• Title/Summary/Keyword: NiFe

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HEAVY METAL CONTINT IN THE SEDIMENTS FROM THE CONTINENTAL SHELF AROUND JEJU ISLAND AND SOUTHERN COASTAL AREA, KOREA (濟州道周圍 및 南海沿岸 堆積物中의 重金屬含量)

  • 석봉출;박병권
    • 한국해양학회지
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    • v.18 no.1
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    • pp.29-42
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    • 1983
  • This stidy was intended to investigate the heavy metal contents in the bottom sediments of the continental shelt around the Jeju Island and ot the southern coastal area of the Korean Peninsula. For this study 39 bottom sedinent samples were taken from the study area using Phleger gramity corer and Snapper. The average contents of heavy metals were 59.1 ppm Zn, 362.6 ppm Mn, 63.8 ppm Cr, 15.7 ppm Pb, 10.0 ppm Co, 28.9 ppm Ni, 10.5 ppm Cu, and 2.7% Fe in the surficial sediments around the Jejr Island; and 79.ppm Zn, 384 ppm Mn, 8.6 ppm Pb, 17.8 ppm Ni, 23.2 ppm Cu, and 1.59 % fe in those of nearsgore of the southern coastal area respectively. The heavy metal contents were higher in the northwestern part around the Jeju Island compared to those in other region. However, these tendencies were not the result of pollution, but of the differences of grain size of the sedimenrs. In the nearshore of the southern coast, the heavy metal contents did not show any geographical tendency. However, those of Masan and Jinhae Bays wew higher than those of the other region. These seemed to be caused by waste disposal from the industrial compsex located at the adjacent land. Nevertheless these values of heavy metal content except for Zn and Cu in Masan Bay and inner bay of Jinhae are lower than the average values of the each world-wide data of the nearshore sedimentl. The pair correlations of the cach heavy metal elements were calculated by regressino analysis using VAX 780 computer. the following pair elements, such as Zn-Cu, Ni-Cu, Fe-cu, Cr-Cu, Co-Zn, Ni-Zn, Cr-Zn, Ni-Co, Fe-Co, Cr-Co, Fe-Ni, Cr-Ni and Cr-Fe show closely posetive linear correlations in the sediments around the Jeju Island. In general, the heavy metal content increases in proportion to the increase of the mean values of the grain size of the sediments around the Jeju Island. In the southern coastal area, in gineral, thepair correlations of each heavy metal elements did not southern coastal area, in general, the pair correlatttttions of rach heavy metal elements did not show any positive correlation except for the positive linear correlations of Cu-Zn, Cu-ni and Ni-Mn. It is interpreted as a result of the differences of the physecochemical environment of the sampling sites and also of the influences of the ondustrial wastes from the manufacturing factores located at the coastal zone of the study area.

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Magnetoresistive Effect in Ferromagnetic Thin Films( I ) (강자성체 박막(Fe-Ni, Co-Ni)의 자기-저항 효과에 관한 연구( I ))

  • Chang, C.G.;Yoo, J.Y.;Song, J.Y.;Yun, M.Y.;Park, J.H.;Son, D.R.
    • Journal of Sensor Science and Technology
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    • v.1 no.1
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    • pp.23-34
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    • 1992
  • In order to fabricate magnetoresistive sensor, Fe-Ni and Co-Ni alleys were evaporated on the slide glass and the silicon wafers. Saturation magnetic induction($B_{s}$), coercive field strength($H_{c}$) and magnetoresistance were measured for fabricated samples. The evaporated Fe-Ni thin films show that the saturation magnetic induction was 0.65 T, and coercive field strength was 0.379 A/cm, and this value was changed to 0.370 A/cm(//), 0.390 A/cm(${\bot}$), respectively after magnetic annealing. For the measurement of coercive field strength, magnetizing frequency of 1 kHz was used. For the fabricated sensor element, the change of magnetoresistance (${\Delta}R/R$) was excessively unstable due to oxidation in the process of fabrication. The evaporated Co-Ni alloy thin films show that saturation magnetic induction was 0.66 T, and coercive field strengthes were 5.895 A/cm(//), 5.898 A/cm(${\bot}$), respectively, after magnetic annelaing. The change of magnetoresistance(${\Delta}R/R$) was $3.6{\sim}3.7%$ of which value was excessively stable to room temperature. Fe-Ni thin film could have many problems due to large affinity in the process of fabrication of magnetoresistance sensor, but Co-Ni thin film could be a suitable material for fabrication of magnetoresistance sensor, because of its small affinity and definite magnetoresistance effects.

