• Title/Summary/Keyword: NbR

Search Result 346, Processing Time 0.025 seconds

Conversion of Ginsenoside $Rb_1$ by Ginseng Soil Bacterium Cellulosimicrobium sp. Gsoil 235 According to Various Culture Broths (인삼 토양 미생물 Cellulosimicrobium sp. Gsoil 235의 배지조성에 따른 Ginsenoside $Rb_1$ 전환)

  • Na, Ju-Ryun;Kim, Yu-Jin;Kim, Se-Hwa;Kim, Ho-Bin;Shim, Ju-Sun;Kim, Se-Young;Yang, Deok-Chun
    • Microbiology and Biotechnology Letters
    • /
    • v.37 no.1
    • /
    • pp.55-61
    • /
    • 2009
  • Ginseng saponins (a secondary metabolite, termed ginsenosides) are the principal bioactive ingredients of ginseng, and modification of the sugar chains may markedly change the its biological activity. One of soil bacteria having $\beta$-glucosidase (to transform ginsenoside $Rb_1$) activity was isolated from soil of a ginseng field in Daejeon. 16S rRNA gene sequence analysis revealed that the isolate belonged to the genus Cellulosimicrobium, with highest sequence similarity (99.7%) to Cellulosimicrobium funkei ATCC BAA-$886^T$. The strain, Gsoil 235, could transform ginsenoside $Rb_1$ into Rd, $Rg_3$ and 3 of un-known ginsenosides by the analyses of TLC, HPLC. By investigating its deglycosylation progress, the optimal broth for, $\beta$-glucosidase was nutrient broth (In 48 hours, almost ginsenoside $Rb_1$ could be transformed into minor ginsenosides). On the contrary, the optimal broth for growth was determined as trypic soy broth (TSB).

Application of Electrochemical Technology for Reusing Biologically Treated Water (생물학적 처리수 재이용을 위한 전기화학 기술의 적용)

  • Kang, Gu-Young
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.30 no.4
    • /
    • pp.453-458
    • /
    • 2008
  • Laboratory experiments were conducted to investigate disinfection as well as removal of color and residual organics from reclaimed municipal wastewater by electrochemical processes with Nb/Pt anode installed. RNO was rapidly bleached by OH$\cdot$ and the second order rate constants of RNO removal were $\frac{0.223l}{mg{\cdot}min}$, $\frac{1.679l}{mg{\cdot}min}$ and $\frac{2.322l}{mg{\cdot}min}$ with for 5 A, 10 A, and 15 A, respectively, with r$^2$ of > 96%. In batch electrochemical processes, after 15 min at currency of 15 A and initial pH of 5, 7,5 and 9, COD$_{Mn}$ was below 4 mg/L, color unit below 5 degree and general bacteria was not detected, the concentration of which are suitable for drinking water regulation. In the continuous electrochemical process, with HRT of 3.7$\sim$49.2 min, free chlorine were 0.2$\sim$0.7 mg/L, general bacteria was not detected, color unit below 5 degree and THMs was 0.017 mg/L. Therefore, electrochemical process with Nb/Pt anode was employed satisfactory to meet for reusing biologically treated water as well as disinfection.

Effects of $B_2O_3$ Additives on the Sintering Temperature and Microwave Dielectric Properties of $Ba(Zn_{1/3}Nb_{2/3})O_3$ Ceramics ($B_2O_3$의 첨가가 $Ba(Zn_{1/3}Nb_{2/3})O_3$ 세라믹스의 소결 온도와 고주파 유전 특성에 미치는 영향)

