
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• pp.5-20
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• 1997

A governing equation of uncoupled three dimensional finite strain theory of consolidation is presented. This equation is suitable for relatively thick layers, possessing large strain, non-linear material property, and variable permeability. A special numerical solution procedure has to be adopted for the finite difference scheme because the solution is not stable in using Forward-Time Centered-Space (FTCS) method and the governing equation is highly non-linear. The solution is capable of predicting settlement with respect to time. The results predicted by the developed method of analysis have been compared with those of experimental tests on different types of highly compressible soils with vertical wick drain. The uncoupled three dimensional finite strain theory of consolidation appears to predict settlement behavior well. A detailed comparison shows good agreement in terms of total settlement, and reasonable agreement with respect to time.