• Title/Summary/Keyword: New Fourier relationship

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Discrimination of Floral Scents and Metabolites in Cut Flowers of Peony (Paeonia lactiflora Pall.) Cultivars

  • Ahn, Myung Suk;Park, Pue Hee;Kwon, Young Nam;Mekapogu, Manjulatha;Kim, Suk Weon;Jie, Eun Yee;Jeong, Jae Ah;Park, Jong Taek;Kwon, Oh Keun
    • Korean Journal of Plant Resources
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    • v.31 no.6
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    • pp.641-651
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    • 2018
  • Floral scents and metabolites from cut flowers of 14 peony cultivars (Paeonia lactiflora Pall.) were analyzed to discriminate different cultivars and to compare the Korean cultivar with the other cut peonies imported to Korea using electronic nose (E-nose) and Fourier transform infrared (FT-IR) spectroscopy combined with multivariate analysis, respectively. Principal component analysis (PCA) and discriminant function analysis (DFA) dendrogram of peony floral scents were not precisely same but there were 3 groups including same cultivars. PCA and partial least squares-discriminant analysis (PLS-DA) dendrograms of peony metabolites showed that different cut peony cultivars were clustered into two major groups including same cultivars. Fragrance pattern of Korean 'Taebaek' was classified to same group with 'Jubilee' on the PCA and DFA results and its metabolite pattern was clearly discriminated by the PCA and PLS-DA compared to the other cultivars. These results show that the 14 peony cut flowers could be discriminated corresponding to their chemical relationship and the metabolic profile of Korean 'Taebaek' has distinctive characteristics. Furthermore, we suggest that these results could be used as the preliminary data for breeding new cut peony cultivars and for improving the availability of Korean cut peony in cosmetic industry.

Hydrogen-bonded clusters in transformed Lewis acid to new Brønsted acid over WOx/SiO2 catalyst

  • Boonpai, Sirawat;Wannakao, Sippakorn;Panpranot, Joongjai;Praserthdam, Supareak;Chirawatkul, Prae;Praserthdam, Piyasan
    • Advances in nano research
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    • v.12 no.3
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    • pp.291-300
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    • 2022
  • The behavior of hydrogen species on the surface of the catalyst during the Lewis acid transformation to form Brønsted acid sites over the spherical silica-supported WOx catalyst was investigated. To understand the structure-activity relationship of Lewis acid transformation and hydrogen bonding interactions, we explore the potential of using the in situ diffuse reflection infrared Fourier transform spectroscopy (DRIFTS) with adsorbed ammonia and hydrogen exposure. From the results of in situ DRIFTS measurements, Lewis acid sites on surface catalysts were transformed into new Brønsted acid sites upon hydrogen exposure. The adsorbed NH3 on Lewis acid sites migrated to Brønsted acid sites forming NH4+. The results show that the dissociated H atoms present on the catalyst surface formed new Si-OH hydroxyl species - the new Brønsted acid site. Besides, the isolated Si-O-W species is the key towards H-bond and Si-OH formation. Additionally, the H atoms adsorbed surrounding the Si-O-W species of mono-oxo O=WO4 and di-oxo (O=)2WO2 species, where the Si-O-W species are the main species presented on the Inc-SSP catalysts than that of the IWI-SSP catalysts.

Development of Misfire Detection Using Spark-plug (스파크플러그를 이용한 실화감지에 관한 연구)

  • 채재우;이상만;정영식;최동천
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.1
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    • pp.27-37
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    • 1997
  • Internal combustion engine is the main source of environmental pollutants and therefore better technology is required to reduce harmful elements from the exhaust gases all over the world. Especially, harmful elements from the exhaust gases are caused by incomplete combustion of mixture inside the engine cylinder and this abnormal combustion like misfire or partial burning is the direct cause of the air pollution and engine performance degradation. the object of this research is to detect abnormal combustion like misfire and to keep the engine performance in the optimal operating state. Development of a new system therefore could be applied to a real car. To realize this, the spark-plug in a conventional ignition system is used as a misfire detection sensor and breakdown voltage is analyzed. In this research, bias voltage(about 3kV) was applied to the electrodes of spark-plug and breakdown voltage signal is obtained. This breakdown voltage signal is analyzed and found that a combustion phenomena in engine cylinder has close relationship with harmonic coefficient K which was introduced in this research. Newly developed combustion diagnostic method( breakdown voltage signal analysis) from this research can be used for the combustion diagnostic and combustion control system in an real car.