  • Kim, Min-Han;Son, Jin-Ok;Nahm, Sahn;Yoo, Myong-Jae;Park, Jong-Cheol;Lee, Hwack-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07b
    • /
    • pp.611-614
    • /
    • 2004
  • [ $Ba(Zn_{1/3}Nb_{2/3})O_3$ ] (BZN) 세라믹스의 소결 온도는 약 $1350^{\circ}C$ 이다. 그러나 $B_2O_3$가 첨가된 경우, BZN 세라믹스는 $900^{\circ}C$에서 소결되었다. $BaB_4O_7$, $BaB_2O_4$ 그리고 $BaNb_2O_6$ 이차상이 $B_2O_3$가 첨가된 BZN 세라믹스에서 관찰되었다. $BaB_4O_7$$BaB_2O_4$ 이차상은 약 $900^{\circ}C$에서 공정 온도를 가지기 때문에 $B_2O_3$를 첨가한 BZN 세라믹스론 $900^{\circ}C$에서 소결하는 동안 액상으로 존재할 것으로 여겨지며, 그것이 BZN 세라믹스의 소결온도를 낮출 것으로 생각된다. 소결 온도의 증가에 따라 유전 상수 ($\varepsilon_r$)와 품질 계수 ($Q{\times}f$)의 값은 증가하였는데, 이는 밀도의 증가에 기인한다. 그러나 $B_2O_3$의 첨가량이 많은 경우 Q 값은 감소하는데, 이는 이차상의 존재가 품질계수의 저하를 초래한다고 생각된다. 2.0 mol% $B_2O_3$가 첨가된 BZN 세라믹스를 $950^{\circ}C$에서 2시간 동안 소결하는 경우, $Q{\times}f$=13.600 GHz, $\varepsilon_r$=37.6 그리고 공진 주파수 온도계수 ($\tau_f$) = 19 ppm/$^{\circ}C$의 유전특성을 얻을 수 있었다.

  • PDF

Synthesis and Luminescent Properties of Y(As, Nb, P, V)O4:Eu3+ Red Phosphors by Combinatorial Chemistry Method (조합화학을 이용한 Y(As, Nb, P, V)O4:Eu3+ 적색형광체의 합성 및 광 특성 분석)

  • Jeon, Il Un;Son, Gi Seon;Park, Hui Dong;Ryu, Seung Gon
    • Journal of the Korean Chemical Society
    • /
    • v.45 no.6
    • /
    • pp.577-588
    • /
    • 2001
  • Eu doped YRO$_4$ (R=As, Nb, P, V) red phosphors were prepared by the combinatorial chemistry method. The quaternary material library of tetrahedron-type composition array was designed to investigate the luminescence of the host material under UV and VUV excitations (254, 147 nm). The photoluminescent characteristics of the samples were comparable to the commercially available red phosphors such as (Y, Gd)BO$_3$: $Eu^{3+}$ and Y$_2$O$_3$: In view of the luminescence yield, V rich region was found to be optimum under UV excitation. But the results under VUV excitation were different from those of UV excitation, the samples of the composition containing a large amount of P shows the highest luminescence. Especially, higher luminescence was obtained in $Y_{0.9}$(A$S_{0.06}$N$B_{0.06}P_{0.83}V_{0.06}$) O$_4$: $Eu_{0.1}$ phosphors than commercial (Y, Gd)BO$_3$red phosphors under 147 nm excitation.

  • PDF

Microwave Dielectric Properties of (Pb,Ca)[(Fe,Nb)Sn]$O_3$ with CuO-$Bi_{2}O_{3}$Additives (CuO-$Bi_{2}O_{3}$첨가에 의한 (Pb,Ca)[(Fe,Nb)Sn]$O_3$세라믹스의 마이크로파 유전 특성)

  • 하종윤;최지원;윤석진;윤기현;김현재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.563-566
    • /
    • 2000
  • The effect of CuO and CuO-B $i_2$ $O_3$ additives on microwave dielectric properties of (P $b_{0.45}$C $a_{0.55}$)[F $e_{0.5}$N $b_{0.5}$)$_{0.9}$S $n_{0.1}$] $O_3$were investigated to decrease the sintering temperature for usage of Low Temperature Co-firing Ceramics (LTCC). The (P $b_{0.45}$C $a_{0.55}$)[F $e_{0.5}$N $b_{0.5}$)$_{0.9}$S $n_{0.1}$] $O_3$ceramics was sintered at 11$65^{\circ}C$. In order to decrease the sintering temperature, CuO and Cuo-B $i_2$ $O_3$ were added in the (Pb,Ca)[(Fe,Nb)Sn] $O_3$ with CuO-B $i_2$ $O_3$. For the addition of 0.4 wt.% CuO, the sintered density and the dielectric constant of the ceramics were revealed the maximum values of the 6.06g/c $m^2$ and 83 respectively and temperature coefficient of resonance frequency ($\tau$$_{f}$) shifted to the positive value. As increasing B $i_2$ $O_3$to the (Pb,Ca)[(Fe,Nb)Sn] $O_3$ with CuO-B $i_2$ $O_3$with 0.2 wt.% CuO, the sintered density, the $\varepsilon$$_{r}$ and the Q was decreased, and $\tau$$_{f}$ was minimized at 0.2 wt.% CuO, and 0.2 wt.% B $i_2$ $O_3$. For this composition, dielectric properties were $\varepsilon$$_{r}$ of 81, Q. $f_{0}$ of 4400 GHz, and $\tau$$_{f}$ of 5 ppm/$^{\circ}C$ at sintering temperature of 100$0^{\circ}C$. the relationship between the microstructure and properties of ceramics was studied by X-ray diffraction(XRD), scanning electron microscopy(SEM).copy(SEM).oscopy(SEM).copy(SEM).EM).

