• Title/Summary/Keyword: Nitrogen Oxide

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Cold spray technology as a potential additive manufacturing (3D 프린팅 공정 관점의 저온분사 기술)

  • Kim, Hyeong-Jun;Yun, Sang-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.90-90
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    • 2017
  • Cold spray (Cold gas dynamic spray, kinetic spray) is the latest spray coating process that is known as solid state deposition process. In cold spray, inert gases (typically nitrogen and helium) accelerate powder particles prior to impact onto the substrate. Accelerating particles start to deposit onto the substrate after reaching certain critical velocities depending on the coating materials and substrate. Since process gas temperatures are kept below to melting temperature of the coating materials, it is possible to spray temperature sensitive materials such as copper and titanium, nanocrystal materials, and amorphous metals without affecting the phase change and oxide formation. It is also possible to deposit thick coatings because cold spray coatings present compressive residual stresses. This ability to deposit thick coatings is suitable to repair or rebuild parts as an additive manufacturing process. In this presentation, cold spray is introduced and compared to other additive manufacturing processes such as laser and electron beam based processes. It is also presented some applications especially in the view point of additive manufacturing process.

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Optical Reactivity Modification of Titanium Oxide coatings on Ceramic filters by Nitrogen ion Implantation

  • Kim, Hyeong-Jin;Park, Jae-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.90-90
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    • 2010
  • We investigated the modification of optical response properties of titanium dioxide (TiO2) coatings on the ceramic water-purification filters by using ultraviolet-visible absorption spectroscopy and X-ray diffraction. The TiO2 coatings were prepared on ceramic substrate by e-beam evaporation method. These amorphous TiO2 were turned into anatase phase by heat treatment at $700^{\circ}C$ for 2 hours. The doping of N atoms into the TiO2 coatings was done by using 70KeV of N+ ion implantation with the dose of $1.0{\times}1017$ ions/cm2, followed by post-irradiation heat treatment at $550^{\circ}C$ for 2 hours. Methylene blue test of TiO2 coatings to solar irradiation showed that the post-evaporation heated TiO2 was photocatalytic and N-doped TiO2 reacted to the visible part of solar irradiation.

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Analysis on Cycle-by-Cycle NO Emissions from an Sl Engine with Fast HO Analyser (고속 NO 분석기를 이용한 Sl 엔진에서의 사이클 변동에 따른 NO 배출에 관한 분석)

  • 성정민;김현우;이경환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.73-79
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    • 2002
  • The NO emissions at the exhaust manifo1d were investigated with a fast NO analyzer to investigate the cycle-by-cycle variations on NO emissions level and the dependence of NO emissions on combustion. The measurement was performed with a part load condition with respect to the mixture ratios and the changes in loads at 1800rpm. The averaged values were obtained during 200 cycles. We found that there is characteristic pattern in 70 emissions from exhaust port and it was possible to set a representative value with the data sampled during specific period. As the load increased, the characteristics of NO emissions were more dependent on combustion pressures. It was also analyzed that the correlation between combustion pressures and NO emissions for different equivalence ratios tends to increase as the mixture goes leaner, Furthermore, this correlation for the lean mixture near the lean limit seemed to be kept.

Effects of Annealing on Silicon Dioxide using Rapid Thermal Process System (급속 열처리 장치를 이용한 실리콘 산화막의 Annealing 효과)

  • Park, H,W.;Jang, H.Y.;Hwang, H.J.
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.383-386
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    • 1988
  • In MOS integrated circuits, annealing after oxidation process is necessary to improve physical properties of silicon dioxide. With subsequent annealing in inert gases such as nitrogen or argon, and excess silicon bond is allowed time to complete the oxidation and surface charge density is reduced. In this paper, we will present effects of the rapid thermal annealing on silicon dioxide. In order to evaluate characteristics of silicon dioxide, we analyzed C-V curve dependent on annealing time and temperature, and presented variation of fixed oxide charge.

