• 제목/요약/키워드: Nb addition

검색결과 491건 처리시간 0.027초

$MnO_2$첨가에 따른 무연 BNKT계의 압전특성 (Piezoelectric properties of Pb-free BNKT ceramics with $MnO_2$ addition)

  • 이미영;류성림;류주현;이수호;정영호;정광현;홍재일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.744-747
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    • 2004
  • [ $0.96[Bio_{0.5}(Na_{0.84}K_{0.16})_{0.5}TiO_3]+0.04SrTiO_3+0.3wt%Nb_2O_5+0.2wt%La_2O_3+xwt%MnO_2$ ], were studied in order to develope the superior dielectric and piezoelectric properties of Lead-free Piezoelectric ceramics. With increasing amount of $MnO_2$ addition, density showed the maximum value of $5.79[gcm^3$] at 0.1wt% $MnO_2$ addition, and electromechanical coupling factor($k_p$) and dielectric constant decreased, and mechanical quality factor($Q_m$) increased and showed the maximum value of 161 at 0.3wt% $MnO_2$ addition.

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ZnO첨가에 따른 무연 BNKT계 세라믹스의 압전특성 (Piezoelectric properties of Pb-free BNKT ceramics with ZnO addition)

  • 류성림;김주현;이미영;류주현;서상현;정광현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.193-195
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    • 2005
  • [ $0.96[Bi_{0.5}(Na_{0.84}K_{0.16})_{0.5}TiO_3]+0.04SrTiO_3+0.3wt%Nb_2O_5+0.2wt%La_2O_3+xwt%ZnO$ ], were studied in order to develope the superior piezoelectric properties of Lead-free piezoelectric ceramics. With increasing amount of ZnO addition, density showed the maximum value of 5.79(g/$cm^3$) at 0wt% ZnO addition, and electromechanical coupling factor($k_p$) and dielectric constant decreased, and mechanical quality factor($Q_m$) increased and showed the maximum value of 280 at 0.4wt% ZnO addition.

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Effect of Mn on Dielectric and Piezoelectric Properties of 71PMN-29PT [71Pb(Mg1/3Nb2/3)O3-29PbTiO3] Single Crystals and Polycrystalline Ceramics

  • Oh, Hyun-Taek;Joo, Hyun-Jae;Kim, Moon-Chan;Lee, Ho-Yong
    • 한국세라믹학회지
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    • 제55권2호
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    • pp.166-173
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    • 2018
  • In order to investigate the effect of Mn on the dielectric and piezoelectric properties of PMN-PT [$Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$], four different types of 71PMN-29PT samples were prepared using the solid-state single crystal growth (SSCG) method: (1) Undoped single crystals, (2) undoped polycrystalline ceramics, (3) Mn-doped single crystals, and (4) Mn-doped polycrystalline ceramics. In the case of single crystals, the addition of 0.5 mol% Mn to PMN-PT decreased the dielectric constant ($K_3{^T}$), piezoelectric charge constant ($d_{33}$), and dielectric loss (tan ${\delta}$) by about 50%, but increased the coercive electric field ($E_C$) by 50% and the electromechanical quality factor ($Q_m$) by 500%, respectively. The addition of Mn to PMN-PT induced an internal bias electric field ($E_I$) and thus specimens changed from piezoelectrically soft-type to piezoelectrically hard-type. This Mn effect was more significant in single crystals than in ceramics. These results demonstrate that Mn-doped 71PMN-29PT single crystals, because they are piezoelectrically hard and simultaneously have high piezoelectric and electromechanical properties, have great potential for application in fields of SONAR transducers, high intensity focused ultrasound (HIFU), and ultrasonic motors.

$(1-x)(Sr_a.Pb_b.Ca_c)TiO_3-xB_i2O_3.TiO_2$계에서의 $Bi_2O_3.3TiO_2$$MnO_2$첨가에 따른 유전특성에 관한 연구 (The Dielectrical Properties of $(1-x)(Sr_a.Pb_b.Ca_c)TiO_3-xB_i2O_3.TiO_2$ system affected by $Bi_2O_3.3TiO_2$ amounts and $MnO_2$)

  • 박상도;이응상
    • 한국세라믹학회지
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    • 제34권2호
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    • pp.123-130
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    • 1997
  • 본 연구에서는 유전상수가 크고, 유전체 손실이 적으며, 사용온도 범위에서 정전용량 변화율(TCC : tem-perature coefficient of capacitance)이 작고, 고압에 견딜 수 있는 재료를 개발하기 위하여 중고압용 capacitance의 기본재료로써 (Sr.Pb.Ca)TiO3-xBi2O3.3TiO2 계에서 Bi2O3.3TiO2의 mol.%를 5, 6, 7, 8, 9 mol.%로 변화시켰으며, 그 결과 고용한계 함량이 6mol.%이며, 6mol.%이상에서는 침상구조의 증가에 기인하여 유전율이 다시 감소하는 경향을 보였다. dopant로써 SiO2, Nb2O3, MnO2를 선정하여 첨가한 결과, MnO2를 첨가한 것이 유전성질이 가장 우수하였으며, MnO2의 함량이 0, 0.15, 0.3, 0.45 wt.% 증가함에 따라서 유전율의 감소와 동시에, TOC특성의 급격한 향상을 가져왔다.

