• Title/Summary/Keyword: Nitrogen oxides (NOx)

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A Study for Developing an Operating Mode-Based Emission Model for Korea (한국형 운행 모드 기반 배출량 산정 모형 개발에 관한 연구)

  • HU, Hyejung;FREY, Christopher;YOON, Chunjoo;YANG, Choongheon;KIM, Jinkook
    • Journal of Korean Society of Transportation
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    • v.34 no.2
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    • pp.180-190
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    • 2016
  • Atmospheric pollutants such as Nitrogen Oxides(NOx), Carbon Monoxide(CO), Carbon Dioxide($CO_2$), Particulate Matter(PM) and Hydrocarbons(HC) come from vehicle exhaust gases. Emission curves based on average travel speeds have been employed for estimating on-road emissions as well as evaluating environmental impacts of transportation plans and policies in Korea. Recently, there is a growing interest in estimation methods of vehicle emissions considering relationship between vehicle dynamic driving characteristics and emissions, and incorporating such emission estimators into traffic simulation models. MOVES Lite, a simplified version of MOVES, is one of the estimation methods. In this study, the authors performed a study to develop an adaptable version of MOVES Lite for Korea, called MOVES Lite-K. Vehicle types, driving characteristics, emission rates, and emission standards of Korea were reflected in MOVES Lite-K. The characteristics of emission calculation of MOVES Lite-K and NIER emission curves were compared and the adaptability of MOVES Lite-K were examined.

A Study on Capacity of Electric Propulsion System by Load Analysis of 6,800TEU Container Ship (6,800TEU 컨테이너선의 부하분석을 통한 전기추진시스템 용량 연구)

  • Jang, Jae-Hee;Son, Na-Young;Oh, Jin-Seok
    • Journal of Navigation and Port Research
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    • v.42 no.6
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    • pp.437-445
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    • 2018
  • IMO (International Maritime Organization) has been strengthening the regulations of ship emission gas such as sulfur oxides (SOX), nitrogen oxides (NOX) and carbon dioxides (CO2) to protect the marine environment. Especially, ECA (Emission Control Area) has been set and operated in the USA and US. As a countermeasure against these environmental regulations, the demand for environmentally, friendly and highly efficient vessels has led to a growing interest in technology related research with respect to electric propulsion systems capable of reducing exhaust gas. Container ships were excluded from the application coverage of the electric propulsion systems for reasons of operation at economical speed. However, in the future, the need for electric propulsion system is expected to rise, because it is easy to monitor and control so that it can be an applicate to smart ship which are represented by fourth industrial revolution technology. In this study, research was carried out to design a generator and battery capacity through the load analysis of the 6,800TEU container ship to apply the electric propulsion system of the container ship. A capacity design based on the load analysis has an advantage that the generator can be operated in a high efficiency section through the load distribution control using the battery.

Trend on the Recycling Technologies for Waste Catalyst by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 폐촉매(廢觸媒) 재활용(再活用) 기술(技術) 동향(動向))

  • Lee, Jin-Young;Pak, Jong-Jin;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.22 no.2
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    • pp.53-61
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    • 2013
  • Since the 2000s, to start inducement of SCR(Selective Catalytic Reduction) denitrification facility by large scale companies which are emitted large amount of nitrogen oxides such as power plants, combined heat and power plant, incinerators and chemical plants due to take effect the regulation of stationary sources of nitrogen oxide(NOx), and the total amount of discharged pollutants, such as regulatory gradually emissions regulations are being strengthened and the expanded coverage due to the use of SCR denitrification catalyst is a growing trend. Since 2010 due to the new catalysts to replace the already installed power plants and incinerators due to inactive, and catalytic denitrification SCR waste catalyst waste as a resource rather than the development of technologies for recycling situation is urgently needed. In this study, analyzed paper and patent for recycling technologies of waste catalyst. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1975 to 2012. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.

Study on the Emission Characteristics of Air Pollutants from Agricultural Area (농업지역(밭) 암모니아 등 대기오염물질 계절별 모니터링 연구)

  • Kim, Min-Wook;Kim, Jin-Ho;Kim, Kyeong-Sik;Hong, Sung-Chang
    • Korean Journal of Environmental Agriculture
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    • v.40 no.3
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    • pp.211-218
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    • 2021
  • BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 concentration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The concentrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses collected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

Electrical resistivity characteristics for cement specimens with TiO2 according to activated carbon content (활성탄 함유량에 따른 광촉매(TiO2) 시멘트 시편의 전기비저항 특성)

  • Kong, Tae-Hyun;Lee, Jong-Won;Ye, Ji-Hun;Ahn, Jaehun;Oh, Tae-Min
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.5
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    • pp.591-610
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    • 2020
  • Concrete with activated carbon and titanium dioxide (TiO2) has been used to reduce the particulate matter (PM) in underground structures (e.g., tunnels) due to the high performance of nitrogen oxides (NOx) abatement. Damage (e.g. crack, spalling, or detachment) can be caused by the environmental and ageing effects on the surface of the particulate matter reduction concrete, installed on the tunnel lining. Therefore, it is important to evaluate the existence of spalling on the concrete surface for maintaining performance of NOx reduction. In this study, a basic research was performed for feasibility of spalling evaluation using electrical resistivity characteristics. Given the test results, the electrical resistivity was decreased as the ratios of activated carbon (0~15%) and TiO2 (0~25%) were increased for specimens. Under a dry condition, electrical resistivity of cement specimens, mixed with activated carbon and TiO2, was decreased up to 2.3 times, compared with the normal cement specimen. In addition, under saturation conditions (degree of saturation: 85~98%), electrical resistivity of cement specimens with activated carbon, was decreased up to 3.5 times, compared with the normal cement specimen. Regardless of the condition (dry or saturated), the difference of electrical resistivity values shows the range of 2.3~2.8 times between the mixing specimen (with activated carbon (15%) and TiO2 (25%)) and the normal cement specimen. This study can help to provide basic knowledge for spalling evaluation using the electrical resistivity on the surface of the particulate matter reduction concrete in tunnels.