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Effects of Heat-treatments on Discharge Characteristics of TiFe1-xNix Alloy Electrodes for Ni/MH Secondary Battery (Ni/MH 2차전지용 TiFe1-xNix 합금전극의 방전특성에 대한 열처리의 영향)

  • Joung, Soon-dol;Joung, Sang-sik;Ahn, Hyo-jun;Kim, Ki-won
    • Journal of Hydrogen and New Energy
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    • v.9 no.4
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    • pp.135-141
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    • 1998
  • The effects of heat-treatment on discharge characteristics of $TiFe_{1-x}Ni_x$ alloy were investigated. The content of Ni in alloy was varied from x = 0.1 to 0.6 by each 0.1 increment. Discharge capacity change of each alloy with C/D cycles was measured. With increasing Ni-content initial discharge capacity was increased. but at x = 0.6 it was deceased again. With increasing C/D cycles discharge capacity was rapidly decreased in the alloy of high Ni-content. In order to investigate the effects of heat-treatment on cycle life, $TiFe_{0.5}Ni_{0.5}$ alloy having maximum initial discharge capacity was heat-treated at various temperatures in the range of $700{\sim}900^{\circ}C$ and tested. The loss of initial discharge capacity was appeared at all temperatures. but cycle characteristics of the alloy was improved. The electrodes heat-treated for 1 hour in the range of $700{\sim}850^{\circ}C$ showed good recovery of discharge capacities through repeated cycles, and from SEM observation results these were considered as 1 hour in the range of $700{\sim}850^{\circ}C$ showed good recovery of discharge capacities through repeated cycles, and from SEM observation results these were considered asbeing due to increased electrode strength and small loss of porosity during heat-treatment. The electrode heat-treated for 1 hour at $900^{\circ}C$ showed poor discharge characteristics because of low porosity.

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Giant Magnetoresistance Properties of NiO Spin Valves with Naturally Oxidized Free Layer (자연산화된 자유층을 갖는 NiO 스핀밸브 박막의 자기저항특성)

  • 김종기;주호완;이기암;황도근;이상석
    • Journal of the Korean Magnetics Society
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    • v.11 no.3
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    • pp.104-108
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    • 2001
  • The effect of specular electron scattering on natural oxidation of free layer in NiO spin valves have been investigated. The magnetoresistance (MR) ratio and the exchange biasing field ( $H_{ex}$) of NiO(600 $\AA$)Ni$_{81}$$Fe_{19}$(50$\AA$)/Co(7 $\AA$)/Cu(20 $\AA$)/Co(7 $\AA$)Ni$_{81}$$Fe_{19}$(70 $\AA$) spin valves were increased from 4.9 % to 7.3 %, and 110 Oe to 170 Oe after natural oxidation in the atmosphere for 80 days, respectively. The sheet resistivity p decreased from 28$\mu$$\Omega$m to 17$\mu$$\Omega$m, but $\Delta$$\rho$ did not almost change after the oxidation. The spin valves enhanced by the specular electron scattering in the natural]y Co/NiFe/NiFe $O_{x}$ free layer were confirmed from the depth profiles using Auger electron spectroscopy.scopy..

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Mechanical and Physical Property Changes of Cu-Ni-Si-Sn-Fe-P Copper Alloy System According to the Heat Treatment Conditions (열처리조건에 따른 Cu-Ni-Si-Sn-Fe-P 석출경화형 동합금계의 물성변화 특성)

  • Kim, Seung-Ho;Yum, Young-Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.5
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    • pp.225-232
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    • 2013
  • The influence of aging treatment, addition elements and rolling reduction ratio on the microstructure, mechanical, electrical and bendability properties of Cu-Ni-Si-P-x (x = Fe, Sn, Zn) alloys for connector material application was investigated. SEM/EDS analysis exhibited that Ni2-Si precipitates with a size of 20~100 nm were distributed in grains. Fe, Sn, Zn elemnets in Cu-Ni-Si-P alloy imporved the mechanical strength but it was not favor in increasing of electrical conductivity. As higher final rolling reduction ratio, the strength and electrical conductivity is increased after aging treatment, but it indicated excellent bendability. Especially, Cu-2Ni-0.4Si-0.5Sn-0.1Fe-0.03P alloy show the tensile strength value of 700MPa and the electrical conductivity was observed to reach a maximum of 40%IACS. It is optimal for lead frame and connector.

