• Title/Summary/Keyword: Nitrogen Oxides

Search Result 462, Processing Time 0.021 seconds

The addition of nitrogen oxides for improving the rate of catalytic ozone-induced oxidation of soot (산화질소 첨가에 의한 오존 기반 탄소입자상물질 촉매연소반응 속도의 개선)

  • Lee, Namhun;Park, Tae Uk;Lee, Jin Soo;Lee, Dae-Won
    • Journal of Industrial Technology
    • /
    • v.39 no.1
    • /
    • pp.1-5
    • /
    • 2019
  • In this study, we examined the effect of NO addition on the ozone-induced soot oxidation activity of $LaMnO_3$ perovskite catalysts. The addition of 10~20% NO ($NO_2$) with respect to the concentration of ozone effectively enhanced the rate of ozone-induced soot oxidation rate over $LaMnO_3$. However, the excessive addition of NO ($NO_2$) was detrimental to ozone-induced soot oxidation activity. It is supposed nitrogen oxides would adsorb on the catalyst and then react with carbon-oxygen species developed on soot surface, but an excessive addition of nitrogen oxide would inhibit the formation of carbon-oxygen species, which is a key intermediate in the reaction, and consequently suppress the oxidation rate of soot.

An Experimental Study on NOx Reduction in Exhaust Gas from Agricultural Diesel Engine with Plasma and Catalyst (플라즈마와 촉매를 이용한 농용 디젤기관 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 이승규;조기현;황의현
    • Journal of Biosystems Engineering
    • /
    • v.24 no.6
    • /
    • pp.465-472
    • /
    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

  • PDF

An Experimental Study on Effect of Plasma for Exhaust Emissions in Small High-Speed Diesel Engine (소형 고속 디젤엔진의 배기 배출물에 미치는 플르즈마의 영향에 관한 실험적 연구)

  • 백태실
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.23 no.6
    • /
    • pp.755-760
    • /
    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conver-sion to $NO_2$ and /or $HNO_3$ due to high activation energies for NO oxidation and reduction, NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

  • PDF

The need to develop Nitrogen Oxides(NOx) Reduction Equipment and Regulation in Marine (선박용 질소산화물(NOx) 저감장치 개발의 필요성 및 규제현황)

  • Kim, Sungyun;Kim, Min
    • 한국연소학회:학술대회논문집
    • /
    • 2012.04a
    • /
    • pp.69-74
    • /
    • 2012
  • Looming global environmental pollution problems around the world movement to minimize the environmental pollution is actively taking place. International Maritime Organization (IMO) a significant portion of the marine pollution by exhaust gases emitted from vessel considered, and accordingly developed around the ship and ship-related environmental regulations, emission standards are going to strengthen gradually, the development of environmentally friendly vessels and equipment is proceeding actively.

  • PDF

An Experimental Stduy on NOx Reduction in Exhaust Gas from Diesel Engine with Plasma (플라즈마를 이용한 디젤엔진 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 조기현;황의현
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.7 no.8
    • /
    • pp.83-90
    • /
    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

  • PDF

Electrical and Reliability properties of MOS capacitors with $N_{2}O$ oxides ($N_{2}O$ 산화막을 갖는 MOS 캐패시터의 전기적 및 신뢰성 특성)

  • 이상돈;노재성;김봉렬
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.31A no.6
    • /
    • pp.117-127
    • /
    • 1994
  • In this paper, electrical and reliability properties of N$_2$O oxides, grown at the temperature of 95$0^{\circ}C$ and 100$0^{\circ}C$ to 74$\AA$, and 82$\AA$. respectively, using NS12TO gas in a conventional furnace, have been compared with those of pure oxide grown at the temperature of 850 to 84$\AA$ using O$_2$ gas. Initial IS1gT-VS1gT characteristics of N$_2$O oxides were similar to those of pure oxide, and reliability properties of N$_2$O oxides, such as charge trapping, interface state density and leakage current at low electric field under F-N stress, were improved much better than those of pure oxide. But, with increasing capacitor area. TDDB characteristics of N$_2$O oxides were more degraded than those of pure oxide and this degradation of TDDB characteristics was more severe in 100$0^{\circ}C$ N$_2$Ooxide than in 95$0^{\circ}C$ N$_2$O oxide. The improvement of reliability properties excluding TDDB in N$_2$Ooxides was attributed to the hardness of the interface improved by nitrogen pile-up at the interface of Si/SiO$_2$, but on the other hand, the degradation of TDDB characteristics in N$_2$O oxides was obsered due to the increase of local thinning spots caused by excessive nitrogen at interface during the growth of N$_2$O oxides.

