• Title/Summary/Keyword: Ni loss

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Corrosion Behavior of Bimetal Materials (Fe-Ni / Fe-Ni-Mo) for Electromagnetic Switches (전자 개폐기용 바이메탈 소재(Fe-Ni / Fe-Ni-Mo)의 부식거동)

  • Yu-Jeong An;Eun-Hye Hwang;Jae-Yeol Jeon;Sung Jin Kim
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.478-483
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    • 2023
  • This study examined the corrosion behavior of bimetal materials composed of Fe-Ni alloy and Fe-Ni-Mo alloy, both suitable for use in electromagnetic switches. Electrochemical polarization and weight loss measurements revealed that, in contrast to Fe-Ni alloy, which exhibited pseudo-passivity behavior, Fe-Ni-Mo alloy had higher anodic current density, displaying only active dissolution and greater weight loss. This indicated a lower corrosion resistance in the Fe-Ni-Mo alloy. Equilibrium calculations for the phase fraction of precipitates suggested that the addition of 1 wt% Mo may lead to the formation of second-phase precipitates, such as Laves and M6C, in the γ matrix. These precipitates might degrade the homogeneity of the passive film formed on the surface, leading to localized attacks during the corrosion process. Therefore, considering the differences in corrosion kinetics between these bimetal materials, the early degradation caused by galvanic corrosion should be prevented by designing a new alloy, optimizing heat treatment, or implementing periodic in-service maintenance.

Transient loss analysis of non-insulation high temperature superconducting coil using the field-based data profiling method

  • Hoon Jung;Yoon Seok Chae;June Hee Han;Ji Hyung Kim;Seung Hoon Lee;Ho Chan Kim;Young Soo Yoon;Ho Min Kim
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.3
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    • pp.38-42
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    • 2023
  • The evaluation of no-insulation (NI) high-temperature superconducting (HTS) typically uses the lumped equivalent circuit (LEC) model. Constant parameters in the NI HTS LEC model accurately predict voltage and central magnetic field at currents below the critical current. However, it is difficult to find constant circuit parameters that simultaneously satisfy the measured voltage and magnetic field under overcurrent conditions. Recent research highlights changes in contact resistance during transient conditions, which may impact power loss estimation in NI HTS coils. Therefore, we confirm the influence of contact resistance changes on loss calculation in the transient state for NI HTS coil. To achieve this, we introduce a measurement data analysis method based on the LEC model and compare it with the LEC model using constant circuit parameters.

The Effects of Additives on Microstructure and Magnetic Properties of Ni0.8Zn0.2Fe2O2 (첨가제 변화에 따른 Ni0.8Zn0.2Fe2O2 의 미세구조와 자기적 특성)

  • 오영우;이선학;이해연;김현식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.406-411
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    • 2002
  • Ni-Zn ferrite is required to have predominant and stable characteristics in the range of high frequency for the power line communication, so that microstructures and magnetic properties such as power loss and initial permeability in $Ni_{0.8}Zn_{0.2}Fe_2O_4$ were investigated in terms of variable $Bi_2O_3,CaO$ and $V_2O_5$ contents. $Bi_2O_3$ and $V_2O_5$ liquid phase created during sintering process promoted sintering and grain growth but much of the closed pore existed in the grains. The grain size of the specimens with $V_2O_5$ of over 0.5 wt% decreased as the result of "pinning effect"and the resonance frequency increased with CaO of 0.3we%. The high initial permeability of 81.52%, resonance frequency of 17.05 MHz and low power loss of 17,858 kW/$\textrm{m}^3$ were obtained from the samples with $Bi_2O_3$ of 0.5, CaO of 0.3, and $V_2O_5$ of 0.7 wt%.

A study on the electrical characteristic of 0-02PYW-0-98PZT ceramics dopped with NiO, $Cr_2O_3$ (NiO, $Cr_2O_3$를 첨가한 0-02PYW-0.98PZT세라믹의 전기적특성에 관한 연구)

  • 김진섭;김현철;손효승;임인호;배선기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.638-641
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    • 1999
  • In consideration of Dielectric loss and Temperature stability, 3-element system dopped with NiO, $Cr_2O_3$, well-known as Hardner and Stabilizer whose primary element is PZT was eximanated its structure, Temperature Coefficient of Capacitor, relative resistivity for Temperature Compensation condensor study. dopping with Nio, $Cr_2O_3$, Temperature Characteristic is developed, Dielectric loss largely represented useful1 small values in specimens dopped with NiO 0.2wt%, and specimence sintered at $110^{\circ}C$ dopped with $Cr_2O_3$, 0.1wt% also relative resistivity largely showed tendency of decrement According to dopping NiO more.

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Complex Permeability Analysis of NiCuZn Ferrites (NiCuZn 계 페라이트의 조성에 따른 복소투자율 변화 해석)

  • 남중희;오재희
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.382-387
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    • 1996
  • The characteristics of the complex permeability of ${(Ni_{x}Cu_{0.2}Zn_{0.8-x}O)}_{1-w}{(Fe_{2}O_{3})}_{1+w}$ with various Ni and $Co_{3}O_{4}$ contents were investigated in this work. It is found that the NiCuZn ferrites with $x{\geq}0.6$ have a relatively small peak width of the imaginary part of permeability $\mu$". The resonance frequency is increased as Ni content becomes higher, where the loss is low. The $\mu$" value decreases with increasing FezO, deficiency, but the resonance frequency($f_{\mu"max}$) is only slightly affected by $Fe_{2}O_{3}$ deficiency. In case of $Co_{3}O_{4}$ addition to the NiCuZn ferrites, the $f_{\mu"max}$ increases since the initial permeability decreases with the amount of $Co_{3}O_{4}$. It is concluded that the Ni content in the NiCuZn ferrite is a dominant factor for the total loss of these spinel ferrites.