Fabrication of Core-Shell Structured Ni-Based Alloy Nanopowder by Electrical Wire Explosion Method

  • Lee, A-Young;Lee, Gwang-Yeob;Oh, Hye-Ryeong;Kim, Hyeon-Ah;Kim, Song-Yi;Lee, Min-Ha
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.409-413
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    • 2016
  • Electrical wire explosion in liquid media is a promising method for producing metallic nanopowders. It is possible to obtain high-purity metallic nanoparticles and uniform-sized nanopowder with excellent dispersion stability using this electrical wire explosion method. In this study, Ni-Fe alloy nanopowders with core-shell structures are fabricated via the electrical explosion of Ni-Fe alloy wires 0.1 mm in diameter and 20 mm in length in de-ionized water. The size and shape of the powders are investigated by field-emission scanning electron microscopy, transmission electron microscopy, and laser particle size analysis. Phase analysis and grain size determination are conducted by X-ray diffraction. The result indicate that a core-shell structured Ni-Fe nanopowder is synthesized with an average particle size of approximately 28 nm, and nanosized Ni core particles are encapsulated by an Fe nanolayer.

Mossbauer Spectra of the $\textrm{Cd}_{x}\textrm{Ni}_{1-x}\textrm{Fe}_{2}\textrm{O}_{4}$ ($\textrm{Cd}_{x}\textrm{Ni}_{1-x}\textrm{Fe}_{2}\textrm{O}_{4}$의 Mossbauer 스펙트럼)

  • Baek, Seung-Do
    • Korean Journal of Materials Research
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    • v.7 no.7
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    • pp.618-622
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    • 1997
  • 상온에서 측정한 Cd$_{x}$Ni$_{1-x}$Fe$_{2}$O$_{4}$의 Mossbauer 스펙트럼은 조성비에 따라 x값이 0.4이하인 시료에서는 준강자성에 의한 여섯개의 공명 흡수선, x값이 0.5인 시료에서는 이완된 형태의 공명흡수선, 그리고 x값이 0.6시료인 상자성에 의한 두개의 공명 흡수선이 나타났다. Cd$_{x}$Ni$_{1-x}$Fe$_{2}$O$_{4}$의 x값이 0.4이하인 시료의 초미세 자기장(H$_{hf}$)과 x값이 0.6 이상인 시료의 사중극자 분열치 (Q.S.)는 Cd농도가 증가함에 따라 감소한다. 시료의자기적 성질에 따른 이성질체 이동치(I.S.)의 차이는 있으나, Ni와 Cd이온의 농도에 따른 뚜렷한 의존성은 나타나지 않았다.다.

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Synthesis and Properties of Ni-Zn Ferrite by Wet-Direct Process (습식 직접 합성법에 의한 Ni-Zn Ferrite의 합성 및 물성 연구)

  • 이경희;이병하;이융걸;황우연
    • Journal of the Korean Ceramic Society
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    • v.28 no.3
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    • pp.225-233
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    • 1991
  • In this study, we tried to find out the appropriate synthetic condition and magnetic properties of Ni-Zn ferrite {(NixZn1-x)Fe2O4} powders (where X=0, 0.1, 0.2, 0.3, ……0.9, 1). Ferrite powders were prepared by wet-direct method at 86℃ for 6hrs from FeCl36H2O, NiCl26H2O, and ZnCl2. The powders of (NixZn1-x)Fe2O4 (where X=0.4, 0.5, 0.6) have a good crystallinity, but the other ferrite powders consist of crystal and precursor ferrite. The ferrite powder's lattice constant is increased when ratio of ZnO contant is increased in the ferrite composition. And initial permeability was measured after sintering, result indicated regular pattern except (Ni0.4Zn0.6)Fe2O4 when the frequency were changed 10KHz to 10MHz.

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