• 제목/요약/키워드: Nitrogen behavior

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HPLC-FLD를 이용한 겨울철 PM2.5 중 아미노산 성분 분석 (Determination of Amino Acids on Wintertime PM2.5 using HPLC-FLD)

  • 박다정;조인환;배민석
    • 한국대기환경학회지
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    • 제31권5호
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    • pp.482-492
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    • 2015
  • Ground-based measurements were conducted from January 6 to 12 of 2015 for understanding characteristics of nitrogen containing carbonaceous aerosols as 16 amino acids at the Mokpo National University, Korea. The detailed amino acid components such as Cystine ($(SCH_2CH(NH_2)CO_2H)_2$) and Methionine ($C_5H_{11}NO_2S$) and their sources were analyzed by High-Performance Liquid Chromatography with Fluorescence Detection (HPLC-FLD) for behavior of secondary products in particulate matter. In addition, organic carbon (OC) and elemental carbon (EC) based on the carbonaceous thermal distribution (CTD), which provides detailed carbon signature characteristics relative to analytical temperature, and water soluble organic carbon (WSOC) by total organic carbon (TOC) analyzer were used to understand the carbon compound behaviors. The backward trajectories were discussed for originations of carbonaceous aerosols as well. Different airmasses were classified with the amino acids and OC thermal signatures. The results can provide to understand the aging process influenced by the long-range transport from East Sea area.

나노복합체 nc-TiN/a-Si$_3$N$_4$ 코팅막의 합성 및 기계적 성질 (Synthesis and Mechanical Properties of nc-TiN/a-Si$_3$N$_4$ Nanocomposite Coating Layer)

  • 김광호;윤석영;김수현;이건환
    • 한국표면공학회지
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    • 제35권3호
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    • pp.133-140
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    • 2002
  • The Ti-Si-N coating layers were synthesized on SKD 11 steel substrate by a DC reactive magnetron co-sputtering technique with separate Ti and Si targets. The high resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS) analyses for the coating layers revealed that microstructure of Ti-Si-N layer was nanocomposite, consisting of nano-sized TiN crystallites surrounded by amorphous $Si_3$$N_4$ phase. The highest hardness value of about 39 GPa was obtained at the Si content of ~11at.%, where the microstructure had fine TiN crystallites (about 5nm in size) dispersed uniformly in amorphous matrix. As the Si content in Ti-Si-N films increased, the TiN crystallites became from aligned to randomly oriented microstructure, finer, and fully penetrated by amorphous phase. Free Si appeared in the layers due to the deficit of nitrogen source at higher Si content. Friction coefficient and wear rate of the Ti-Si-N coating layer significantly decreased with increase of relative humidity. The self-lubricating tribe-layers such as $SiO_2$ or (OH)$Si_2$ seemed to play an important role in the wear behavior of Ti-Si-N film against steel.

부산지역 일부 중학교 축구부 학생의 식행동, 영양섭취상태 및 혈액성상 조사 (A Study on Dietary Behaviors, Nutrients Intake Status and Hematological Status of Middle School Football Players in Busan)

  • 이정숙;김나영;이영화
    • 대한지역사회영양학회지
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    • 제13권5호
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    • pp.601-609
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    • 2008
  • The study was carried out to investigate the dietary attitude and hematological status of the middle school football players in Busan. The survey was conducted from September 15 to October 15, 2006 by questionnaires and data analyzed by the SPSS program. The results are summarized as follows: The weights and body mass indices of the football players were significantly lower than those of the control. Dietary attitude scores showed no significant differences between the groups. Nutrition knowledge scores of the football players were lower than those of the control. Both football players and the control preferred the sweet taste rather than others. The football players preferred the hot taste, meats, and fish rather than the control did. Serum triglyceride level of the football players was significantly lower than that of the control. Blood iron level was significantly lower in the football players than in the control. Blood urea nitrogen concentration was higher in the football players than in the control. Therefore proper nutritional education programs are required for middle school football players to improve their nutritional status and physical strength.

