Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2015.25.6.252

De-NOX evaluation of SCR catalysts adding vanadium-graphene nanocomposite  

Jeong, Bora (Green Manufacturing 3Rs R&D Group, Ulsan Regional Division, Korea Institute of Industrial Technology)
Lee, Heesoo (School of Materials Science & Engineering, Pusan National University)
Kim, Eok-Soo (Green Manufacturing 3Rs R&D Group, Ulsan Regional Division, Korea Institute of Industrial Technology)
Kim, HongDae (Green Manufacturing 3Rs R&D Group, Ulsan Regional Division, Korea Institute of Industrial Technology)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.25, no.6, 2015 , pp. 252-256 More about this Journal
Abstract
Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.
Keywords
De-$NO_X$; Graphene; Nanocompostite; Selective Catalytic Reduction; Vanadium oxide;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 G. Centi, S. Perathoner and F. Vazznana, "Oscillating behavior in $N_2O$ decomposition over Rh supported on zirconia-based catalysts: The role of the reaction conditions", J. Catal. 192 (2000) 224.   DOI
2 C.M. Schar, C.H. Onder and H.P. Geering, "Control of a urea SCR catalytic converter system for a mobile heavy duty diesel engine", SAE SP-1754 (2003) 295.
3 S.S. Park, "Thermal behavior of $TiO_2$-based honeycomb type SCR catalyst and the Influence of cell density on the reaction efficiency", Gyeongsang National University (2010).
4 J.H. Choi, M.H. Kim and I.S. Nam, "Heating element of an air preheater in a utility boiler as an SCR reactor removing NO by $NH_3$" Ind. Eng. Chem. Res. 44 (2005) 707.   DOI
5 V.I. Parvulescu, P. Grange and B. Delmon, "Cataytic removal of NO", Catal. Today 46 (1998) 223.   DOI
6 S. Broer and T. Hammer, "Selective catalytic reduction of nitrogen oxide by combining a non-thermal plasma and a $V_2O_5-WO_3/TiO_2$ catalysts", Appl. Catal. B: Environ 28 (2000) 101.   DOI
7 M. Kobayashi and K. Miyoshi, "$WO_3-TiO_2$ monolithic catalysts for high temperature SCR of NO by $NH_3$: Influence of preparation method on structural and physico chemical properties, activity and durability", Appl. Catal. B: Environ. 72 (2007) 253.   DOI
8 A.K.Geim, "Graphene: Status and prospects", Science 324 (2009) 1530.   DOI
9 C. Zhang, W. Lv, Q. Yang and Y. Liu, "Grphene supported nano particle of Pt-Ni for CO oxidation", ASS 258 (2012) 7795.
10 K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva and A.A. Firsov, "Electric field effect in atomically thin carbon films", Science 306 (2004) 666.   DOI
11 C. Wang, S. Yang, H. Chang, Y. Peng and J. Li, "Dispersion of tungsten oxide on SCR performance of $V_2O_5-WO_3/TiO_2$ : Acidity, surface species and catalystic activity", J. Chem. Engie. 225 (2013) 520.   DOI
12 B.J. Jang, "The research of reaction characteristic and the improvement of efficiency of $TiO_2$ Catalyst for SCR in high temperature", Kyinggi University (2008).
13 G. Cristallo, E. Roncari, A. Rinaldo and F. Trifiro, "Study of anatase-rutile transition phase in monolithic catalyst $V_2O_5/TiO_2$ and $V_2O_5-WO_3/TiO_2$", Appl. Catal. A 209 (2009) 249.
14 S.M. Park, "Selective catalytic reduction of nitrogen oxides promoted by storage function", Chonnam National University (2010).
15 G. Deo, A.M. Turek, I.E. Wachs, T. Machej, J. Haber, N. Das, H. Eckert and A.M. Hirt, "Physical and chemical characterization of surface vanadium oxide sup-ported on titania: influence of the titania phase (anntase, rutile, brookite and B)", Appl. Catal. A 91 (1992) 27.   DOI
16 B.Y. Kim, B.K. Shin, H.S Lee and H.H. Chun, "Physico- chemical effects of cerium oxide on catalytic activity of $CeO_2-TiO_2$ prepared by sol-gel method for $NH_3-SCR$", Korean Cryst. Growth Cryst. Technol. 23 (2013) 320.   DOI
17 S.H. Yoon, J.H. Kim, B.K. Shin, S.S. Park, D.W. Shin and H.S. Lee, "Effects of anatase-rutile phase transition and grain growth with $WO_3$ on thermal stability for $TiO_2$ SCR catalyst", J. Korean Cryst. Growth Cryst. Technol. 21 (2011) 181.   DOI