• Title/Summary/Keyword: Nb addition

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Ferroelectricity of Bi-doped ZnO Films Probed by Scanning Probe Microscopy

  • Ben, Chu Van;Lee, Ju-Won;Kim, Jung-Hoon;Yang, Woo-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.323-323
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    • 2012
  • We present ferroelectricity of Bi-doped ZnO film probed by piezoresponse force microscopy (PFM), which is one of the Scanning Probe Microscopy techniques. Perovskite ferroelectrics are limited to integration of devices into semiconductor microcircuitry due to hard adjusting their lattice structure to the semiconductor materials. Transition metal doped ZnO film is one of the candidate materials for replacing the perovskite ferroelectrics. In this study, ferroelectric characteristics of the Bi-doped ZnO grown by pulsed laser deposition were probed by PFM. The polarization switching and patterning of the ZnO films were performed by applying DC bias voltage between the AFM tips and the films with varying voltages and polarity. The PFM contrast before and after patterning showed clearly polarization switching for a specific concentration of Bi atoms. In addition, the patterned regions with nanoscale show clearly the local piezoresponse hysteresis loop. The spontaneous polarization of the ZnO film is estimated from the local piezoresponse based on the comparison with LiNbO3 single crystals.

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Effects of Tin Addition on Microstructure and Corrosion of Zr-based Alloys (다원계 Zr합금에서 Sn첨가가 미세조직과 부식특성에 미치는 영향)

  • Kim, Jong-Seong;Park, Sang-Yun;Lee, Myeong-Ho;Jeong, Yong-Hwan;Jeong, Yeon-Ho
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.978-984
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    • 1999
  • ZrNbFeCu-xSn 합금을 진공 아크 용해법으로 제조하여 $360^{\circ}C$의 물, $400^{\circ}C$의 수증기 및 36$0^{\circ}C$의 70ppm LiOH 분위기에서 부식실험을 실시하였으며, 시편의 미세구조는 광학현미경, SEM 및 TEM으로 관찰하였다. 36$0^{\circ}C$에서 210일까지 부식 실험한 결과 대부분의 합금이 천이 전 영역에서의 부식거동을 보였다. $400^{\circ}C$ 경우, 초기에는$ 360^{\circ}C$에서의 부식거동과 비슷한 경향을 보였으나 80일 이후부터는 천이현상이 발생하여 부식속도가 급격히 증가하는 경향을 나타내었는데, Sn량이 많을수록 보다 빠른 시간에 천이현상이 발생했다. LiOH 용액에서는 전반적으로 $400^{\circ}C$에서 보다 더 늦은 시간에 천이현상이 발생했다. 석출물은 Zr(Fe,Cu)$_2$나Zr(Fe,Cu)$_3$로 추정되는 성분을 가지지만, Sn의 증가에 따라 석출물의 조성이나 크기는 거의 변화가 없는 것으로 관찰되었다.

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Effects of Alloying Elements on the Characteristics of Microstructure and High Temperature Oxidation of Cast Austenitic Stainless Steel (오스테나이트 스테인리스 주강의 미세 조직 및 고온 산화 특성에 미치는 합금원소의 영향)

  • Lee, In-Sung;Jeon, Soon-Hyeok;Kim, Soon-Tae;Lee, Jung-Suk;Ko, Young-Sang;Kim, Jong-Myoung
    • Journal of Korea Foundry Society
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    • v.30 no.5
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    • pp.179-186
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    • 2010
  • To elucidate the effects of alloying elements on the characteristics of microstructure and high temperature oxidation of cast austenitic stainless steel, a thermodynamic calculation, a cyclic oxidation test, a X-ray diffraction, a scanning electron microscopy-back scattered electron, a electron probe microanalysis were conducted. The thermodynamic calculation for the effect of vanadium (V) addition on the formation of various precipitates leads to a decrease of chromium (Cr)-rich $M_{23}C_6$ carbides due to the formation of M (C, N) carbo-nitrides containing V and / or niobium (Nb). The V added alloy increased the resistance to high temperature oxidation due to a decrease of Cr-depleted zone deteriorating the oxidation resistance and due to the V-enriched oxide layer formed in inner oxide layer blocking the outward transport of cations.