  • PDF

Biological Removal of Nitrogen Oxides from Combustion Flue Gases (연소배가스 중 질소산화물(NOx) 제거를 위한 생물학적 기술)

  • Lee, Ki-Say
    • Applied Chemistry for Engineering
    • /
    • v.21 no.3
    • /
    • pp.243-251
    • /
    • 2010
  • Nitrogen oxides (NOx) in combustion flue gas are currently mitigated by chemical processes such as catalytic reduction, absorption and adsorption. However, development of environmentally sustainable biological processes is necessary in the near future. In this paper, the up-to-dated R&D trend of biological methodologies regarding NOx removal was reviewed, and their advantages and disadvantages were discussed. The principles and applications of bacterial system including nitrification and denitrification and photosynthetic microalgae system were compared. In order to enhance biological treatment rate and performance, the insoluble nitric oxide (NO) should be first absorbed using a proper solubilization agent, and then microbial degradation or fixation is to be followed. The use of microalgal system has a good prospect because it can fix $CO_2$ and NOx simultaneously and requires no additional carbon for energy source.

Comparison of Exhaust Gas Recirculation and Excess Air Strategies for Improving Thermal Efficiency and Reducing Nitrogen Oxides emissions in Hydrogen Spark-ignition Engines at Low-load Operation (수소 스파크점화 엔진의 저부하 운전에서 열효율 및 질소산화물 배출 개선을 위한 배기가스재순환과 과잉공기 전략 비교)

  • Hyunwook Park;Junsun Lee;Seungmook Oh;Yonggyu Lee;Changup Kim
    • Journal of ILASS-Korea
    • /
    • v.29 no.2
    • /
    • pp.60-67
    • /
    • 2024
  • This study compared exhaust gas recirculation (EGR) and excess air strategies for improving thermal efficiency and emissions of hydrogen combustion engines at low-load operation. The experimental investigation was conducted in a single-cylinder, heavy-duty engine under throttling and wide-open throttle (WOT) conditions. Although both EGR and excess air strategies reduced peak heat release rates and increased combustion durations, the net indicated thermal efficiencies were improved by reducing the pumping losses. Under the constraint of similar nitrogen oxides emissions, the EGR strategy had higher net indicated thermal efficiencies compared to the excess air strategy in throttling operation. However, the difference between their thermal efficiencies was reduced under WOT condition. The trend of reducing nitrogen oxides emissions according to the two strategies was similar.

Computational Analysis of Nitrogen Oxides Reduction in Exhaust Gas from Livestock Manure Solid Fuel Using Urea-based Selective Non-catalytic Reduction (우레아 기반 SNCR 적용에 따른 가축분뇨 고체연료 배기가스 NOx 저감에 대한 전산해석)

  • Donghwan Shin;Hyeongwon Lee;Junghwan Kim;Jongyoung Jo
    • New & Renewable Energy
    • /
    • v.20 no.3
    • /
    • pp.1-11
    • /
    • 2024
  • Livestock manure solid fuel has been studied as a promising domestic energy resource for reducing greenhouse gas emissions in agricultural fields. To successfully commercialize this technology, the environmental facilities require optimization in accordance with domestic environmental standards. In the present study, a computational analysis model of a livestock manure solid fuel boiler system was developed using Aspen Plus® to investigate nitrogen oxides (NOx) emissions and NOx conversion efficiency using urea-based selective non-catalytic reduction (SNCR). All data were compared across different livestock species and simulated at various operating temperatures. The simulation showed that NOx emissions were the highest from chicken manure and the lowest from swine manure. However, when converted to an oxygen concentration of 12%, NOx emissions were the highest from cattle manure. Dominant factors influencing NOx emissions through a range of temperatures were analyzed, and the optimal operating temperature range (875-950℃) was derived.

Size and Shape Effect of Metal Oxides on Hydrocarbon Selective Catalytic Reduction of Nitrogen Oxides (금속 산화물 촉매의 크기와 형태에 따른 질소산화물의 탄화수소 선택적 촉매환원 특성)

  • Ihm, Tae-Heon;Jo, Jin-Oh;Hyun, Young Jin;Mok, Young Sun
    • Journal of the Korean Institute of Gas
    • /
    • v.19 no.5
    • /
    • pp.20-28
    • /
    • 2015
  • This work investigated the size and shape effect of ${\gamma}$-alumina-supported metal oxides on the hydrocarbon selective catalytic reduction of nitrogen oxides. Several metal oxides including Ag, Cu and Ru were used as the catalysts, and n-heptane as the reducing agent. For the Ag/${\gamma}$-alumina catalyst, the $NO_x$ reduction efficiency in the range of $250{\sim}400^{\circ}C$ increased as the size of Ag decreased (20 nm>50 nm>80 nm). The shape effect of metal oxides on the $NO_x$ reduction was examined with spherical- and wire-shape nanoparticles. Under identical condition, higher catalytic activity for $NO_x$ reduction was observed with Ag and Cu wires than with the spheres, while spherical- and wire-shape Ru exhibited similar $NO_x$ reduction efficiency to each other. Among the metal oxides examined, the best catalytic activity for $NO_x$ reduction was obtained with Ag wire, showing almost complete $NO_x$ removal at a temperature of $300^{\circ}C$. For Cu and Ru catalysts, considerable amount of NO was oxidized to $NO_2$, rather than reduced to $N_2$, leading to lower $NO_x$ reduction efficiency.