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http://dx.doi.org/10.5572/KOSAE.2015.31.5.482

Determination of Amino Acids on Wintertime PM2.5 using HPLC-FLD  

Park, Da-Jeong (Department of Environmental Engineering, Mokpo National University)
Cho, In-Hwan (Department of Environmental Engineering, Mokpo National University)
Bae, Min-Suk (Department of Environmental Engineering, Mokpo National University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.31, no.5, 2015 , pp. 482-492 More about this Journal
Abstract
Ground-based measurements were conducted from January 6 to 12 of 2015 for understanding characteristics of nitrogen containing carbonaceous aerosols as 16 amino acids at the Mokpo National University, Korea. The detailed amino acid components such as Cystine ($(SCH_2CH(NH_2)CO_2H)_2$) and Methionine ($C_5H_{11}NO_2S$) and their sources were analyzed by High-Performance Liquid Chromatography with Fluorescence Detection (HPLC-FLD) for behavior of secondary products in particulate matter. In addition, organic carbon (OC) and elemental carbon (EC) based on the carbonaceous thermal distribution (CTD), which provides detailed carbon signature characteristics relative to analytical temperature, and water soluble organic carbon (WSOC) by total organic carbon (TOC) analyzer were used to understand the carbon compound behaviors. The backward trajectories were discussed for originations of carbonaceous aerosols as well. Different airmasses were classified with the amino acids and OC thermal signatures. The results can provide to understand the aging process influenced by the long-range transport from East Sea area.
Keywords
Amino acid; Organic carbon; Molecular marker;
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1 Akyuz, M. and S. Ata (2006) Simultaneous determination of aliphatic and aromatic amines in water and sediment samples by ion-pair extraction and gas chromatographyemass spectrometry, J. Chromatogr. A, 1129, 88-94.   DOI   ScienceOn
2 Aznar, M., E. Canellas, and C. Nerin (2009) Quantitative determination of 22 primary aromatic amines by cation-exchange solid-phase extraction and liquid chromatographyemass spectrometry, J. Chromatogr. A, 1216, 5176-5181.   DOI   ScienceOn
3 Bae, M.S., J. Schauer, J. DeMinter, J. Turner, D. Smith, and R. Cary (2004) Validation of a semi-continuous instrument for elemental carbon and organic carbon using a thermal-optical method, Atmos. Environ., 38, 2885-2893.   DOI   ScienceOn
4 Bae, M.S., S.S. Park, and Y.J. Kim (2013) Characteristics of carbonaceous aerosols measured at Gosan- Based on analysis of thermal distribution by carbon analyzer and organic compounds by GCMS, J. Korean Soc. for Atmos. Environ., 6, 722-733.
5 Busca, G. and C. Pistarino (2003) Abatement of ammonia and amines from waste gases: a summary, J. Loss Prev. Process Ind., 16, 157-163.   DOI   ScienceOn
6 Carlsen, L., O.A. Kenesova, and S.E. Batyrekova (2007) A preliminary assessment of the potential environmental and human health impact of unsymmetrical dimethylhydrazine as a result of space activities, Chemosphere, 67, 1108-1116.   DOI   ScienceOn
7 Clegg, S.L., M.J. Kleeman, R.J. Griffin, and J.H. Seinfeld (2008) Effects of uncertainties in the thermodynamic properties of aerosol components in an air quality modelepart 1: treatment of inorganic electrolytes and organic compounds in the condensed phase, Atmos. Chem. Phys., 8, 1057-1085.   DOI
8 Draxler, R.R. and G.D. Rolph (2015) HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website (http://www.arl.noaa.gov/HYSPLIT.php), NOAA Air Resources Laboratory, College Park, MD.
