• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1195-1198
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• 2013

Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

• Particle and aerosol research
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• v.17 no.4
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• pp.115-123
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• 2021

The emission gas from meat grilled restaurants has unpleasant odor and sticky particulate matters (PM) in form of oil mist. This affects the residents living nearby. In oder to decrease the odor and PM, electrostatic precipitators (ESP) were installed at several restaurants by support of Seoul metropolitan government and emission characteristics of PM and odor were investigated. The removal efficiency of odor and PM at before- and after-ESP was that total hydrocarbon (THC), NH₃, H₂S, acetaldehyde, butyraldehyde were not much decreased. Total suspended particles (TSP) emitted from the vent was below the value of 7 mg/m³ regardless of the concentration of before-ESP and removal efficiency was in the range of 64 ~ 86%. The ratio of PM_1.0 to PM₁₀ of emission gas was over 0.9. So it was revealed that most PM of emission gas was PM1.0. The PM concentration in the air of the street near the vent was higher than another street due to the emission gas and the PM of indoor air of restaurant grilling meats was measured very high compared to outdoor air. So it needs more powerful ventilation of indoor air.

• The Bulletin of The Korean Astronomical Society
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• v.45 no.1
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• pp.36.1-36.1
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• 2020

The progenitor of Type Ia supernovae (SNe Ia) is mainly believed to be a carbon/oxygen white dwarf (WD) with non-degenerate (single degenerate) or another WD companion (double degenerate). However, there is little observational evidence of their progenitor system. Recent studies suggest that shock-breakout cooling emission after the explosion can constrain the size of the progenitor system. To do so, we obtained a optical/Near-IR light curve of SN 2019ein, a normal but slightly sub-luminous type Ia supernova, from the very early phase using our high-cadence observation of Intensive Monitoring Survey of Nearby Galaxies (IMSNG). Assuming the expanding fireball model, the simple power-law fitting of the early part of the light curve gives power indices of 1.91 (B) and 2.09 (R) implying radioactive decay of 56Ni is the dominant energy source. By comparison with the expected light curve of the cooling emission, the early observation provides us an upper limit of the companion size of R∗≤1R⊙. This result suggests that we can exclude a large companion such as red giants, which is consistent with the previous study.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.06a
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• pp.197-201
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• 1997

The momentum, heat and mass trasfer phenomena in the silicon melt of the Czochralki crystal growth system are calculated using a three dimensional numerical simulation thechnique. Even though axisymmetrical boundary conditions are imposed to all calculations in a 3cm diameter crucible, several types of non-axisymmetric profiles of velocities, temperature and oxygen concentration appeared in the melt. Because of the non-axisymmetric profiles of velocities, temperature and oxygen concentration appeared in the melt. Because of the non-axisymmetric profiles and rotations of fluid induced by the crucible rotation, temperatures and oxygen concentrations in the silicon melt fluctuate. The rotating velocity of the profile is calculated from the phase shift of the data of temperature or oxygen at two different points which have same radius from center but 90 degree angular difference. From this calculation, it is found that the rotating veolocity of the oxygen and temperature is different from the crucible rotation rates. Therefore the frequencies of the oscillating temperature and oxygen concentrations are not same to the frequencies of the crucible rotations. Futhermore, the components of the frequencies of the temperature and oxygen concentration at the same point are not same. The fluctuation behaviors of the temperature or oxygen themselves are also different when the points are different. The calculation show that the temperature and the oxygen concentration near the interface also fluctuate. The results suggest that the striation pattern found in the grown silicon single crystals may ben generated by the oxygen concentration and the temperature oscillations of the melt occurred near the interface.

• Journal of the Korean Chemical Society
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• v.19 no.5
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• pp.289-293
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• 1975

According to the viscosity and density studies of an aqueous solution of dodecyl pyridinium chloride (DPC) it was shown that the 2nd critical micelle concentration (2nd cmc) existed in the solution in addition to the 1st cmc. The volume fraction ${\phi}_m$ of the hydrated micelle was calculated by using the following equation: ${\Pi}_{rm}=1+2.5{\phi}_m+14.1{\phi}_m^2$ It has been found that the increment of ${\phi}_m$ in the ${\phi}_m$ vs. $C_m$ curve decreased at near the 2nd cmc. And the partial specific volume ($\={v}$) of DPC obtained from the density measurement also decreased rapidly at near the 2nd cmc and remains constant value above the 2nd cmc. This may be attributed to a change in the micelle structure at the 2nd cmc caused by a variation in the type of aggregation and by a decrease in the counterion binding by the micelle.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.17 no.3
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• pp.166-177
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• 2005

This study developed the jet integral model to analyze the behavior of the wastewater discharge in the near field using the fourth order Runge-Kutta method in order to numerically solve the problems of six ordinary differential equations and six unknowns. This jet integral model used the entrainment hypothesis and the manipulation of sonle shape constant. This study also conducted the hydraulic experiments fnr single horizontal buoyant Jet using LIF through the calibration procedure. The results calculated by the previous models, CORMIX 1 and VISJET, and the proposed jet integral model were compared to the hydraulic experimental results. The centerline trajectories predicted by the proposed model were in good agreements with the experimental results in the transition region whereas the trajectories calculated by the VISJET model agreed well with the measured data in the momentum and buoyancy-dominated regions. The centerline dilution calculated by the proposed model agreed generally with the measured dilution in the intial and transition regions while the centerline dilution predicted by the CORMIX 1 was in good agreements with the experimental results in the momentum and buoyancy-dominated regions.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.35.1-35.1
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• 2015