  • PDF

Identification and Functional Characterization of an afsR Homolog Regulatory Gene from Streptomyces venezuelae ATCC 15439

  • Maharjan, Sushila;Oh, Tae-Jin;Lee, Hei-Chan;Sohng, Jae-Kyung
    • Journal of Microbiology and Biotechnology
    • /
    • v.19 no.2
    • /
    • pp.121-127
    • /
    • 2009
  • Sequencing analysis of a 5-kb DNA fragment from Streptomyces venezuelae ATCC 15439 revealed the presence of one 3.1-kb open reading frame(ORF), designated as afsR-sv. The deduced product of afsR-sv(1,056 aa) was found to have high homology with the global regulatory protein AfsR. Homology-based analysis showed that aftR-sv represents a transcriptional activator belonging to the Streptomyces antibiotic regulatory protein(SARP) family that includes an N-terminal SARP domain containing a bacterial transcriptional activation domain(BTAD), an NB-ARC domain, and a C-terminal tetratricopeptide repeat domain. Gene expression analysis by reverse transcriptase PCR(RT-PCR) demonstrated the activation of transcription of genes belonging to pikromycin production, when aftR-sv was overexpressed in S. venezuelae. Heterologous expression of the aftR-sv in different Streptomyces strains resulted in increased production of the respective antibiotics, suggesting that afsR-sv is a positive regulator of antibiotics biosynthesis.

Crystal Structure and Piezoelectric Properties of Four Component Langasite A3B Ga3Si2O14 (A = Ca or Sr, B = Ta or Nb)

  • Ohsato, Hitoshi;Iwataki, Tsuyoshi;Morikoshi, Hiroki
    • Transactions on Electrical and Electronic Materials
    • /
    • v.13 no.4
    • /
    • pp.171-176
    • /
    • 2012
  • As langasite $A_3BC_3D_2O_{14}$ compounds with piezoelectric properties exhibit no phase transition up to the melting point of 1,400-$1,500^{\circ}C$, many high temperature applications are expected for the SAW filter, temperature sensor, pressure sensor, and so on, based on the digital transformation of wider bandwidth and higher-bit rates. It has a larger electromechanical coupling factor compared to quartz and also nearly the same temperature stability as quartz. The $La_3Ga_5SiO_{14}$ (LGS) crystal with the $Ca_3Ga_2Ge_4O_{14}$-type crystal structure was synthesized and the crystal structure was analyzed by Mill et al. It is also an important feature that the growth of the single crystal is easy. In the case of three-element compounds such as $[R_3]_A[Ga]_B[Ga_3]_C[GaSi]_DO_{14}$ (R=La, Pr and Nd), the piezoelectric constant increases with the ionic radius of R. In this study, crystal structures of four-element compounds such as $[A_3]_A[B]_B[Ga_3]_C[Si_2]_DO_{14}$ (A = Ca or Sr, B = Ta or Nb) are analyzed by a single crystal X-ray diffraction, and the mechanism and properties of the piezoelectricity depending on the species of cation was clarified based on the crystal structure.

Effects of Yb3+/Er3+ Ratios on the Down- and Up-Conversion Luminescence of YNbO4:Yb3+/Er3+ (Yb3+/Er3+ 비가 YNbO4:Yb3+/Er3+의 하향 및 상향전환 발광 특성에 미치는 영향)