9 Facchini, M.C., M. Mircea, S. Fuzzi, and R.J. Charlson (1999) Cloud albedo enhancement by surface-active organic solutes in growing droplets, Nat., 401, 257-259.   DOI
10 Filippo, P.D., D. Pomata, C. Riccardi, F. Buiarelli, V. Gallo, and A. Quaranta (2014) Free and combined amino acids in size-segregated atmospheric aerosol samples, Atmos. Environ., 98, 179-189.   DOI   ScienceOn
11 Gray, H.A., G.R. Cass, J.J. Huntzicker, E.K. Heyerdahl, and J.A. Rau (1986) Characteristics of atmospheric organic and elemental carbon particle concentrations in Los Angeles, Environ. Sci. Technol., 20, 580-589.   DOI   ScienceOn
12 Ge, Xinlei, A.S. Wexler, and S.L. Clegg (2011) Atmospheric amines e Part I. A review, Atmos. Environ., 45, 524-546.   DOI   ScienceOn
13 Gibb, S.W., R.F.C. Mantoura, and P.S. Liss (1995) Analysis of ammonia and methylamines in natural waters by flow injection gas diffusion coupled to ion chromatography, Anal. Chim. Acta., 316, 291-304.   DOI   ScienceOn
14 Gibb, S.W., R.F.C. Mantoura, and P.S. Liss (1999) Oceanatmosphere exchange and atmospheric speciation of ammonia and methylamines in the region of the NW Arabian Sea, Global Biogeochem. Cycles, 13, 161-178.   DOI   ScienceOn
15 Greim, H., H.J. Klimisch, M. Oeben-Negele, and K. Ziegler- Skylakakis (1998) Toxicity of aliphatic amines: structure-activity relationship, Chemosphere, 36, 271-295.   DOI   ScienceOn
16 Grimmer, G., K.W. Naujack, and G. Dettbarn (1987) Gas chromatographic determination of polycyclic aromatic hydrocarbons, aza-arenes, aromatic amines in the particle and vapor phase of mainstream and sidestream smoke of cigarettes, Toxicol. Lett., 35, 117-124.   DOI   ScienceOn
17 Kieber, R.J., M.S. Long, and J.D. Willey (2005) Factors influencing nitrogen speciation in coastal rainwater, J. Atmos. Chem., 52, 81-99.   DOI
18 Leach, J., A. Blanch, and A.C. Bianchi (1999) Volatile organic compounds in an urban airborne environment adjacent to a municipal incinerator, waste collection centre and sewage treatment plant, Atmos. Environ., 33, 4309-4325.   DOI   ScienceOn
19 Lee, Y., M. Park, S. Jung, S. Kim, M. Jo, I. Song, Y. Lyu, Y. Lim, J. Kim, H. Jung, S. Lee, W. Choi, J. Ahn, M. Lee, H. Kang, S. Park, S. Seo, D. Jung, J. Hyun, J. Park, T. Hwang, Y. Hong, J. Hong, and H. Shin (2015) Characteristics of Particulate Carbon in the Ambient Air in the Korean Peninsula, J. Korean Soc. for Atmos. Environ., 31, 330-344.   DOI
20 Lee, T., J. Choi, G. Lee, J. Ahn, J. Park, S.A. Atwood, M. Schurman, Y. Choi, Y. Chung, and J.L. Collett Jr. (2015) Characterization of aerosol composition, concentrations, and sources at Baengnyeong Island, Korea using an aerosol mass spectrometer, Atmos. Environ., 120, 297-306.   DOI   ScienceOn
21 Murphy, S.M., A. Sorooshian, J.H. Kroll, N.L. Ng, P. Chhabra, C. Tong, J.D. Surratt, E. Knipping, R.C. Flagan, and J.H. Seinfeld (2007) Secondary aerosol formation from atmospheric reactions of aliphatic amines, Atmos. Chem. Phys., 7, 2313-2337.   DOI
22 Park, D.J., J.Y. Ahn, H.J. Shin, and M.S. Bae (2014) Characteristics of $PM_{2.5}$ Carbonaceous Aerosol using PILSTOC and GC/MS-TD in Seoul, J. Korean Soc. for Atmos. Environ., 30, 461-476.   DOI   ScienceOn
23 Rappert, S. and R. Muller (2005) Odor compounds in waste gas emissions from agricultural operations and food industries, Waste Manage. Res., 25, 887-907.   DOI   ScienceOn
24 Schade, G.W. and P.J. Crutzen (1995) Emission of aliphatic amines from animal husbandry and their reactions: potential source of $N_2O$ and HCN, J. Atmos. Chem., 22, 319-346.   DOI
25 Schauer, J.J., M.J. Kleeman, G.R. Cass, and B.R.T Simoneit (1999) Measurement of emissions from air pollution sources. 1. C1 through C29 organic compounds from meat charbroiling, Environ. Sci. Technol., 33, 1566-1577.   DOI   ScienceOn
26 Sullivan, A.P., R.J. Weber, A.L. Clements, J.R. Turner, M.S. Bae, and J.J. Schauer (2004) A method for on-line measurement of water-soluble organic carbon in ambient aerosol particles: Results from an urban site, Geophys. Res. Lett., 31, L13105.   DOI   ScienceOn
27 Schauer, J.J., W.F. Rogge, L.M. Hildemann, M.A. Mazurek, and G.R. Cass (1996) Source apportionment of airborne particulate matter using organic compounds as tracers, Atmos. Environ., 30, 3837-3855.   DOI   ScienceOn
28 Silva, P.J., M.E. Erupe, D. Price, J. Elias, O.G. Malloy, Q. Li, B. Warren, and D.R. Cocker III (2008) Trimethylamine as precursor to secondary organic aerosol formation via nitrate radical reaction in the atmosphere, Environ. Sci. Technol., 42, 4689-4696.   DOI   ScienceOn
29 Smith, J.N., K.C. Barsanti, H.R. Friedli, M. Ehn, M. Kulmala, D.R. Collins, J.H. Scheckman, B.J. Williams, and P.H. McMurry (2010) Observations of aminium salts in atmospheric nanoparticles and possible climatic implications, Proc. Natl. Acad. Sci., 107, 66434-66439.
30 Willey, J.D., R.J. Kieber, M.S. Eyman, and G.B. Avery Jr. (2000) Rainwater dissolved organic carbon: concentrations and global flux, Global Biogeochem. Cycles, 14, 139-148.   DOI   ScienceOn