• Title/Summary/Keyword: Negative temperature coefficient

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Investigation of Autoignition of Propane and n-Butane Blends Using a Rapid Compression Machine

  • Kim, Hyunguk;Yongseob Lim;Kyoungdoug Min;Lee, Daeyup
    • Journal of Mechanical Science and Technology
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    • v.16 no.8
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    • pp.1127-1134
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    • 2002
  • The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

Polymorphic Phase Transition and Temperature Coefficient of Capacitance of Alkaline Niobate Based Ceramics

  • Bae, Seon-Gi;Shin, Hyea-Gyiung;Sohn, Eun-Young;Im, In-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.78-81
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    • 2013
  • $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3+0.2wt%\;Ag_2O$ (hereafter, No excess NKN) ceramics and $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3+0.2wt%\;Ag_2O$ with excess $(Na_{0.5}K_{0.5})NbO_3$ (hereafter, Excess NKN) were fabricated by the conventional solid state sintering method, and their phase transition properties and dielectric properties were investigated. The crystalline structure of No excess NKN ceramics and Excess NKN ceramics were shown characteristics of polymorphic phase transition (hereafter, PPT), especially shift from the orthorhombic to tetragonal phase by increasing sintering temperature range from $1,100^{\circ}C$ to $1,200^{\circ}C$. Also, the temperature coefficient of capacitance (hereafter, TCC) of No excess NKN ceramics and Excess NKN ceramics from $-40^{\circ}C$ to $100^{\circ}C$ was measured to evaluate temperature stability for applications in cold regions. The TCC of No excess NKN and Excess NKN ceramics showed positive TCC characteristics at a temperature range from $-40^{\circ}C$ to $100^{\circ}C$. Especially, Excess NKN showed a smaller TCC gradient than those of Excess NKN ceramics in range from $-40^{\circ}C$ to $100^{\circ}C$. Therefore, NKN piezoelectric ceramics combined with temperature compensated capacitor having negative temperature characteristics is desired for usage in cold regions.

Measuring Apparatus for Convective Heat Transfer Coefficient of Nanofluids Using a Thermistor Temperature Sensor (더미스터 온도센서를 이용한 나노유체의 대류열전달계수 측정 장치)

  • Lee, Shin Pyo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.2
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    • pp.103-110
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    • 2016
  • Fine wires made from platinum have been used as sensors to evaluate the convection performance of nanofluids. However, the wire sensor is difficult to handle due to its fragility. Additionally, an unrealistic convective heat transfer coefficient (h) is obtained if a rigorous calibration process combined with precision equipment is not used for measurement. This paper proposes a new evaluation apparatus for h of nanofluids that uses a thermistor sensor instead of the platinum wire. The working principles are also explained in detail. Validation experiments for pure engine oil comparing h from the two sensors confirmed numerous practical benefits of the thermistor. The proposed system can be used as a useful tool to justify the adoption of developed nanofluids.

Electrical Properties of Multilayer Chip Varistors in the Response Surface Analysis (반응표면분석법에 의한 적층 칩 바리스터의 전기적 특성)

  • Yoon, Jung-Rag;Jeong, Tae-Seok;Choi, Keun-Mook;Lee, Seok-Weon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.496-501
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    • 2007
  • In order to enhance sintering characteristics on the $ZnO-Pr_6O_{11}$ based multilayer chip varistors (MLVs), a response surface analysis using central composite design method were carried out. As a result, varistor voltage($V_{1mA}$), nonlinear coefficient ($\alpha$), leakage current ($I_L$) and capacitance (C) were considered to be mainly affected by sintered temperature and holding time. MLVs sintered at $1200^{\circ}C$ and above $1200^{\circ}C$ revealed poor electrical characteristics, possibly due to the reaction between electrode materials(Pd) and $ZnO-Pr_6O_{11}$ based ceramics. On the sintering temperature range $1150{\sim}1175^{\circ}C$, nonlinear coefficient ($\alpha$) and leakage current ($I_L$) were shown to be $60{\sim}69$ and below $0.3{\mu}A$, respectively. In particular, MLVs sintered at $1175^{\circ}C$, 1.5 hr and $2^{\circ}C/hr$ (cooling speed) showed stable ESD(Electrical Static Discharge) characteristics under the condition of 10 times at 8 Kv with deviation varistor voltage, and deviation nonlinear coefficient were 0.3% and 0.33% (at positive), 0.55% (at negative), respectively.

Thermoelectric Properties of Binary Skutterudite CoSb3 Prepared by Encapsulated Induction Melting (밀폐유도용해로 제조된 2원계 Skutterudite CoSb3의 열전특성)

  • You, Sin-Wook;Jung, Jae-Yong;Ur, Soon-Chul;Kim, Il-Ho
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.312-317
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    • 2006
  • Binary skutterudite $CoSb_3$ compounds were prepared by the encapsulated induction melting (EIM) process, and their thermoelectric, microstructural and mechanical properties were examined. Single-phase ${\delta}-CoSb_3$ was successfully produced by the EIM and subsequent heat treatment at 773 K-873 K for 24 hours in vacuum. Seebeck coefficient increased with increasing heat treatment temperature up to 673 K, showing the positive signs in the range of measuring temperature. However, the samples heat-treated at 773 K-873 K showed negative Seebeck coefficient from room temperature to 400 K, while it showed positive signs above 400 K. Electrical resistivity decreased with increasing temperature, showing typical semiconducting conductivity. Thermal conductivity decreased drastically with increasing heat-treatment temperature. This is closely related with the phase transition to ${\delta}-CoSb_3$.