Synthesis, Structure and Magnetization Behaviors of MnBi/Fe3B/Nd2Fe14B Nanocomposite alloy

  • Yang, Y.;Wu, Q.;Hu, Y.C.;Zhang, P.Y.;Ge, H.L.
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.235-238
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    • 2016
  • Microstructure and magnetization behaviors of $MnBi/Fe_3B/Nd2_Fe_{14}B$ nanocomposite alloy have been investigated. It was found that the coercivity increased firstly and then decreased, and saturation magnetization decreased with the additon of MnBi alloy. The addition of 40 wt.% MnBi powder enhanced the coercivity from 192.8 kA/m to 311.2 kA/m. The ${\delta}M$ and D(H)-H plots suggested the occurrence of a stronger exchange-coupling occurring between the hard and soft magnetic phase for this sample. The dependence of coercivity with temperature was discussed in 40 wt.% $Mn_{55}Bi_{45}$/ 60 wt.% $Nd_{4.5}Fe_{76.5}Nb_{0.5}B_{18.5}$ alloy powder, and a positive temperature coefficient was founded from 298 K to 350 K.

Collective effect of hydrogen in argon and Mg as ambiance for the heat treatment on MgB2

  • Sinha, B.B.;Jang, S.H.;Chung, K.C.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.2
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    • pp.24-28
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    • 2014
  • Magnesium diboride superconductor is still of considerable interest because of its appealing characteristics towards application mainly at around 20 K. Unlike Nb-based superconductors, $MgB_2$ can be operated by cryogen-free cooler which provides a cost effective alternative at low field of around 2-5 T. To explore this operating field region considerable efforts are necessary to marginally improve the superconducting properties of $MgB_2$. Under this situation, even the heat treatment environment during the synthesis is considered as an important factor. The addition of $H_2$ gas in small amount with Ar as a mixed gas during annealing has an adverse effect on the superconducting properties of $MgB_2$. It is although interesting to find that the presence of Mg vapor along with hydrogen during heat treatment results in the appreciable improvement in the flux pinning and the overall response of the critical current density for the ex-situ $MgB_2$ samples.

Ferroelectric and Piezoelectric Properties of PMW-PNN-PZT Ceramics as a Function of BiFeO3 Substitution (BiFeO3 치환에 따른 PMW-PNN-PZT세라믹스의 강유전 및 압전 특성)

  • Ra, Cheol-Min;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.9
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    • pp.577-580
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    • 2015
  • In this paper, in order to develop the composition ceramics with the outstanding piezoelectric properties, $Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$ ceramics substituted with $BiFeO_3$ were prepared by the conventional solid-state reaction method. The addition of small amount of $Li_2CO_3$ and $CaCO_3$ as sintering aids decreased the sintering temperature of the ceramics. The effects of $BiFeO_3$ substitution on their piezoelectric and dielectric properties were investigated. when 0.015 mol $BiFeO_3$ was substituted, the optimal physical properties of $d_{33}=590pC/N$, $E_c=8.78kV/mm$ were obtained.

Piezoelectric Properties of NKN-LST Ceramics with ZnO and CuO Addition (ZnO와 CuO 첨가에 따른 NKN-LST 세라믹스의 압전 특성)

  • Lee, Seung-Hwan;Lee, Sung-Gap;Lee, Young-Hie
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.8
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    • pp.632-635
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    • 2011
  • Additions (ZnO, CuO) doped $0.98(Na_{0.5}K_{0.5})NbO_3-0.02Li(Sb_{0.17}Ta_{0.83})O_3$ (0.98NKN-0.02LST-x) lead free piezoelectric ceramics have been fabricated by ordinary sintering technique. The effects of additions doping on the dielectric, piezoelectric, and ferroelectric properties of the ceramics were mainly investigated. X-ray diffraction of the sample appeared orthorhombic phase. The specimen doped with additions exhibits enhanced electrical properties ($d_{33}$= 153 pC/N). These results indicate that the 0.98NKN-0.02LST-x ceramics is a promising candidate for lead-free piezoelectric ceramics for applications such as piezoelectric actuators, harmonic oscillator and so on.