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Microwave Absorbance of Polymer Composites Containing SiC Fibers Coated with Ni-Fe Thin Films

  • Liu, Tian;Kim, Sung-Soo;Choi, Woo-cheal;Yoon, Byungil
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.375-378
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    • 2018
  • Conductive and dielectric SiC are fabricated using electroless plating of Ni-Fe films on SiC chopped fibers to obtain lightweight and high-strength microwave absorbers. The electroless plating of Ni-Fe films is achieved using a two-step process of surface sensitizing and metal plating. The complex permeability and permittivity are measured for the composite specimens with the metalized SiC chopped fibers dispersed in a silicone rubber matrix. The original non-coated SiC fibers exhibit considerable dielectric losses. The complex permeability spectrum does not change significantly with the Ni-Fe coating. Moreover, dielectric constant is sensitively increased with Ni-Fe coating, owing to the increase of the space charge polarization. The improvements in absorption capability (lower reflection loss and small matching thickness) are evident with Ni-Fe coating on SiC fibers. For the composite SiC fibers coated with Ni-Fe thin films, a -35 dB reflection loss is predicted at 7.6 GHz with a matching thickness of 4 mm.

Self-field Loss Characteristics of a long Bi-2223/AgMgNi Tape (장척 Bi-2223/AgMgNi 테이프의 자기자계손실 특성)

  • Ryu, Gyeong-U;Park, Gwon-Bae;Cha, Gwi-Su;Choe, Gyeong-Dal;Lee, Ji-Gwang;Han, Song-Yeop
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.49 no.4
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    • pp.240-245
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    • 2000
  • The self-field losses in a long multifilamentary Bi-2223/AgMgNi tape with varying transport current, voltage tap configurations, frequency and tape arrangements were investigated. Experimental results show that the measured losses are strongly dependent on voltage gap configurations but independent on tape arrangements. All voltage taps except the center tap are found to agree well with those predicted by Norris for an elliptical conductor. The self-field losses are purely hysteretic in nature in the range of applied frequencies for the transport currents below the critical current.

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A Study on the Electrochemical Characteristics of the Nickel Hexacyanoferrate Ion Exchanger (Nickel Hexacyanoferrate 이온교환체의 전기화학적 특성에 관한 연구)

  • Hwang, Young-Gi
    • Journal of the Korean Society of Industry Convergence
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    • v.19 no.4
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    • pp.198-205
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    • 2016
  • For the study on the ion exchange of nickel hexacyanoferrate(NiHCNFe) electrode with the several cations, the film of hexacyanoferrate was prepared on the bare nickel surface by the electrochemical and chemical methods in the solution composed with 5mM K3Fe(CN)6 and 100mM KNO3. To compare the capability of the ion exchange of NiHCNFe film electrode, the repeated cyclic voltammograms were measured in the 0.5M cation nitrate solutions at $25^{\circ}C$ and pH7. It was found that the capacity of the electrochemically derivatized NiHCNFe reduced in the rate of 0.5~0.7%/cycle and was nearly exhausted at the 150th potential cycle. Better result was obtained from that the capacity loss of the chemically assembled NiHCNFe was less than 0.02%/cycle for 5,000cycles. Furthermore, the residual capacity was more than 30% at the 5,000th cycle.

Characteristics of the Electrochemical Ion Exchanger for the Treatment of Cations in Nuclear Wastewater (원자력 폐수의 양이온 처리를 위한 전기화학적 이온교환체의 특성)

  • Hwang, Young-Gi
    • Journal of the Korean Society of Industry Convergence
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    • v.19 no.4
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    • pp.176-184
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    • 2016
  • Electrochemical ion exchange method is expected to be one of the most acceptable techniques for the separation of radioactive cations from nuclear wastewater. In this study a thin film of hexacyanoferrate on nickel surface was derivatized chemically in an aqueous potassium-ferricyanide solution. Electrochemical redox behavior of the nickel hexacyanoferrate(NiHCNFe) film electrode was investigated with the use of cyclic voltammetry potentiostated from -100 to 800 mV versus SCE. The electro-reduction characteristics of the NiHCNFe film were examined in the cobalt solutions. The NiHCNFe ion exchanger was more useful at lower concentration, lower temperature, and pH7 of the cobalt solution. The capacity loss of NiHCNFe was 0.018%/cycle that was less than the average loss of 2~3%/cycle of the convective organic exchanger. The 45~55% of the initial cobalt ions was electro-deposited on the NiHCNFe by using continuous recirculating reactor system. As a result, it was found that the electroactive NiHCNFe films showed better performance than the organic resins for the separation of cobalt ion from the aqueous solutions.

Development Trend of Ni-less Surface Treatment Technology for Semiconductor Packaging Substrates (반도체 패키지 기판용 Ni-less 표면처리 기술 개발동향)

  • Min-Kyo Cho;Jin-Ki Cho;Kyoung-Min Kim;Sung Yong Kim;Deok-Gon Han;Tae-Hyun Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.1
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    • pp.49-54
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    • 2023
  • Recently, System in Packaging(SIP) technology needs to meet high frequency (5G and more) communication technology and fine pitch surface treatment. The conventional Electroless Ni/Immersion Au plating(ENIG) is not suitable for high frequency range because of magnetic properties are increasing the transmission loss. Without nickel plating layer, the pattern and pad reliability level must be meet the condition. In this review paper, we investigated research trends on Ni-less surface treatment technology for high-frequency communication and frequency characteristics according to materials.