• Title/Summary/Keyword: New Materials

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Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

  • Zhao, Pusu;Jing, Wang;Jing, Long;Jian, Fangfang;Li, Yufeng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3743-3748
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    • 2013
  • A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with $ZnI_2$ and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of $I^-$ ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.

The Study of a-Si Film Crystallization using an XeCl Laser Annealing on the Plastic Substrate

  • Kim, Do-Young;Suh, Chang-Ki;Shim, Myung-Suk;Kim, Chi-Hyung;Yi, Jun-Sin;Lee, Min-Chul;Han, Min-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.634-638
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    • 2003
  • We reported the a-Si crystallization using a XeCl excimer laser annealing on the plastic substrate. The poly-Si film is able to grow in the low temperature and light substrate like a plastic. For the preparation of sample, substrate is cleaned by organic liquids. The film of $CeO_{2}$ layer as the buffer layer was grown by sputtering methods. After a-Si film deposition using ICPCVD, the film was crystallized by XeCl excimer laser. In this paper, we present the crystallization properties of a-Si on the plastic substrate

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Application of Spray Pyrolysis Process for Production of Ultra Pure and Fine Powder. (고순도 초미립 분체제조를 위한 분무열분해법의 응용)

  • Yu, Jae-Keun;Park, Hee-Beom;Park, Joo-Ill;Han, Jung-Soo;Han, Jin-A;Nam, Yung-Hyeon
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.39-41
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    • 2000
  • Newly modified spray Pyrolysis system was developed to Produce ultra Pure and fine Powder by spray Pyrolysis Process. In this system, raw material solution was effectively atomized and sprayed into the reaction furnace. Also, thermal decomposition process fully completed in the three zone reaction furnace, and produced powder was effectively collected. A technology to reduce impurities in complex acid solution below 20ppm was also developed. The characteristics of produced powder were studied by changing the reaction conditions such as reaction temperature, the injection velocity of the solution and air, nozzle tip size and concentration of solution. The morphology of powder had spherical shape under the most experimental conditions, and the composition and the particle size distribution were almost uniform. Under the most experimental conditions average particle size of most produced powder was below 100nm.

New Bio-based Polymeric Materials from Plant Oils

  • Uyama, Hiroshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.359-359
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    • 2006
  • This study deals with development of new bio-based polymeric materials from epoxidized soybean oil (ESO). The curing of ESO in the presence of organophilic montmorillonite produced an oil polymer-clay nanocomposite ("green nanocomposite") showing flexible property. A green nanocomposite (oil polymer-silica nanocomposite) coatings were synthesized by an acidcatalyzed curing of ESO with 3-glycidoxypropyltrimethoxysilane. The curing of ESO in the presence of a biodegradable plastic, poly(caprolactone), produced a composite with semi-IPN structure. The mechanical properties of the composite was much superior to those of polyESO. These new oil-based materials have large potential for applications in various fields.

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