Investigation on Diesel Injection Characteristics of Natural Gas-Diesel Dual Fuel Engine for Stable Combustion and Efficiency Improvement Under 50% Load Condition (천연가스-디젤 혼소 엔진의 50% 부하 조건에서 제동효율 및 연소안정성 개선을 위한 디젤 분무 특성 평가)

  • Oh, Sechul;Oh, Junho;Jang, Hyungjun;Lee, Jeongwoo;Lee, Seokhwan;Lee, Sunyoup;Kim, Changgi
    • Journal of the Korean Institute of Gas
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    • v.26 no.3
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    • pp.45-53
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    • 2022
  • In order to improve the emission of diesel engines, natural gas-diesel dual fuel combustion compression ignition engines are in the spotlight. In particular, a reactivity controlled compression ignition (RCCI) combustion strategy is investigated comprehensively due to its possibility to improve both efficiency and emissions. With advanced diesel direct injection timing earlier than TDC, it achieves spontaneous reaction with overall lean mixture from a homogeneous mixture in the entire cylinder area, reducing nitrogen oxides (NOx) and particulate matter (PM) and improving braking heat efficiency at the same time. However, there is a disadvantage in that the amount of incomplete combustion increases in a low load region with a relatively small amount of fuel-air. To solve this, sensitive control according to the diesel injection timing and fuel ratio is required. In this study, experiments were conducted to improve efficiency and exhaust emissions of the natural gas-diesel dual fuel engine at low load, and evaluate combustion stability according to the diesel injection timing at the operation point for power generation. A 6 L-class commercial diesel engine was used for the experiment which was conducted under a 50% load range (~50 kW) at 1,800 rpm. Two injectors with different spray patterns were applied to the experiment, and the fraction of natural gas and diesel injection timing were selected as main parameters. Based on the experimental results, it was confirmed that the brake thermal efficiency increased by up to 1.3%p in the modified injector with the narrow-angle injection added. In addition, the spray pattern of the modified injector was suitable for premixed combustion, increasing operable range in consideration of combustion instability, torque reduction, and emissions level under Tier-V level (0.4 g/kWh for NOx).

A Study on the Cold Flow Characteristics of a Flue Gas Recirculation Burner with Both Outlets Opening (양쪽 출구가 트인 배기가스 재순환 버너의 냉간 유동 특성에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.22 no.3
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    • pp.7-12
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    • 2018
  • Thermal NOx is generated in a high temperature environment in a combustion facilities. Exhaust gas recirculation method is widely used among various methods for reducing nitrogen oxides in combustion devices. In the present study, the computational fluid dynamic analysis was accomplished to elucidate the cold flow characteristics in the flue gas recirculation burner with both outlets opening. Because the reciculation pipes is installed toward the tangential direction, the swirling flow is formulated in the burner and the phenomenon of the reverse flow creation is detected at the center area of circular burner. We are confirmed that this is the similar trend with the burner with one side outlet closed. From the present study, it was seen that the recirculated inflow from both recirculated burner outlets increased by about 5% compared to the burner with one side outlet opening. At the outlet located at the exhaust gas recirculation pipe inlet(gas exit 1), the inlet flow was formed in the entire region. At the opposite outlet(gas exit 2), the total flow was discharged, but the center part of the burner was observed to have a reverse flow. The flow rate at the gas exit 2 was 3 ~ 5 times larger than the flow rate at the gas exit 1.

De-NOX evaluation of SCR catalysts adding vanadium-graphene nanocomposite (바나듐 담지된 그래핀 나노복합체를 첨가한 SCR 촉매의 제조 및 활성 평가)

  • Jeong, Bora;Lee, Heesoo;Kim, Eok-Soo;Kim, HongDae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.252-256
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    • 2015
  • Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.

Environmental Mobilization Characteristics of Total Gaseous Mercury in the Western Coast of Korea During the Yellow Sand Period, 2001 (2001년 봄철 황사기간 중 서해안지역에서 관측한 대기 중 수은의 환경유동특성 연구)

  • Kim, Min-Young;Shin, Jae-Young;Cho, Suk-Choo;Kim, Joon;Lee, Gang-Woong;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.480-490
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    • 2001
  • The soil-air exchange processes of Hg were investigated from the Hari area of Kang Hwa Island during the late March 2001. In the course of our study, we determined the concentration gradients of Hg and combined these gradient data with micrometeorological components to derive its fluxes. Results of our study indicate that the concentration levels of Hg in the study area are notably lower than those typically found in urbanized areas of Korea. However, the computed fluxes were seen to be significantly larger for relatively remote areas, reaching over 200 ng/m$^2$/hr. Comparison of environmental conditions shows that the concentrations of most pollutant species including NO$_X$ and PM were significantly higher during emission, while meteorological conditions were characterized by high temperature and low humidity. Results of correlation analysis also indicate that such pollutants as hydrocarbons, nitrogen oxides, and PM generally exhibit strong positive correlations with Hg-related parameters during emission events, while such relationships were reversed during dry deposition events. The results of our present study suggest the possibility that the concentrations and fluxes of total gaseous Hg observed during deposition events can be influenced by the processes that are also important for the fine, rather than coarse, size fraction of particles.

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A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.