• Bulletin of the Korean Chemical Society
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• v.5 no.3
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• pp.112-117
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• 1984

The association constants (K) of 3,5,N-trimethyl pyridinium iodide in 95 volume percent ethanol-water mixed solvent were determined by a modified UV and conductance method at $25^{\circ},\;30{\circ},\;40{\circ}\;and\;50{\circ}C$ over the pressure range 1 to 2000 bars. The association process is enhanced with increasing pressure and decreasing temperature. From K values, we obtained the total partial molar volume change (${\Delta}V$) and some thermodynamic parameters. The electrostriction volume (${\Delta}V_{el}$) and intrinsic volume (${\Delta}V_{in}$) were also evaluated. The values of ${\Delta}V,\;{\Delta}V_{el},\;{\Delta}V_{in}$ are negative, negative and positive, respectively, and the absolute values of all these three decrease with increasing pressure and temperature. The ion-pair size (a) were varied 3 to 6 ${\AA}$, with pressure and temperature. The solvation number (n) decreased from 2 to 0.5 with increasing temperature.

• Journal of Industrial Technology
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• v.15
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• pp.15-22
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• 1995

We have studied the generation and behavior of negative ions in silane plasmas. The negative ions were formed by homogeneous reaction in silane plasma and the behavior of negative ions were predicted by solving the model equations. The concentration profiles of negative ions were shown as a function of reactor length and time. The effects of process variables such as reactor pressure, flow rate and electrical field strengths on the behavior of negative ions were analyzed.

• Archives of Plastic Surgery
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• v.42 no.1
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• pp.59-67
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• 2015

Background Negative-pressure wound therapy (NPWT) induces angiogenesis and collagen synthesis to promote tissue healing. Although acetic acid soaks normalize alkali wound conditions to raise tissue oxygen saturation and deconstruct the biofilms of chronic wounds, frequent dressing changes are required. Methods Combined use of NPWT and acetic acid irrigation was assessed in the treatment of chronic wounds, instilling acetic acid solution (1%) beneath polyurethane membranes twice daily for three weeks under continuous pressure (125 mm Hg). Clinical photographs, pH levels, cultures, and debrided fragments of wounds were obtained pre- and posttreatment. Tissue immunostaining (CD31, Ki-67, and CD45) and reverse transcription-polymerase chain reaction (vascular endothelial growth factor [VEGF], vascular endothelial growth factor receptor [VEGFR]; procollagen; hypoxia-inducible factor 1 alpha [HIF-1-alpha]; matrix metalloproteinase [MMP]-1,-3,-9; and tissue inhibitor of metalloproteinase [TIMP]) were also performed. Results Wound sizes tended to diminish with the combined therapy, accompanied by drops in wound pH (weakly acidic or neutral) and less evidence of infection. CD31 and Ki-67 immunostaining increased (P<0.05) post-treatment, as did the levels of VEGFR, procollagen, and MMP-1 (P<0.05), whereas the VEGF, HIF-1-alpha, and MMP-9/TIMP levels declined (P<0.05). Conclusions By combining acetic acid irrigation with negative-pressure dressings, both the pH and the size of chronic wounds can be reduced and infections be controlled. This approach may enhance angiogenesis and collagen synthesis in wounds, restoring the extracellular matrix.

• Explosives and Blasting
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• v.35 no.1
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• pp.1-17
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• 2017

The understanding of the pressure associated with air blast, which travels through air, and its effect on surface and underground structures is highly important. It is necessary to determine the pressure change with time and distance for a computer simulation of the explosion impact on a structure. From the previous studies, many empirical equations for estimating the parameters related to the pressure change. In this study, the empirical equations for predicting peak overpressure, duration of positive phase, impulse, minimum negative pressure, duration of negative pressure, arrival time, and decay constant were reviewed and analyzed. Also, the pressure changes predicted from the Kingery equation, which is the most commonly used, and from the other empirical equations were compared.

• Journal of Microbiology and Biotechnology
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• v.12 no.1
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• pp.149-152
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• 2002

The effect of pressure on the catalytic properties of glutamate racemase from Aquifex pyrophilus, an extremophilic bacterium, was investigated. The activation volume for the overall reaction $({\Delta}V^{\neq})$ and catalysis $({{Delta}V_{cat}}^{\neq})$ was -96.97 ml/mol and 4.97 ml/mol, respectively, while the reaction volume for the substrate binding (${\Delta}V_{K_m^-1}$) was -101.94 ml/mol. The large negative ${\Delta}V^{\neq}$ for the overall reaction indicated that the pressurization of glutamate racemase resulted in enhanced catalytic efficiencies. In addition, this value was also due to the large negative ${Delta}V_{K_m^-1}$ for the substrate binding. The negative value of ${Delta}V_{K_m^-1}$ implied that the conformational changes in the enzyme molecule occurred during the substrate binding process, thereby increasing the degree of hydration. The small value of ${{Delta}V_{cat}}^{\neq}$suggested that the pressure did not affect the glutamate racemase catalysis after the substrate binding.