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Fabrication Technology of high Tc Superconductor for Electrical Equipment (전력기기 초전도 합성기술)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.364-366
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

Impact of DPN on Deep Nano-technology Device Employing Dual Poly Gate (Nano-technology에 도입된 Dual Poly Gate에서의 DPN 공정 연구)

  • Kim, Chang-Jib;Roh, Yong-Han
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.4
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    • pp.296-299
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    • 2008
  • The effects of radio frequency (RF) source power for decoupled plasma nitridation (DPN) process on the electrical properties and Fowler-Nordheim (FN) stress immunity of the oxynitride gate dielectrics for deep nano-technology devices has been investigated. With increase of RF source power, the threshold voltage (Vth) of a NMOS transistor(TR) decreased and that of a PMOS transistor increased, indicating that the increase of nitrogen incorporation in the oxynitride layer due to higher RF source power induced more positive fixed charges. The improved off-current characteristics and wafer uniformity of PMOS Vth were observed with higher RF source power. FN stress immunity, however, has been degenerated with increasing RF source power, which was attributed to the increased trap sites in the oxynitride layer. With the experimental results, we could optimize the DPN process minimizing the power consumption of a device and satisfying the gate oxide reliability.

Physical Characteristics of PECVD SiON Films with Composition Variation (조성변화에 따른 PECVD SiON 박막의 물성특성)

  • Cho Yu Jung;Han Kil Jin;Kim Yeong Cheol;Seo Hwa Il
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.3 s.12
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    • pp.1-4
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    • 2005
  • Silicon oxynitride films were deposited using ammonia as a nitrogen source via PECVD (plasma enhanced chemical vapor deposition) to study the physical properties of the films. Silane and nitrous oxide were used as silicon and oxygen sources, respectively. The composition of the silicon oxynitride films was well controlled by changing the ratios of the sources and confirmed by XPS. The silicon oxynitride films with high oxygen content showed bigger compressive stress and less refractive index, while the values of surface roughness were around 1 nm, irrespective of the variation of the source ratios.

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Premixed VIStA Burner for an Once-Through Type Boiler (관류보일러를 위한 예혼합 VIStA 버너 개발)

  • Ahn, Joon;Kim, Hyouck-Ju;Choi, Kyu-Sung
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1013-1018
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    • 2008
  • Vortex Inertial Staged Air (VIStA) burner for an once-through type boiler has been restored to the original premixed type to reduce nitrogen oxide (NOx) emission. The premixed version yields additional de-NOx effect by 20 ppm. The flame is formed closer to the wall at the 1st stage combustion chamber compared with the non-premixed one. The combustion characteristics are more sensitive to the air distribution for the premixed type, which necessitates proper optimization.

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Metallothionein Induces Site-specific Cleavages in tRNAPhe

  • Seon, Jung-Yun;Koh, Moon-Joo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.921-924
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    • 2005
  • It is known that metallothionein (MT) plays a role in the scavenging of free radicals, which is produced under various stress conditions. MT may function as an antioxidant that protects against oxidative damage of DNA, protein, and lipid induced by superoxide anion, hydrogen peroxide, hydroxyl radical, nitric oxide, and peroxynitrite. This study was undertaken to test the hypothesis that MT also protects from RNA damage induced by peroxynitrite, an important reactive nitrogen species that causes a diversity of pathological processes. A cell-free system was used. RNA damage was detected by the mobility of $tRNA^{Phe}$ in electrophoresis. Cleavages on tRNA were not induced by 3-morpholinosydnomine, which produces peroxynitrite directly. MT induced tRNA damage which was site specific.

Experimental Study for NOx Reduction Using Reburning and Numerical Study with FLUENT (재연소를 이용한 NOx 저감의 실험적 연구 및 FLUENT를 이용한 수치적 연구)

  • Kim, Jae-Kwan;Kim, Hak-Young;Baek, Seung-Wook
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.1967-1972
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    • 2008
  • Reburning is an efficient combustion technology to reduce nitrogen oxide by injecting hydro-carbon fuel to the downstream of the main combustion. In this paper LPG has been used not only as main fuel but also as reburn fuel and air was used as an oxidizer with 15kW swirl burner. Experimental studies have been done to evaluate effect of reburning for NOx reduction. Also to examine the effect of the amount of burnout air for complete combustion by reburn fuel on NOx reduction, test was conducted by reducing the amount of burnout air. Computational fluid dynamic (CFD) simulation was performed using the commercial CFD code FLUENT 6.3 to simulate experimental results and investigate the thermo-chemical characteristics. An evaluation of reaction models for swirl burner has been carried out for propane-air with two step finite-rate eddy-dissipation model in FLUENT.

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