HSPF-Paddy Development for Simulating Pollutant Loadings from Paddy Fields

  • Jeon, Ji-Hong;Yoon, Chun G.;Jung, Kwang-Wook;Jang, Jae-Ho
    • 한국농공학회논문집
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    • 제47권7호
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    • pp.57-66
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    • 2005
  • The Hydrological Simulation Program - FORTRAN (HSPF) was modified to simulate nonpoint pollutant loadings from paddy fields using a field experimental data collected during 2001-2002. The concept of a 'dike height' was added in a modified HSPF code, named HSPF-Paddy, to consider the function of retaining water by a weir at the field outlet. The effect of fertilization on the variances of nutrients on the soil surface and shallow soil layer was described mathematically with a Dirac delta function (or first-order kinetics). As confirmed through model verification, the HSPF-Paddy modifications were shown to represent the function of retaining water, varied ponded water, and surface runoff by forced drain during both rainy and non-rainy seasons and reasonably predicted the water balance and nutrients behavior in paddy fields. It is a distributed watershed model which, with the paddy modifications, can now simulate nonpoint pollutant loadings where paddy fields are dominant, and it can be used to evaluate the effects of paddy fields on the water quality at a basin scale, and assess the impacts of proposed BMPs applied to paddy fields.

탄성지지된 엔진, 고정지지된 발전기 및 탄성 커플링으로 구성된 발전기 세트의 엔진 본체 진동 특성에 관한 사례 연구 (A Case Study on the Engine Body Vibration Characteristics of Generator Set consists of Engine-resilient-mounted, Generator-rigid-mounted and Flexible-coupling)

  • 김효정;김상환;이돈출
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2014년도 춘계학술대회 논문집
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    • pp.443-446
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    • 2014
  • Recently the demand for natural gas as clean and safe energy due to concerns about global warming and interests in green ship is increasing. The dual fuel(DF) engine, one of environmentally friendly engines, is preferred for general merchant ships and power plants as well as LNG carriers. This is for the reasons of having higher efficiency and lower nitrogen and sulfur oxides emissions by operating on LNG fuel with a small amount of light fuel oil. In this study, the engine body vibration characteristics of 12V50DF in a generator set with engine-resilient-mounted, generator-rigid-mounted and flexible-coupling configuration are investigated through theoretical analysis and comprehensive vibration measurement. This analysis showed the dynamic behavior of engine excitation forces and seismic waves. And the suitable countermeasures for reducing vibration and safe operation are proposed.

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아조(Azo)화합물 열분해특성 (Thermal Decomposition Characteristics of Azo compounds)

  • 김관응
    • 한국안전학회지
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    • 제17권2호
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    • pp.39-44
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    • 2002
  • This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

Twin-jet 대향류에서 메탄 비예혼합화염에 대한 수치적 연구 (Numerical Study on Non-premixed Methane Flames in Twin-jet Counterflow)

  • 천강우;김준홍;정석호
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.49-56
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    • 2004
  • A two-dimensional twin-jet counterflow system has been designed, in which two streams from two double-slit nozzles form a counterflow. This flow system enables one to systematically investigate various effects on non-premixed flames, including the non-premixed flame interaction, the edge flame behavior and the effect of curvature. Non-premixed flame interaction in the twin-jet counterflow system has been investigated numerically for methane fuel diluted with nitrogen. Three types of non-premixed flame(conventional counterflow flame, crossed twin-jet flame and petal shaped flame) were simulated depending on the combination of fuel/oxidizer supply to each nozzle. The extinction characteristics of non premixed methane flame in the twin-jet counterflow have been investigated numerically. The boundary of the existence of petal-shaped flames was identified for the twin-jet counterflow flames. Due to the existence of the unique petal-shaped flames, the extinction boundary for the twin-jet counterflow can be extended significantly compared to that for the conventional counterflow non-premixed flames, through the interaction of two flames. Through the comparison of the crossed twin-jet flame and the conventional counterflow flame, structure of the crossed twin-jet counterflow flame is analysed. Through the comparison of the petal shaped flame and the conventional counterflow flame, the extension of the extinction boundary for the twin-jet counterflow is investigated.

