• 제목/요약/키워드: Nb addition

검색결과 491건 처리시간 0.024초

합성방법과 소결 온도가 PZNN-PZT 압전 세라믹스 소재특성에 미치는 영향 (Effects of the Mixing Method and Sintering Temperature on the Characteristics of PZNN-PZT Piezoelectric Ceramic Materials)

  • 김소원;정용정;이희철
    • 한국분말재료학회지
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    • 제25권6호
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    • pp.487-493
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    • 2018
  • The impact of different mixing methods and sintering temperatures on the microstructure and piezoelectric properties of PZNN-PZT ceramics is investigated. To improve the sinterability and piezoelectric properties of these ceramics, the composition of $0.13Pb((Zn_{0.8}Ni_{0.2})_{1/3}Nb_{2/3})O_3-0.87Pb(Zr_{0.5}Ti_{0.5})O_3$ (PZNN-PZT) containing a Pb-based relaxor component is selected. Two methods are used to create the powder for the PZNN-PZT ceramics. The first involves blending all source powders at once, followed by calcination. The second involves the preferential creation of columbite as a precursor, by reacting NiO with $Nb_2O_5$ powder. Subsequently, PZNN-PZT powder can be prepared by mixing the columbite powder, PbO, and other components, followed by an additional calcination step. All the PZNN-PZT powder samples in this study show a nearly-pure perovskite phase. High-density PZNN-PZT ceramics can be fabricated using powders prepared by a two-step calcination process, with the addition of 0.3 wt% MnO2 at even relatively low sintering temperatures from $800^{\circ}C$ to $1000^{\circ}C$. The grain size of the ceramics at sintering temperatures above $900^{\circ}C$ is increased to approximately $3{\mu}m$. The optimized PZNN-PZT piezoelectric ceramics show a piezoelectric constant ($d_{33}$) of 360 pC/N, an electromechanical coupling factor ($k_p$) of 0.61, and a quality factor ($Q_m$) of 275.

딥러닝 기반 음향 신호 대역 확장 시스템 (Deep Learning based Raw Audio Signal Bandwidth Extension System)

  • 김윤수;석종원
    • 전기전자학회논문지
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    • 제24권4호
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    • pp.1122-1128
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    • 2020
  • 대역 확장(Bandwidth Extension)이란 채널 용량 부족 혹은 이동통신 기기에 탑재된 코덱의 특성으로 인해 부호화 및 복호화 과정에서 대역 제한(band limited)되거나 손상된 협대역 신호(NB, Narrow Band)를 복원, 확장하여 광대역 신호(WB, Wide Band)로 전환 시켜주는 것을 의미한다. 대역 확장 연구는 주로 음성 신호 위주로 대역 복제(SBR, Spectral Band Replication), IGF(Intelligent Gap Filling)과 같이 고대역을 주파수 영역으로 변환하여 복잡한 특징 추출 과정을 거쳐 이를 바탕으로 사라지거나 손상된 고대역을 복원한다. 본 논문에서는 딥러닝 모델 중 오토인코더(Autoencoder)를 바탕으로 1차원 합성곱 신경망(CNN, Convolutional Neural Network)들의 잔차 연결을 활용하여 복잡한 사전 전처리 과정 없이 일정한 길이의 시간 영역 신호를 입력시켜 대역 확장 시킨 음향 신호를 출력하는 모델을 제안한다. 또한 음성 영역에 제한되지 않는 음악을 포함한 여러 종류의 음원을 포함하는 데이터셋에 훈련시켜도 손상된 고대역을 복원할 수 있음을 확인하였다.

자연기반해법 적용에 따른 강원도 양구군 해안면의 비점오염 저감 효과 추정 (Estimation of non-point pollution reduction effect of Haean Catchment by application of Nature-based Solutions)

  • 이지우;박찬
    • 한국환경복원기술학회지
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    • 제25권3호
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    • pp.47-62
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    • 2022
  • The Ministry of Environment has been working to reduce the impact on biodiversity, ecosystems, and social costs caused by soil runoff from highland Agricultural fields by setting up non-point pollution source management districts. To reduce soil loss, runoff path reduction technology has been applied, but it has been less cost effective. In addition, non-point pollution sources cause environmental conflicts in downstream areas, and recently highland Agricultural fields are becoming vulnerable to climate change. The Ministry of Environment is promoting the optimal management plan in earnest to convert arable land into forests and grasslands, but since non-point pollution is not a simple environmental problem, it is necessary to approach it from the aspect of NbS(Nature-Based Solution). In this study, a scenario for applying the nature-based solution was established for three subwatersheds west of Haean-myeon, Yanggu-gun, Gangwon-do. The soil loss distribution was spatialized through GeoWEPP and the amount of soil loss was compared for the non-point pollution reduction effect of mixed forests and grasslands. When cultivated land with a slope of 20% or more and ginseng fields were restored to perennial grasslands and mixed forests, non-point pollution reduction effects of about 32% and 29.000 tons compared to the current land use were shown. Also, it was confirmed that mixed forest rather than perennial grassland is an effective nature-based solution to reduce non-point pollution.

