• Title/Summary/Keyword: Nitrogen Oxides

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Methane Production and Nitrogen Removal from Piggery Wastewater in the TPAD Coupled with BNR Process (질소제거공정과 결합한 2상 혐기성 소화공정에서 돈분폐수의 메탄생성 및 질소제거)

  • Park, Noh-Back;Park, Sang-Min;Choi, Woo-Young;Jun, Hang-Bae
    • Journal of Korean Society on Water Environment
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    • v.25 no.1
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    • pp.18-25
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    • 2009
  • Nitrogen removal and methane production from piggery wastewater were investigated in two-phase anaerobic digestion (TPAD) coupled with biological nitrogen removal (BNR) process at $35^{\circ}C$. Methane production rate was about $0.7L/L{\cdot}day$ at organic loading rate (OLR) of $1.2g{\cdot}TCOD/L{\cdot}day$ in methanogenic UASB. Conversion efficiency of the removed TCOD into methane in UASB was as high as 72% and overall TCOD removal efficiency in this system was over 97%. Ammonia nitrogen were stably removed in BNR system and overall efficiency were 98%. With recirculation of the nitrified final effluent to TPAD, nitrogen oxides were completely removed by anaerobic denitrification in the acidogenic reactor, which did not inhibit the acidogenic activities. Overall TN removal efficiency in the TPAD-BNR system was as high as 94%.

Effect of the Intake Valve Opening Timings and Fuel Injection Pressures on the Exhaust Emission Characteristics of a Gasoline Engine at Part Load Condition

  • Lee, Hyung-Min;Jeong, Yeon-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.3
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    • pp.317-322
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    • 2011
  • This work has investigated the exhaust emissions such as Total Hydrocarbon (THC), Nitrogen Oxides(NOx), and Particulate Matter (PM) characteristics emitted from the tail-pipe of a continuously variable valve timing (CVVT) gasoline-fueled engine with different intake valve opening timings and injection pressures at the part load condition. Valve overlap period was varied from $40^{\circ}CA$ to $10^{\circ}CA$ and fuel injection pressure was increased from 3.5 bar to 5.0 bar. THC and NOx emissions decreased as intake valve opening timing was advanced regardless of fuel injection pressure. When the fuel was injected with the condition of 5.0 bar at all of valve overlap ranges, THC levels were reduced by 55%. NOx concentrations were diminished about 75% as valve overlap increased. PM size distributions were analyzed as bi-modal type of the nucleation and accumulation mode. Comparing with fuel injection pressures, PM emission levels were decreased at high pressure injection of 5.0 bar condition.

Effect of Mixing Ratio of n-heptane Fuel on the Combustion Characteristics of n-butanol Fuel (n-heptane 연료 혼합비에 따른 n-butanol 연료의 연소 특성)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.20 no.3
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    • pp.21-26
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    • 2015
  • This study was performed to provide the information of the combustion characteristics of n-butanol fuel in accordance with the n-heptane fuel mixing ratio. The closed homogeneous reactor model was used for the analysis. The analysis conditions were set to 800 K of the initial temperature, 20 atm of initial pressure and 1.0 of equivalence ratio. The results of analysis were compared in terms of combustion temperature, combustion pressure, CO, Soot and $NO_X$ emissions. The results of combustion and exhaust emission characteristics showed that ignition delay was decreased and the combustion temperature was increased as the n-heptane mixing ratio was increased. Also, the carbon monoxide(CO) was slightly decreased however, the soot and nitrogen oxides($NO_X$) increased a little in accordance with the n-heptane fuel mixing ratio. In addition, the pressure difference was almost the same in any conditions.

Performance and emission characteristics of biodiesel blends in a premixed compression ignition engine with exhaust gas recirculation

  • Kathirvelu, Bhaskar;Subramanian, Sendilvelan
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.294-301
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    • 2017
  • This paper is based on experiments conducted on a stationary, four stroke, naturally aspirated air cooled, single cylinder compression ignition engine coupled with an electrical swinging field dynamometer. Instead of 100% diesel, 20% Jatropha oil methyl ester with 80% diesel blend was injected directly in engine beside 25% pre-mixed charge of diesel in mixing chamber and with 20% exhaust gas recirculation. The performance and emission characteristics are compared with conventional 100% diesel injection in main chamber. The blend with diesel premixed charge with and without exhaust gas recirculation yields in reduction of oxides of nitrogen and particulate matter. Adverse effects are reduction of brake thermal efficiency, increase of unburnt hydrocarbons (UBHC), carbon monoxide (CO) and specific energy consumption. UBHC and CO emissions are higher with Diesel Premixed Combustion Ignition (DPMCI) mode compared to compression ignition direct injection (CIDI) mode. Percentage increases in UBHC and CO emissions are 27% and 23.86%, respectively compared to CIDI mode. Oxides of nitrogen ($NO_x$) and soot emissions are lower and the percentage decrease with DPMCI mode are 32% and 33.73%, respectively compared to CIDI mode.