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Role of RIN4 in Regulating PAMP-Triggered Immunity and Effector-Triggered Immunity: Current Status and Future Perspectives

  • Ray, Sujit Kumar;Macoy, Donah Mary;Kim, Woe-Yeon;Lee, Sang Yeol;Kim, Min Gab
    • Molecules and Cells
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    • 제42권7호
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    • pp.503-511
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    • 2019
  • As sessile organisms, plants have developed sophisticated system to defend themselves against microbial attack. Since plants do not have specialized immune cells, all plant cells appear to have the innate ability to recognize pathogens and turn on an appropriate defense response. The plant innate immune system has two major branches: PAMPs (pathogen associated molecular patterns)-triggered immunity (PTI) and effector-triggered immunity (ETI). The ability to discriminate between self and non-self is a fundamental feature of living organisms, and it is a prerequisite for the activation of plant defenses specific to microbial infection. Arabidopsis cells express receptors that detect extracellular molecules or structures of the microbes, which are called collectively PAMPs and activate PTI. However, nucleotidebinding site leucine-rich repeats (NB-LRR) proteins mediated ETI is induced by direct or indirect recognition of effector molecules encoded by avr genes. In Arabidopsis, plasmamembrane localized multifunctional protein RIN4 (RPM1-interacting protein 4) plays important role in both PTI and ETI. Previous studies have suggested that RIN4 functions as a negative regulator of PTI. In addition, many different bacterial effector proteins modify RIN4 to destabilize plant immunity and several NB-LRR proteins, including RPM1 (resistance to Pseudomonas syringae pv. maculicola 1), RPS2 (resistance to P. syringae 2) guard RIN4. This review summarizes the current studies that have described signaling mechanism of RIN4 function, modification of RIN4 by bacterial effectors and different interacting partner of RIN4 in defense related pathway. In addition, the emerging role of the RIN4 in plant physiology and intercellular signaling as it presents in exosomes will be discussed.

Co와 Fe+Co혼합미분의 소결치밀화 특성 (Characteristics of Sintering Densification of Co and Fe+Co Fine Powders)

  • 임태환
    • 한국분말재료학회지
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    • 제3권2호
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    • pp.97-103
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    • 1996
  • The densification of the compacts of pure Co, Fe+50%.Co and Fe+25% Co sintered under H$_2$ gas or in vacuum was investigated. The effects of AL, Nb, Ti, and V additions on the densification were also studied. The sintered compact of Co was fully-dense when the density of the compact was lower than $Dg^c$. However, above $Dg^{c}$, it was never fully-dense regardless of sintering atmosphere, temperature, and time. The densification of sintered compacts of Fe-50% Co and Fe-25% Co were always incomplete. While the addition of AL made all compacts fully-dense, the addition of Ti was effective for the compacts of Co and Fe-25% Co. V was effective only for the Fe-25% Co. These results tell us that the particle size of Co powder, the amount of Fe, and the amount of additives forming stable oxides play on important role for the complete densification. Therefore it is desirable to reduce or eliminate the equilibrium pressure of H$_{2}$O or CO in isolated pores to obtain a fully-dense sintered compact.

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$MnO_2$가 첨가된 PZT-PSN압전세라믹의 압전 및 전기적특성 분석 (Ihe Electrical and Piezoelectric Characteristics of PZT-PSN ceramics added $MnO_2$)

  • 김성곤;김철수;박정호;이상렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.161-164
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    • 2001
  • In this paper, we investigated the dielectric and piezoelectric properties of Pb(Sb, Nb)O$_3$-Pb(Zr, Ti)O$_3$ ceramic(PSN) for piezoelectric transformer and actuator etc. Effect of MnO$_2$ addition on the PSN ceramic was investigated. Anisotropic properties of electromechanical coupling factor and piezoelectric properties proved to be varied with amount of MnO$_2$ impurity and sintering temperature. The electromechanical coupling factor k$_{p}$ of 0.38 and the mechanical quality factor Q$_{m}$ of 1944 were obtained from the specimen with 0.4 wt% MnO$_2$ sintered at 115$0^{\circ}C$ addition. Experimental results indicated that the PSN ceramic with MnO$_2$ impurity can be effectively used for piezoelectric transformer and actuator.tor.