Micro flow sensor using polycrystalline silicon carbide (다결정 실리콘 카바이드를 이용한 마이크로 유량센서)

  • Lee, Ji-Gong;Lei, Man I;Lee, Sung-Pil;Rajgopal, Srihari;Mehregany, Mehran
    • Journal of Sensor Science and Technology
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    • v.18 no.2
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    • pp.147-153
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    • 2009
  • A thermal flow sensor has been fabricated and characterized, consisting of a center resistive heater surrounded by two upstream and one downstream temperature sensing resistors. The heater and temperature sensing resistors are fabricated from nitrogen-doped(n-type) polycrystalline silicon carbide(poly-SiC) deposited by LPCVD(low pressure chemical vapor deposition) on LPCVD silicon nitride films on a Si substrate. Cavities were etched into the Si substrate from the front side to create suspended silicon nitride membranes carrying the poly-SiC elements. One upstream sensor is located $50{\mu}m$ from the heater and has a sensitivity of $0.73{\Omega}$/sccm with ${\sim}15\;ms$ rise time in a dynamic range of 1000 sccm. N-type poly-SiC has a linear negative temperature coefficient and a TCR(temperature coefficient of resistance) of $-1.24{\times}10^{-3}/^{\circ}C$ from room temperature to $100^{\circ}C$.

Analysis of Temperature Profiles by Land Use and Green Structure on Built-up Area (시가화지역 토지이용 및 녹지구조에 따른 온도변화 연구)

  • Hong Suk-Rwan;Lee Kyong-Jae;Han Bong-Ho
    • Korean Journal of Environment and Ecology
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    • v.19 no.4
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    • pp.375-384
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    • 2005
  • This study was conducted selecting 44 places with a block unit subject to urban area in Gangnam-gu, to analyze a temperature change according to land use and green structure. In this study, it was used the broad-wide urban temperature, supported by Landset TM and ETM+ satellite image 6scene(1999${\~}$2002). The result of the research, the land use pattern has slightly influence on a temperature change of urban area. The result from correlation analysis between temperature and the factors affected by land cover type, such as building-to-land ratio(A correlation coefficient is 0.368${\~}$0.709) have positive correlation and green area ratio(a correlation coefficient is -0.551${\~}$-0.860) have negative correlation. The result from correlation analysis between temperature and green capacity of the land, crown projection area ratio, each factor have negative correlation with temperature, as showing that a correlation coefficient of green capacity of the land is -0.577(June 2006)${\~}$-0.882(June 1999) and crown projection area ratio's is -0.549(June 2001)${\~}$-0.817(June 1999). The result of the regression analysis for establishing urban area temperature change prediction model showed that green capacity of the land of the explanation variable was accepted.

Electrical properties of (Na0.5Bi0.5)(Zr0.75Ti0.25)O3 ceramic

  • Lily, Lily;Yadav, K.L.;Prasad, K.
    • Advances in materials Research
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    • v.2 no.1
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    • pp.1-13
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    • 2013
  • Lead-free compound $(Na_{0.5}Bi_{0.5})(Zr_{0.75}Ti_{0.25})O_3$ was prepared using conventional ceramic technique at $1070^{\circ}C$/4h in air atmosphere. X-ray diffraction analysis showed the formation of single-phase orthorhombic structure. Permittivity data showed low temperature coefficient of capacitance ($T_{CC}{\approx}5%$) up to $100^{\circ}C$. Complex impedance studies indicated the presence of grain boundary effect, non-Debye type dielectric relaxation and evidences of a negative temperature coefficient of resistance. The ac conductivity data were used to evaluate the density of states at Fermi level and apparent activation energy of the compound.

Design of an Embedded RC Oscillator With the Temperature Compensation Circuit (온도 보상기능을 갖는 내장형RC OSCILLATOR 설계)

  • 김성식;조경록
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.4
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    • pp.42-50
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    • 2003
  • This paper presents an embedded RC oscillator which has temperature compensation circuits. The conventional RC oscillator has frequency deviation about 15%, which is caused by variation of resistors and the reference voltage of schmitt trigger from the temperature condition. In this paper, the proposed circuit use a CMOS bandgap reference having balanced current temperature coefficients as a triggering voltage of schmitt trigger. The constant current sources consist of current mirror circuit with the positive and negative temperature coefficient. The proposed circuit shows less 3% frequency deviation for variation of temperature, supply voltage and process parameters.

Electrical Conductive Mechanism of Hot-pressed $\alpha-SiC-ZrB_2$ Composites (고온가압소결한 $\alpha-SiC-ZrB_2$ 복합체의 전기전도기구)

  • Shin, Yong-Deok;Ju, Jin-Young;Kwon, Ju-Sung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.104-108
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    • 1999
  • The electrical conductive mechanism and temperature dependence of electrical resistivity of $\alpha-SiC-ZrB_2$ composites with $ZrB_2$ contents were investigated. The electrical resistivity of hot-pressed composites was measured by the Pauw method form $25^{\circ} to 700^{\circ}C$. The electrical resistivity of the composites follow the electrical conduction model for a homogeneous mixture of two kind of particles with different conductivity. Also, the electrical resistivity versus temperature curves indicate the formation of local chains of $ZrB_2$ particles. In case of $\alpha-SiC-ZrB_2$ composites containing above 39vol.% $ZrB_2$ showed positive temperature coefficient resistance(PTCR), whereas the electrical resistivity of $\alpha-SiC-21vol.% ZrB_2$ showed negative temperature coefficient resistance(NTCR).

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