• Title/Summary/Keyword: Nitrogen Oxide

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Annealing Effects on Ultra thin MOS Capacitors

  • Ng, Alvin Chi-hai;Xu, Jun;Xu, J.B.;Cheung, W.Y.
    • Electrical & Electronic Materials
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    • v.16 no.9
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    • pp.62.1-62
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    • 2003
  • Silicon oxide with thickness lee than 9 nm is fabricated by tube furnace oxidation. Nitrogen is added to dilute the oxidation rate. Aluminum dots with radius of 0.05 cm are deposited on the oixde. High frequency capacitance-voltage(HF C-V), conductance-voltage(G-V) and current-voltage(I-V) characteristics are measured. Annealing under nitrogen atmosphere is carried out with different time and at different temperature. Densities of the interface states before and after annealing are compared. After annealing, a decrease in density of the interface states is found. Experiments show that 45$0^{\circ}C$ annealing for 30 minutes has the lowest density of the interface states.

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Photovoltaic Properties of Sintered CdS/CdTe Solar Cell (소결체 ITO/CdS/CdTe 태양전지의 광전압특성)

  • 김동섭;조은철;안병태;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.216-220
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    • 1994
  • Polycrystalline CdS films have been prepared by coating a slurry, which consisted of CdS, 11w% CdCl$_2$ and appropriate amount of propylene glycol, on glass substrate and glass substrate coated with indium tin oxide(ITO) followed by sintering in a nitrogen atmosphere. CdTe slurries consisting of Te powder and Cd powder were coated on the sintered CdS films and ITO/CdS films and were sintered in nitrogen to prepare sintered CdS/CdTe and ITO/CdS/CdTe solar cells. The value of fill factor increased due to low series resistance and open circuit voltage decreased due to low shunt resistance in the ITO/CdS/CdTe solar cells.

An Emission Characteristics of a Controlled Auto-Ignition Gasoline Engine (제어자발화 가솔린기관의 배기 특성)

  • Kim, H.S.
    • Journal of Power System Engineering
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    • v.13 no.3
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    • pp.5-10
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    • 2009
  • This work deals with a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector is cooled by the water of a specially designed coolant passage. The engine emission characteristics were investigated under the wide range of operating conditions such as 32 to 63 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, and 150 to $180^{\circ}C$ in the inlet air temperature. The ultra lean-burn can be achieved by the auto-ignition of gasoline fuel due to the heated inlet air in the compression ignition gasoline engine. It is confirmed that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide can be significantly reduced by CAI combustion compared with the combustion of a conventional spark ignition engine.

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Surface Characterization of $\beta$-Sialon Powder Prepared from Hadong Kaolin (하동 카올린으로부터 제조한 $\beta$-Sialon 분체의 표면특성)

  • 임헌진;이홍림
    • Journal of the Korean Ceramic Society
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    • v.28 no.12
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    • pp.961-968
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    • 1991
  • The nature and composition of the surfaces of silicon nitride and β-Sialon powders were investigated using high voltage and high resolution transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). β-Sialon powder was produced from Hadong kaolin by the carbothermic reduction and simultaneous nitridation. XPS showed that Al was contained in the surface of β-Sialon powder besides Si, N and O components, which is different from that of silicon nitride. It was supposed that Al in the surface of β-Sialon was bonded with oxygen from the oxygen-nitrogen ratio and the measurement of Al 2p binding energies. After both silicon nitride and β-Sialon powders were oxidized at 800℃ for 24h in air, nitrogen didn't exist in the surfaces and the depth of the oxide layer increased. The measurement of Si 2p binding energies showed that the chemical shifts occurred from Si3N2O and/or Si2N2O to SiO2 phase.

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The effect of cryogenic rolling on critical current density of Bi-2223/Ag HTS tapes (Bi-2223/Ag 고온초전도선재의 Jc와 미세조직에 미는 저온압연의 영향)

  • 최정규;황선역;하동우;오상수;권영길;이세종
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.142-145
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    • 2003
  • In order to investigate the effect of cryogenic rolling on the critical current density (Jc), 54 and 55-multi-filament Bi-2223/hg tapes have been fabricated using a PIT process including two different types of cooling methods. The densification of oxide filament was found to occur due to the cryogenic rolling, and this enhanced the critical current density. However, when the wire was fully immersed in liquid nitrogen used as the coolant in cryogenic rolling, Jc degradation appeared caused by the nitrogen penetration into the filament. The cryogenically rolled tape with an improved type of cooling showed approximately 10% Jc's increase.

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Nitrogen Doping Characterization of ZnO Prepared by Atomic Layer Deposition (원자층 증착법으로 성장된 ZnO 박막의 질소 도핑에 대한 연구)

  • Kim, Doyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.10
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    • pp.642-647
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    • 2014
  • For feasible study of opto-electrical application regarding to oxide semiconductor, we implemented the N doped ZnO growth using a atomic layer deposition technique. The p-type ZnO deposition, necessary for ZnO-based optoelectronics, has considered to be very difficulty due to sufficiently deep acceptor location and self-compensating process on doping. Various sources of N such as $N_2$, $NH_3$, NO, and $NO_2$ and deposition techniques have been used to fabricate p-type ZnO. Hall measurement showed that p-type ZnO was prepared in condition with low deposition temperature and dopant concentration. From the evaluation of photoluminescence spectroscopy, we could observe defect formation formed by N dopant. In this paper, we exhibited the electrical and optical properties of N-doped ZnO thin films grown by atomic layer deposition with $NH_3OH$ doping source.