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소결조제 첨가에 따른 PMW-PMN-PZT 세라믹의 저온소결 특성 (Low temperature sintering properties of the $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Zi,Ti)O_3$ ceramics with the addition of sintering aids)

  • 이현석;류주현;이창배;정영호;백동수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.350-351
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    • 2005
  • In this study, in order to develop the low temperature sintering multilayer piezoelectric transformer, PMW-PMN-PZT system ceramics were manufactured with the addition of sintering aids, and their dielectric and piezoelectric characteristics were investigated. At the composition ceramics sintered at $900^{\circ}C$, dielectric constant(${\varepsilon}r$), electromechanical coupling factor(kp) and mechanical quality factor(Qm) showed the optimal value of 1043, 0.44 and 793, respectively, for multilayer piezoelectric transformer application.

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BCTZ첨가가 NKLN-AS계 압전세라믹스의 미세구조와 압전/유전특성 및 상전이현상에 미치는 효과 (BCTZ Addition on the Microstructure, Piezoelectric/Dielectric Properties and Phase Transition of NKLN-AS Piezoelectric Ceramics)

  • 이웅재;어순철;이영근;윤만순
    • 한국재료학회지
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    • 제22권1호
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    • pp.35-41
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    • 2012
  • Presently, the most promising family of lead-free piezoelectric ceramics is based on $K_{0.5}Na_{0.5}NbO_3$(KNN). Lithium, silver and antimony co-doped KNN ceramics show high piezoelectric properties at room temperature, but often suffer from abnormal grain growth. In the present work, the $(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$ component, which has relaxor ferroelectric characteristics, was doped to suppress the abnormal grain growth. To investigate this effect, Lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3-x(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$[KNLN-AS-xBCTZ] piezoelectric ceramics were synthesized by ball mill and nanosized-milling processes in lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3$ in order to suppress the abnormal grain growth. The nanosized milling process of calcined powders enhanced the sintering density. The phase structure, microstructure, and ferroelectric and piezoelectric properties of the KNLN-AS ceramics were systematically investigated. XRD patterns for the doped and undoped samples showed perovskite phase while tetragonality was increased with increasing BCZT content, which increase was closely related to the decrease of TO-T. Dense and uniform microstructures were observed for all of the doped BCZT ceramics. After the addition of BCTZ, the tetragonal-cubic and orthorhombic-tetragonal phase transitions shifted to lower temperatures compared to those for the pure KNNL-AS. A coexistence of the orthorhombic and tetragonal phases was hence formed in the ceramics with x = 0.02 mol at room temperature, leading to a significant enhancement of the piezoelectric properties. For the composition with x = 0.02 mol, the piezoelectric properties showed optimum values of: $d_{33}$ = 185 pC/N, $k_P$ = 41%, $T_C=325^{\circ}C$, $T_{O-T}=-4^{\circ}C$.

방사성 폐기물 내 $^{59/63}Ni$ 정량을 위한 분리 (Separation for the Determination of $^{59/63}Ni$ in Radioactive Wastes)

  • 이창헌;정기철;최광순;지광용;김원호
    • 방사성폐기물학회지
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    • 제3권4호
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    • pp.309-317
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    • 2005
  • 방사성 폐기물 핵종 재고량 평가에 필요한 핵종분석을 위하여 다양한 매질의 방사성 폐기물 시료로부터 $^{99}Tc,\;^{94}Ng,\;^{55}Fe,\;^{90}Sr$$^{59/63}Ni$의 분리에 관한 연구가 수행되고 있다. Ni은 음이온교환 수지와 Sr-Spec 추출 크로마토그래피 수지로 Re($^{99}Tc$의 대용물), Nb, Fe 및 Sr을 차례로 분리하는 과정에서 Ca, Mg, Al, Cr, Ti, Mn, Ce, Na, K 및 Cu와 함께 회수되었다. 본 연구에서는 Ni의 선택적 분리기술을 확립하기 위하여 Ni-Spec 추출 크로마토그래피 및 양이온교환수지법으로 이들의 분리거동을 비교하였다. 또한 Ni의 정제와 기체비례계수법으로 방사능을 측정하기에 적합한 계측시료 준비를 위하여 ammonium $citrate/ethanol-H_2O$ 및 tartaric $acid/acetone-H_2O$에서 dimethylglyoxime(DMG)에 의한 Ni의 침전거동을 조사하였다 원자력발전소로부터 채취한 폐이온교환수지 시료 용해용액의 화학조성을 모사하여 만든 모의 폐이온교환수지 용액을 사용하여 Re, Nb, Fe 및 Sr 분리과정을 거쳐 최종적으로 분리한 Ni의 회수율은 $92.1\%\;(RSD:\;0.9\%)$이었다. 또한 tartaric $acid/acetone-H_2O$에서 DMG에 의한 Ni의 회수율은 $85.6\%\;(RSD:\;1.9\%)$이었다.

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