Atmospheric Photochemistry in Low-and High-NOx Regimes

  • Kim, Do-Yong;Soda, Satoshi;Kendo, Akira;Oh, Jai-Ho
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.1-8
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    • 2007
  • Atmospheric photochemistry of $O_3-NOx-RH$ were considered theoretically, to clarify the reasons for the different trends of between the formation of photochemical oxidants (Ox) and its primary pollutants for the Low-and High-NOx regimes. Equations of OH, $HO_2$, and production of ozone ($O_3$) as a function of nitrogen oxides (NOx) and reactive hydrocarbons (RH) were represented in this study. For the Low-NOx regime, $HO_2$ radical is proportional to RH but independent of NOx. OH radical is proportional to NOx but inversely-proportional to RH. $O_3$ production is proportional to NOx but has a weak dependence on RH. For the High-NOx regime, OH and $HO_2$ radicals concentrations and $O_3$ production are proportional to RH but inversely-proportional to NOx. In addition, the Osaka Bay and surrounding areas of Japan were evaluated with the mass balance of odd-hydrogen radicals (Odd-H) using CBM-IV photochemical mechanism, in order to distinguish the Low- and High-NOx regimes. The Harima area (emission ratio, RH/NOx = 6.1) was classified to the Low-NOx regime. The Hanshin area (RH/NOx = 3.5) and Osaka area (RH/NOx = 4.3) were classified to the High-NOx regime.

A Study on the Usability of Biodiesel Fuel Derived from Rice Bran Oil as an Alternative Fuel for IDI Diesel Engine

  • Ryu, Kyunghyun;Oh, Youngtaig
    • Journal of Mechanical Science and Technology
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    • v.17 no.2
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    • pp.310-317
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    • 2003
  • The world is faced with a problem of air pollution due to the exhaust emissions from automobile. Recently, lots of researchers have been attracted to develope various alternative fuels and to use renewable fuels as a solution of these problems. There are many alternative fuels studied in place of diesel fuel made from petroleum. Biodiesel fuel (BDF) is a domestically produced. renewable fuel that can be manufactured from vegetable oils, used vegetable oils, or animal fats. In this study, the usability of BDF, one of the oxygenated fuels as an alternative fuel for diesel engines was investigated in an IDI diesel engine. Emissions were characterized with a neat BDF and with a blend of BDF and conventional diesel fuel. Since the BDF includes oxygen of about 11 %, it could influence the combustion process strongly. Therefore, the use of BDF resulted in lower emissions of carbon monoxide and smoke emissions with some increase in emissions of oxides of nitrogen. It is concluded that BDF can be utilized effectively as a renewable fuel for IDI diesel engines.

Electricial properties of oxynitride films prepared by furnace oxidation in $N_2O$ ($N_2O$ 가스에서 형성된 oxynitride막의 전기적 특성)

  • Bae, Sung-Sig;Seo, Yong-Jin;Kim, Tae-Hyung;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.90-93
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    • 1992
  • In this paper, MOS characteristics of gate dielectrics prepared by furnace oxidation of Si in an $N_2O$ ambient have been studied. Compared with the oxides grown in $O_2$, $N_2O$ oxides show significantly improved breakdown field and low flat band voltage. Also, $N_2O$ oxide is more controllable for ultrathin film growth than $O_2$ oxide. This improvement is caused by nitrogen incorporation into the $N_2O$ oxide. Therefore, the nitrogen-rich-layer at the Si/$SiO_2$ interface formed during $N_2O$ oxidation not only strengthen $N_2O$ oxide structure at the interface and improves the gate dielectric quality, it also acts as a oxidant diffusion barrier that reduces the oxidation rate significantly.

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Effects of Pitch Length of Stack-type EGR Cooler on Heat Exchange Characteristics in a Diesel Engine (적층형 EGR Cooler의 Pitch 길이 변화가 열교환 특성에 미치는 영향)

  • Hwang, Se-Joon;Kim, Min-Chol;Jang, Sang-Hoon;Kim, Hyung-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.2
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    • pp.135-140
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    • 2010
  • An important goal in diesel engine research is the development of a means to reduce the emissions of nitrogen oxides (NOX). The use of a cooled exhaust gas recirculation (EGR) system is one of the most effective techniques currently available for reducing nitrogen oxides. Since Particular Matter (PM) fouling reduces the efficiency of an EGR cooler, a trade-off exists between the amount of NOX and PM emissions, especially at high engine loads. In the present study, engine dynamometer experiments have been performed to investigate the heat exchange characteristics of the stack-type EGR coolers with wave fin pitches of 3.6 and 4.6 mm. The results show that the heat exchange effectiveness is decreased as surface area decrease with pitch of 4.6 mm due to PM fouling. As surface area increase at pitch of 3.6 mm, super-cooling happens in the recirculated exhaust gas.

Effects of Two-Stage Injection on Combustion and Exhaust Emission Characteristics in a HCCI Engine (2단분사법에 따른 예혼합압축착화엔진의 연소 및 배기특성)

  • Kook, Sang-Hoon;Park, Cheol-Woong;Choi, Wook;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.5
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    • pp.32-39
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    • 2004
  • HCCI (Homogeneous Charge Compression Ignition) combustion has a great advantage in reducing NOx (Nitrogen Oxides) and PM (Particulate Matter) by lowering the combustion temperature due to spontaneous ignitions at multiple sites in a very lean combustible mixture. However, it is difficult to make a diesel-fuelled HCCI possible because of a poor vaporability of the fuel. To resolve this problem, the two-stage injection strategy was introduced to promote the ignition of the extremely early injected fuel. The compression ratio and air-fuel ratio were found to affect not only the ignition, but also control the combustion phase without a need for the intake-heating or EGR (Exhaust Gas Recirculation). The ignition timing could be controlled even at a higher compression ratio with increased IMEP (Indicated Mean Effective Pressure). The NOx (Nitrogen Oxides) emission level could be reduced by more than 90 % compared with that in a conventional DI (Direct Injection) diesel combustion mode, but the increase of PM and HC (Hydrocarbon) emissions due to over-penetration of spray still needs to be resolved.