We present the results of extinction measurements toward the main ejecta shell of the Cassiopeia A supernova (SN) remnant using the flux ratios between the two near-infrared (NIR) [Fe II] lines at 1.26 and $1.64{\mu}m$. We find a clear correlation between the NIR extinction (E(J-H)) and the radial velocity of ejecta knots, showing that redshifted knots are systematically more obscured than blueshifted ones. This internal "self-extinction" strongly indicates that a large amount of SN dust resides inside and around the main ejecta shell. At one location in the southern part of the shell, we measure E(J-H) by the SN dust of $0.23{\pm}0.05mag$. By analyzing the spectral energy distribution of thermal dust emission at that location, we show that there are warm (~100K) and cool (~40K) SN dust components and that the latter is responsible for the observed E(J-H). We investigate the possible grain species and size of each component and find that the warm SN dust needs to be silicate grains such as $MgSiO_3$, $Mg_2SiO_4$, and $SiO_2$, whereas the cool dust could be either small (${\leq}0.01{\mu}m$) Fe or large (${\geq}0.01{\mu}m$) Si grains. We suggest that the warm and cool dust components in Cassiopeia A represent grain species produced in diffuse SN ejecta and in dense ejecta clumps, respectively.

• Journal of Veterinary Clinics
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• v.34 no.5
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• pp.396-399
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• 2017

This is a case report of a northern goshawk (Accipiter gentilis), admitted to the wildlife rescue center with right coracoid and scapular fracture which received conservative treatment and was soft-released successfully. At the admission, the goshawk had callus formed on the fractured bones, scars on eyebrows and severely damaged tail feathers with inability to fly. Cage rest was indicated to prevent further occurrence of fracture and to promote reunion of the fracture surface. The bird went through a rehabilitation process with appropriate physical training in flying cage to recover its fitness and flying ability. Complete molting of flight feathers with damaged rectrices was achieved during the rehabilitation period and its flight ability was recovered favorably. It was released into a proper habitat for northern goshawks, but the bird was found near the aviary where its last phase of rehabilitation was performed. A soft-release program was applied and finally the bird returned to near the first rescue location 235 km away from the release site.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.2
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• pp.50.2-50.2
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• 2016

Polarization is a rich source of information on the physical properties of astronomical objects. In particular, scattered sunlight by optically thin media (e.g., cometary comae) shows linear polarization of light, which highly depends on the phase angle (an angle between the Sun-Comet-Earth), wavelengths, and physical properties of cometary dust particles such as size, composition, and structures. Here, we present a study of polarimetric properties of non-periodic comet C/2013 US10 (Catalina) in optical and near-infrared wavelength regions obtained from imaging, spectroscopy, and polarimetric observations taken on UT 2015 December 17 - 19 welcoming its (probably) first close approach to the Earth. In this presentation, we want to introduce our progress since the last Korean Astronomical Society meeting (at BEXCO, Busan, 2016 April 14 - 15) especially in terms of spatial variations of degree of linear polarization (DOLP) and its possible scenarios to explain the correlations with other observational results. In particular, we found that there is strong anti-correlation between the gas/dust flux ratio and DOLP at the cometocentric distance of $(2-5){\times}104 km$. Besides, within 10 arcseconds in radii (corresponding to inner coma region of 104 km from the center), the inverse relationship of these two parameters does not hold anymore. We conjecture that the rapid outward increase of DOLP can be supported by either the sublimation/evaporation of icy volatiles, disaggregation of cometary dust particles ejected from the nucleus, and/or difference of dominant dust particle sizes. From our results, we can conclude that comet C/2013 US10 (Catalina) corroborates rather indefinite traditional classification of poalrimetric classes of comets, and provides good opportunity to study less processed material which probably cherishes its memory at the formation epoch of the Solar System.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.2
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• pp.37.3-37.3
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• 2016

The SPEHREx (Spectro-Photometer for the History of the Universe Epoch of Reionization, and Ices Explorer) is one of the candidates for the Astrophysical Small Explore mission of the NASA proposed together with KASI (PI Institute: Caltech). It will perform an all-sky near-infrared spectral survey to probe the origin of the Universe and water in the planetary systems and to explore the evolution of galaxies. The SPHEREx is designed to cover wide field of view of $3.5{\times}7deg$. as well as wide spectral range from 0.7 to $4.8{\mu}m$ by using four linear variable filters. The SPHEREx is under the Phase-A study to finalize the conceptual design and test plan of the instrument. The international partner, KASI will contribute to the SPHEREx in the hardware as well as the major science cases. The final selection will be made in the early 2017. Here, we report the current status of the SPHEREx mission.