  • Park, Jung Hye;Ahn, Wonsik;Lee, Eun Young;Kim, Young Jin
    • Korean Journal of Materials Research
    • /
    • v.25 no.9
    • /
    • pp.475-479
    • /
    • 2015
  • $YNbO_4:Yb^{3+}/Er^{3+}$ is synthesized using a solid-state reaction process with a LiCl flux. The effects of the Er/(Yb+Er) ratios ($R_{Er}$) on the up-conversion (UC) and down-conversion (DC) spectra are investigated. The XRD data confirm that the $Yb^{3+}$ and $Er^{3+}$ ions are fully substituted for the $Y^{3+}$ sites. The UC emission spectra activated by 980 nm consists of green and red emission bands, which originate from the $Er^{3+}$ ions through an energy transfer (ET) process from $Yb^{3+}$ to $Er^{3+}$. The UC emission intensity depends on the $R_{Er}$ value, and the findings demonstrate that $R_{Er}{\leq}0.14$ is suitable for an effective UC process. The DC emission spectra under 269 nm radiation of the synthesized powders exhibits not only a strong blue emission assigned to the $[NbO_4]^{3-}$ niobates, but also green peaks that originate from the $Er^{3+}$ ions through an ET process between $[NbO_4]^{3-}$ and $Er^{3+}$.

Temperature Coefficient of Dielectric Constant in CaTiO3-A(B′, B″)O3 Microwave Dielectric Ceramics (A=Ca, La, Li, B′=Al, Fe, Mg, B″=Nb, Ta)

  • Kim, Jeong-Seog;Cheon, Chae-Il;Park, Chan-Sik;Byun, Jae-Dong
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.10
    • /
    • pp.925-930
    • /
    • 2003
  • The dielectric polarizability-related factors contributing to the $\tau$$_{\varepsilon}$ have been analysed in terms of dielectric permittivity $\varepsilon$, Tolerance Factor (TF), and octahedron tilt angles in (1-x)CaTi $O_3$-x[A(B', B″) $O_3$] (A=Ca, La, Li, B'=Al, Fe, Mg, B″=Nb, Ta) and (S $r_{0.2}$C $a_{0.8}$)( $Ti_{1-x}$ Z $r_{x}$) $O_3$. All the compounds have the orthorhombic Pbnm structure except the end members A(B', B″) $O_3$ and the solid solutions of x$\geq$0.8. The additional dipole field effect is suggested as a dominant factor contributing to $\tau$$_{\varepsilon}$ in CaTi $O_3$-based ceramics having relatively large $\varepsilon$, which has not been generally considered in the previous reports dealing with the $\tau$$_{\varepsilon}$. This study has been focussed on delineating the dipole field effect on the $\tau$$_{\varepsilon}$ in comparison to the octahedron tilt effect in CaTi $O_3$-based ceramics.cs..cs.

Microwave Dielectric Properties of Ca[(Li1/3Nb2/3)0.2Ti0.8]O3-δ Ceramics with Addition of Zn-B-O Glass Systems (Zn-B-O 글라스 첨가에 의한 Ca[(Li1/3Nb2/3)0.2Ti0.8]O3-δ 세라믹스의 마이크로파 유전특성)

  • In, Chi-Seung;Kim, Shi Yeon;Yeo, Dong-Hun;Shin, Hyo-Soon;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.29 no.12
    • /
    • pp.781-785
    • /
    • 2016
  • With trend of the miniaturization and the high-functionalizing of mobile communication system, low-loss microwave dielectric materials are widely used for high frequency communication components. These dielectric materials should be co-sintered with highly electric-conducting metal such as silver or copper for high-frequency and thick film process application. Sintering temperature of $Ca(Li_{1/3}Nd_{2/3})_{0.2}Ti_{0.8}]O_{3-{\delta}}$, which has excellent dielectric properties such as ${\varepsilon}_r$ above 40, quality factor ($Q{\cdot}f_0$) above 16,000 GHz, and TCF (temperature coefficient of resonant frequency) of $-20{\sim}-10ppm/^{\circ}C$, is reported as high as $1,175^{\circ}C$, so it could not be co-sintered with silver or copper. Therefore in this study, low-temperature melting glasses of Zn-B-O and Zn-B-Si-O systems were added to $Ca[(Li_{1/3}Nb_{2/3})_{0.8}Ti_{0.2}]O_{3-{\delta}}$ to lower its sintering temperature under $900^{\circ}C$ without losing excellency of dielectric properties. With 15 weight % of Zn-B-Si-O glass and sintered at $875^{\circ}C$, specimen showed density of $4.11g/cm^3$, ${\varepsilon}_r$ of 40.1, $Q{\cdot}f_0$ of 4,869 GHz, and TCF of $-5.9ppm/^{\circ}C$. With 15 weight % of Zn-B-O glass and sintered at $875^{\circ}C$, specimen showed density of $4.14g/cm^3$, ${\varepsilon}_r$ of 40.4, $Q{\cdot}f_0$ of 7,059 GHz, and TCF of $-0.92ppm/^{\circ}C$.