Effect of Green Manure Crop and Biochar on Nitrous Oxide Emission from Red Pepper Field (녹비작물과 바이오숯의 고추 재배지 아산화질소 배출량 저감 효과)

  • Seo, Young-Ho;Kim, Se-Won;Choi, Seung-Chul;Kim, In-Jong;Kim, Kyung-Hi;Kim, Gun-Yeob
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.540-543
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    • 2012
  • Atmospheric nitrous oxide ($N_2O$) level has been increasing at a rate of 0.2~0.3% per year. The rise in $N_2O$ concentration in atmosphere was mainly due to an increased application of nitrogen fertilizers. The objective of the study was to assess the effect of green manure crop and biochar on $N_2O$ emissions from upland crop field. The green manure crop used in the study was hairy vetch and the cultivated crop was red pepper (Capsicum annuum L.). Nitrogen was applied at a rate of $190kg\;ha^{-1}$, standard N fertilization rate for red pepper. Emissions of $N_2O$ from the field were reduced from the plots applied with hairy vetch and biochar by 46.5% and 24.6%, respectively, compared with nitrogen fertilizer treated plots with $N_2O$ emission of $1.14kg\;N_2O-N\;ha^{-1}$. The results from the study imply that green manure crop and biochar can be utilized to reduce greenhouse gas emission from the upland crop field.

Performance Evaluation of Nitrogen Oxide Removal by Air Purification Blocks with Titanium Dioxide (이산화티타늄을 이용한 대기정화 블록의 질소산화물 제거 성능 평가)

  • Oh, Ri-On;Kim, Hwang-Hee;Park, Sung-Ki;Cha, Sang-Sun;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.39-46
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    • 2020
  • This study evaluated the nitrogen oxide (NOx) removal efficiency by air purification concrete blocks with titanium dioxide (TiO2). The concrete in the mixtures had a 30% water:cement ratio, to which TiO2 was added at 0%, 5%, and 10% of cement weight. The compressive strength reduction rate and removal efficiency of NOx were investigated. The result of the compressive strength test in the study indicated that addition rate of TiO2 did not lead to signifcant effect. In terms of the average removal efficiency of NOx, mix No. 1 using a TiO2 mixing ratio of 0% had a removal efficiency of 0.57% on average; thus, the removal effect w as not significant. For the other samples prepared by mixing, the average removal efficiencies for mix No. 2 (5% TiO2) were 58.86% and 62.05% for normal and washing surface treatments, respectively, and those of sample No. 3 (10% TiO2) were 59.94% and 67.61%. mixs No. 4 (5%) and No. 5 (10%), in which TiO2 diluted with distilled water was sprayed onto the block surface, had an average NOx removal efficiency of 61.72% and 68.48%, respectively. In terms of NOx removal efficiency, Mixs No. 3 and No. 5 with 10% TiO2 were better than Mixs No. 2 and No. 4 with 5% TiO2. In addition, analyzing the NOx removal efficiency results from the fixing method, it was capable to apply mixing (washing) and the diluted spray methods. Therefore, it was found that the diluted spray method applied in this study can be employed in any manufacture of air purification concrete blocks.

Real Time Measurement of Exhaust Emissions from Main Engine using Training Ship (실습선을 이용한 주 추진기관의 배기배출물의 실시간 계측)

  • Choi, Jung-Sik;Lee, Sang-Deuk;Lee, Kyoung-Woo;Chun, Kang-Woo;Nam, Youn-Woo;Yoon, Seok-Hun;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.5
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    • pp.531-537
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    • 2013
  • In this study, we conducted real-time measurement at the ship arrivals and departures at the port and at a constant speed of 150 rpm for exhaust emissions from a main engine installed on the training ship, HANBADA, of Korea Maritime University. The result showed that the concentration of nitrogen oxide was measured in the range of 800 ppm to 1,000 ppm at constant speed mode. On the other hand, the concentration of nitrogen oxide during ship arrivals and departures was significantly fluctuated between 210 ppm and 1,230 ppm. And, the concentration of carbon oxide at the arrivals and departures was also larger than that of at constant speed mode. These results show that the ship maneuvering skills to prevent a sudden load change of main engine at the arrivals and departures of ship is needed. Additionally, it means that the difference of exhaust emissions generated between the constant speed mode and the arrival/departure has to be considered when invented many technologies are adopted into the reduction technologies of air pollutants from ships.

Dynamics of Nitrogen Compounds and Functional Genes in a Nitrification-Denitrification Coupling Process (질산화-탈질 연계공정에서 질소화합물 및 기능성 유전자 거동)

  • Kwon, Ji-Hyeon;Park, Hyung-Joo;Lee, Yun-Yeong;Cho, Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.48 no.1
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    • pp.72-78
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    • 2020
  • The dynamics of nitrogen compounds and RNA-based functional genes were characterized in the nitrification-denitrification coupling process. For the removal of residual ammonium, intermittent aeration was introduced in the denitrification reactor. N2O production was not observed in both reactors. In both reactors, the nitrifying genes (achaeal-amoA, bacterial-amoA and hor) and denitrifying genes (narG, nirK, norB and nosZ) had a copy number of 3.92 × 102-7.25 × 105 and 2.85 × 102-3.06 × 104 per ng of DNA, respectively. These results suggest that denitrification and nitrification reactions occur in both the nitrification and denitrification reactors, respectively. Therefore, the coupling process is a promising one for the conversion of ammonium to nitrogen without generating N2O.