• The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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• v.22 no.1
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• pp.65-70
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• 2016

Background: To determine the correlation Between forward head posture and plantar pressor in a McKenzie Exercise. Methods: This study had a cross-sectional design. There are included 20 participants with forward head posture. We measured the craniovertebral angle (CVA), cranial rotation angle (CRA) by image obtained digital camera and the plantar pressure, static balance using Gait Analyzer each before and after McKenzie Exercise. Results: There was negative correlation between CVA and CRA (p<.05). There was negative correlation between CVA and fore foot(p<.05). There was positive correlation between CRA and both fore foot (p<.05). There was negative correlation between CVA and static balance(p<.05). There was positive correlation between CRA and static balance (p<.05). Conclusions: There is a correlation between the change a mount of forward head position and plantar pressure in the McKenzie Exercise.

• Journal of The Korea Institute of Healthcare Architecture
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• v.28 no.4
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• pp.51-60
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• 2022

Purpose: This study aims to analyze and supplement the standards related to healthcare facilities, negative pressure isolation wards, and emergency treatment facilities. In addition, through environmental investigations, analysis of emergency remodeling cases centered on the structural and HVAC characteristics of healthcare facilities is conducted. Methods: Domestic and foreign standards related to healthcare facilities were analyzed. Field investigations and architectural drawing analysis of general and emergency treatment facilities were conducted. Results: Healthcare facilities have different space classifications and air conditioning methods depending on the site situation. Emergency treatment facilities are classified into cases where the HVAC system is remodeled and portable negative pressure unit is installed, and some facilities did not meet the standards for differential pressure and air change rate. Implications: When developing emergency remodeling technology, remodeling and safety evaluation guidelines, it is considered possible to propose clearer guidelines for emergency remodeling treatment facilities for infectious diseases in Korea by referring to the results of this study.

• Journal of the Korean Geotechnical Society
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• v.23 no.10
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• pp.57-64
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• 2007

Since matric suction of unsaturated soil was related to soil and ground water contaminations, it is very important to analyze its mechanism that was represented by shear characteristics. In three phases of soil, a little air makes the condition of unsaturated soil on contract or shrinkage surface between water and air. Capillarity and suction in pore of unsaturated soil cause surface tension and surface force so it makes negative pore water pressure and increases effective stress as a result. Therefore, negative pore water pressure in partially saturated soil affects the soil structure and degree of saturation and it is important to evaluate accurately unsaturate flow and behavior. In this study, the shear strength characteristics of the seven sandy soils were investigated using consolidated drained triaxial tests with special emphasis on the effects of the negative pore pressure and the matric suction. These tests involved shearing under either a constant net confining pressure and varying matric suction or under a constant matric suction and varying net normal stress.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.4
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• pp.281-288
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• 2014

As a gas explosion is the most fatal accident in shipbuilding and offshore plant industries, all safety critical elements on the topside of offshore platforms should retain their integrity against blast pressure. Even though many efforts have been devoted to develop blast-resistant design methods in the offshore engineering field, there still remain several issues needed to be carefully investigated. From a procedure for calculation of explosion design pressure, impulse of a design pressure model having completely positive side only is determined by the absolute area of each obtained transient pressure response through the CFD analysis. The negative pressure phase in a general gas explosion, however, is often quite considerable unlike gaseous detonation or TNT explosion. The main objective of this study is to thoroughly examine the effect of the negative pressure phase on structural behavior. A blast wall for specific FPSO topside is selected to analyze structural response under the blast pressure. Because the blast wall is considered an essential structure for blast-resistant design. Pressure time history data were obtained by explosion simulations using FLACS, and the nonlinear transient finite element analyses were performed using LS-DYNA.

• Wind and Structures
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• v.18 no.6
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• pp.651-668
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• 2014

Wind tunnel tests are conducted to investigate the wind loads on vertical fixed-roof cylindrical tanks with a very low aspect ratio of 0.275, which is a typical ratio for practical tanks with a volume of $100,000m^3$. Both the flat-roof tank and the dome-roof tank are investigated in present study. The first four moments of the measured wind pressure, including the mean and normalized deviation pressure, kurtosis and skewness of the pressure signal, are obtained to study the feature of the wind loads. It is shown that the wind loads are closely related to the behavior of flow around the structure. For either tank, the mean wind pressures on the cylinder are positive on the windward area and negative on the sides and the wake area, and the mean wind pressures on the whole roof are negative. The roof configurations have no considerable influence on the mean pressure distributions of cylindrical wall in general. Highly non-Gaussian feature is found in either tank. Conditional sampling technique, envelope method, and the proper orthogonal decomposition (POD) analysis are employed to investigate the characteristics of wind loads on the cylinder in more detail. It is shown that the patterns of wind pressure obtained from conditional sampling are similar to the mean pressure patterns.An instantaneous pressure coefficient can present a wide range from the maximum value to the minimum value. The quasi-steady assumption is not valid for structures considered in this paper according to the POD analysis.