A study on the piezoelectric characteristics of 0.05PAN-0.95PZT ceramics with additive (첨가제에 의한 0.05PAN-0.95PZT계 세라믹의 압전특성에 관한 연구)

  • 김현철;허석현;김진섭;임인호;배선기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.419-422
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    • 2000
  • This paper was to measure the structure, piezoelectric properties of 0.05Pb($A1_{0.5}$$Nb_{0.5}$)-0.95Pb($Zr_{0.52}$$Ti_{0.48}$)$O_3$ ceramics dopped with additive after creating the specimens with a general method. It is shown that X-ray diffraction pattern variation of lines (200) have tendency to move in simple peak by addition of additive. According to the increase of $Cr_2$$O_3$, tetragonality hardly have variation, according to the increase of $Fe_2$$O_3$, tetragonality decreased on the whole. According to dopping with $Cr_2$$O_3$ and $Fe_2$$O_3$, electromechanical factor(kp) largely increased, in case of sintering at $1200^{\circ}C$ kp was maximum value of 40.04[%] at $Cr_2$$O_3$ 0.3wt%, and maximum value of kp 42.9 [%] at $Fe_2$$O_3$, 0.9wt%. In case of sintering at 120$0^{\circ}C$, mechanical duality factor(Qm) was maximum value of Qm 268.8 at $Cr_2$$O_3$, 0.9 wt%.

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A Study on the High Temperature Gas Nitriding Heat Treatment of STS 347 and STS 310S Austenitic Stainless Steel (STS 347 및 STS 310S 오스테나이트계 스테인리스강의 고온 가스질화 열처리 특성 연구)

  • Yoo, Dae Kyoung;Kong, Jung Hyun;Lee, Hea Joeng;Sung, Jang Hyun;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.11
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    • pp.708-712
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    • 2008
  • The influence of high temperature gas nitriding (HTGN) in STS347 and STS310S steels was experimentally investigated. The HTGN was carried out at $1,050^{\circ}C{\sim}1,150^{\circ}C$ for 10 hrs in a gaseous atmosphere containing $1kg/mm^2$ of nitrogen. After HTGN, fine precipitates of $Cr_2N$ and NbN appeared in austenite on the surface of STS 347, while nitrogen pearlite, which was layeredof $Cr_2N$ and austenite alternatively, appeared in austenite on the surface of STS 310S. The surface hardness of HTGN-treated, STS 347 and STS 310S specimens was 250~360 Hv and 270~400 Hv, respectively, depending on the temperature of HTGN. The nitrogen content was analyzed 1.4 wt% and 1.6 wt% at the surface layer of STS 347 and STS 310S steels, respectively. In addition, an improvement in the corrosion resistance of HTGN treated specimens was observed.

Sentiment Analysis of COVID-19 Vaccination in Saudi Arabia

  • Sawsan Alowa;Lama Alzahrani;Noura Alhakbani;Hend Alrasheed
    • International Journal of Computer Science & Network Security
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    • v.23 no.2
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    • pp.13-30
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    • 2023
  • Since the COVID-19 vaccine became available, people have been sharing their opinions on social media about getting vaccinated, causing discussions of the vaccine to trend on Twitter alongside certain events, making the website a rich data source. This paper explores people's perceptions regarding the COVID-19 vaccine during certain events and how these events influenced public opinion about the vaccine. The data consisted of tweets sent during seven important events that were gathered within 14 days of the first announcement of each event. These data represent people's reactions to these events without including irrelevant tweets. The study targeted tweets sent in Arabic from users located in Saudi Arabia. The data were classified as positive, negative, or neutral in tone. Four classifiers were used-support vector machine (SVM), naïve Bayes (NB), logistic regression (LOGR), and random forest (RF)-in addition to a deep learning model using BiLSTM. The results showed that the SVM achieved the highest accuracy, at 91%. Overall perceptions about the COVID-19 vaccine were 54% negative, 36% neutral, and 10% positive.