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Characteristics of the Fatigue Index in EMG Power Spectrum Analysis During Isokinetic Exercise (등속성 운동 시 근전도 주파수 분석에서 얻은 피로지수의 특성)

  • Won, Jong-Im;Cho, Sang-Hyun;Yi, Chung-Hwi;Kwon, Oh-Youn;Lee, Young-Hee;Park, Jung-Mi
    • Physical Therapy Korea
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    • v.8 no.3
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    • pp.11-26
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    • 2001
  • In rehabilitation programs involving muscle re-education and endurance exercise, it is necessary to confirm when fatigue occurs. It is also necessary to quantify fatigue, to confirm whether the muscle has been exercised sufficiently. In general, as fatigue occurs, the force-generating ability of the muscle is reduced. If the median frequency (MDF) obtained from electromyogram (EMG) power spectrum is correlated highly with work, then the timing and degree of fatigue may be confirmed. This study examined the relationship between work and MDF obtained from the EMG power spectrum during repetitive isokinetic exercise. Surface EMG signals were collected from biceps brachii and vastus lateralis of 52 normal subjects (26 males, 26 females) at $120^{\circ}/sec$ and $60^{\circ}/sec$ while performing an isokinetic exercise. The exercise was finished at 25% of peak work. MDF data was obtained using a moving fast Fourier transformation (FFT), and random noise was removed using the inverse FFT, then a new MDF data was obtained from the main signal. There was a high correlation between work and MDF during repetitiv isokinetic exercise in the biceps brachii and vastus lateralis of males and the biceps brachii of females (r=.50~.77). However, there was a low correlation between work and MDF in the vastus lateralis of females (r=.06~.19).

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Ultrasonic characterization of exhumed cast iron water pipes

  • Groves, Paul;Cascante, Giovanni;Knight, Mark
    • Smart Structures and Systems
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    • v.7 no.4
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    • pp.241-262
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    • 2011
  • Cast iron pipe has been used as a water distribution technology in North America since the early nineteenth century. The first cast iron pipes were made of grey cast iron which was succeeded by ductile iron as a pipe material in the 1940s. These different iron alloys have significantly different microstructures which give rise to distinct mechanical properties. Insight into the non-destructive structural condition assessment of aging pipes can be advantageous in developing mitigation strategies for pipe failures. This paper examines the relationship between the small-strain and large-strain properties of exhumed cast iron water pipes. Nondestructive and destructive testing programs were performed on eight pipes varying in age from 40 to 130 years. The experimental program included microstructure evaluation and ultrasonic, tensile, and flexural testing. New applications of frequency domain analysis techniques including Fourier and wavelet transforms of ultrasonic pulse velocity measurements are presented. A low correlation between wave propagation and large-strain measurements was observed. However, the wave velocities were consistently different between ductile and grey cast iron pipes (14% to 18% difference); the ductile iron pipes showed the smaller variation in wave velocities. Thus, the variation of elastic properties for ductile iron was not enough to define a linear correlation because all the measurements were practically concentrated in single cluster of points. The cross-sectional areas of the specimens tested varied as a result of minor manufacturing defects and levels of corrosion. These variations affect the large strain testing results; but, surface defects have limited effect on wave velocities and may also contribute to the low correlations observed. Lamb waves are typically not considered in the evaluation of ultrasonic pulse velocity. However, Lamb waves were found to contribute significantly to the frequency content of the ultrasonic signals possibly resulting in the poor correlations observed. Therefore, correlations between wave velocities and large strain properties obtained using specimens manufactured in the laboratory must be used with caution in the condition assessment of aged water pipes especially for grey cast iron pipes.