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Microstructural Change and Magnetic Properties of Nanocrystalline Fe-Si-B-Nb-Cu Based Alloys Containing Minor Elements

  • Nam, Seul-Ki;Moon, Sun-Gyu;Sohn, Keun Yong;Park, Won-Wook
    • Journal of Magnetics
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    • 제19권4호
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    • pp.327-332
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    • 2014
  • The effect of minor element additions (Ca, Al) on microstructural change and magnetic properties of Fe-Nb-Cu-Si-B alloy has been investigated, in this paper. The Fe-Si-B-Nb-Cu(-Ca-Al) alloys were prepared by arc melting in argon gas atmosphere. The alloy ribbons were fabricated by melt-spinning, and heat-treated under a nitrogen atmosphere at $520-570^{\circ}C$ for 1 h. The soft magnetic properties of the ribbon core were analyzed using the AC B-H meter. A differential scanning calorimetry (DSC) was used to examine the crystallization behavior of the amorphous alloy ribbon. The microstructure was observed by X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscope (SEM). The addition of Ca increased the electrical resistivity to reduce the eddy current loss. And the addition of Al decreased the intrinsic magnetocrystalline anisotropy $K_1$ resulting in the increased permeability. The reduction in the size of the ${\alpha}$-Fe precipitates was observed in the alloys containing of Ca and Al. Based on the results, it can be concluded that the additions of Ca and Al notably improved the soft magnetic properties such as permeability, coercivity and core loss in the Fe-Nb-Cu-Si-B base nanocrystalline alloys.

2단계 가스압 소결에 의한 질화규소의 치밀화 (Densification of $Si_3N_4$ Cera,ocs by Two Step Gas Pressure Sintering)

  • 이상호
    • 한국세라믹학회지
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    • 제35권7호
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    • pp.659-664
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    • 1998
  • 구조재료용 요업체로 널리 쓰이는 질화규소 요업체를 2단계 가스압 소결 방식에 의해 치밀화시켰을 때의 효과를 상압조절, 단순 가스압소결 또는 HIP 처리시와 비교하였다. 상압 소결시에는 $1800^{\circ}C$ 이상에서 분해가 일어나지만 질소 가스에 의한 가스압 소결시에는 소결 온도를 더 높일 수 있어서 ${\beta}-Si_3N_4$ 침상 조직의 발달을 이룰 수 있었다. 질소 가스압이 2MPa 정도이면 $1890^{\circ}C$까지도 상압소결시에 비해 분해가 현저히 억제될 수 있어서, 폐기공이 형성될 수 있는 단계까지는 분해만 억제시킬 수 있는 정도의 비교적 낮은 압력으로 치밀화시키고, 이어서 10MPa의 높은 압력을 가하는 소위 2단계 가스압 소결시 경도와 인성이 증진되는 것을 확인할 수 있었다.

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다공성 매질에서 액화질소의 거동에 대한 연구 (STUDY ON BEHAVIOR OF LIQUID NITROGEN IN POROUS MEDIA)

  • 최성웅;이우일
    • 한국전산유체공학회지
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    • 제18권2호
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    • pp.17-25
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    • 2013
  • The process of flow through porous media is of interest a wide range of engineering fields and areas, and the importance of fluid flow with a change in phase arises from the fact that many industrial processes rely on these phenomena for materials process, energy transfer. Especially, the flow phenomena of cryogenic liquid subjected to evaporation is of interest to investigate how the cryogenic liquid behaves in the porous structure. In this study, thermo physical properties, morphological properties of the glass wool with different bulk densities in terms of its temperature-dependence and permeability behaviors under different applying pressure are discussed. Using the experimentally determined properties, characteristics of two main experimental results are investigated. In addition, simulation results are used to realize the cryogenic liquid's flow in porous media, and are compared with experimental results. By using the experimentally determined properties, more reasonable results can be suggested in dealing with porous media flow.