방전플라즈마 소결 공정 적용 전이금속 카바이드 서멧의 소결 및 기계적 특성 (Sintering Behavior and Mechanical Property of Transition Metal Carbide-Based Cermets by Spark Plasma Sintering)

  • 이정한;박현국;홍성길
    • 한국재료학회지
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    • 제32권1호
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    • pp.44-50
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    • 2022
  • Transition metal carbides (TMCs) are used to process difficult-to-cut materials due to the trend of requiring superior wear and corrosion properties compared to those of cemented carbides used in the cutting industry. In this study, TMC (TiC, TaC, Mo2C, and NbC)-based cermets were consolidated by spark plasma sintering at 1,300 ℃ (60 ℃min) with a pressure of 60 MPa with Co addition. The sintering behavior of TMCs depended exponentially on the function of the sintering exponent. The Mo2C-6Co cermet was fully densified, with a relative density of 100.0 %. The Co-binder penetrated the hard phase (carbides) by dissolving and re-precipitating, which completely densified the material. The mechanical properties of the TMCs were determined according to their grain size and elastic modulus: TiC-6Co showed the highest hardness of 1,872.9 MPa, while NbC-6Co showed the highest fracture toughness of 10.6 MPa*m1/2. The strengthened grain boundaries due to high interfacial energy could cause a high elastic modules; therefore, TiC-6Co showed a value of 452 ± 12 GPa.

$WO_3$첨가하여 PZT-PSN압전세라믹의 압전 및 전기적특성 연구 (The Piezoelectric and Electrical Characteristics of PZT-PSN Ceramics Added $WO_3$)

  • 김성곤;김철수;박정호;이상렬
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.134-136
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    • 2001
  • In this paper, we investigated the electrical and piezoelectric characteristics of $Pb(Sb,Nb)O_3-Pb(Zr,Ti)O_3$ for piezoelectric transformer and actuator etc. Effect of $WO_3$ addition($0\;wt%{\sim}0.6\;wt%$) on the PSN-PZT ceramic was investigated. Anisotropic properties of electromechanical coupling factor and piezoelectric properties were proved to be varied with amount of $WO_3$ impurity and sintering temperature($1100{\sim}1300^{\circ}C$). The electromechanical coupling factor $k_p$ of 0.41 and the mechanical quality factor am of 1243 were obtained from the specimen with 0.6 wt% $WO_3$ addition sintered at $1100^{\circ}C$ Experimental results indicated that the PZT-PSN ceramics with $WO_3$ impurity can be effectively used for piezoelectric transformer and actuator. etc.

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$\textrm{SrTiO}^3$ 와 과잉 MgO가 첨가된 $\textrm{Pb(Mg_{1/3}Nb_{2/3})O}_3$ - $\textrm{PbTiO}^3$ 계 세라믹스의 유전 및 변위 특성 (Dielectric and Strain Properties of PMN-PT Ceramics Doped with $\textrm{SrTiO}^3$ and excess MgO)

  • 이상훈
    • 전자공학회논문지T
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    • 제36T권3호
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    • pp.7-12
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    • 1999
  • 본 논문은 (1-x-y)PMN-yPT-xST세라믹스의 유전 및 변위특성을 ST의 양에 따라 조사하였다. ST의 성분은 1∼ 6㏖%이내로 변화시켰고 과잉 MgO에 따른 조성변화에 따라 결과를 조사하였다. ST의 성분의 증가에 따라 유전상수는 5㏖%인 조성에서 최대값을 나타내었다. 큐리온도는 ST의 성분이 증가함에 따라 선형적으로 감소하였다. 항전계와 잔류분극은 l㏖%인 조성에서 최대값을 나타내었다. 과잉 MgO의 효과에 따라 유전상수는 0.8PMN-0.12PT-0.04ST조성에서 MgO를 3㏖%까지 과잉 첨가함에 따라 증가하였으나 변위특성은 감소함을 나타내었다.

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$La_2O_3$의 첨가가 PZN-BT-PT 세라믹스의 구조적, 전기적 특성에 미치는 영향 (An Effect on the Structural, Electrical Characteristis of PZN-BT-PT Ceramics according to the Variations of $La_2O_3$ Additon Amount)

  • 박성환;윤현상;백동수;이두희;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 추계학술대회 논문집
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    • pp.42-45
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    • 1992
  • In this study, the structural, dielectric and electrical properties of $0.85Pb(Zn_{1/3}Nb_{2/3})O_3-0.1BaTiO_3-0.05PbTiO_3$ ceramics were investigated with respect to the variations of $La_2O_3$ addition amount. The specimen with 0.2 [wt%] $La_2O_3$ addition amount, which has the coupling constants with the value of $k_p$=44.8[%]. $k_{31}$=25.4[%] and the piezoelectric constant with $d_{31}=100{\times}10^{-12}$[C/N] respectively, exhibits the relatively good values in the applications of electrostriction actuators.

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HEAT-UP AND COOL-DOWN TEMPERATURE-DEPENDENT HYDRIDE REORIENTATION BEHAVIORS IN ZIRCONIUM ALLOY CLADDING TUBES

  • Won, Ju-Jin;Kim, Myeong-Su;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
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    • 제46권5호
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    • pp.681-688
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    • 2014
  • Hydride reorientation behaviors of PWR cladding tubes under typical interim dry storage conditions were investigated with the use of as-received 250 and 485ppm hydrogen-charged Zr-Nb alloy cladding tubes. In order to evaluate the effect of typical cool-down processes on the radial hydride precipitation, two terminal heat-up temperatures of 300 and $400^{\circ}C$, as well as two terminal cool-down temperatures of 200 and $300^{\circ}C$, were considered. In addition, two cooling rates of 2.5 and $8.0^{\circ}C/min$ during the cool-down processes were taken into account along with zero stress or a tensile hoop stress of 150MPa. It was found that the 250ppm hydrogen-charged specimen experiencing the higher terminal heat-up temperature and the lower terminal cool-down temperature generated the highest number of radial hydrides during the cool-down process under 150MPa hoop tensile stress, which may be explained by terminal solid hydrogen solubilities for precipitation, and dissolution and remaining circumferential hydrides at the terminal heat-up temperatures. In addition, the slower cool-down rate generates the larger number of radial hydrides due to a cooling rate-dependent, longer residence time at a relatively high temperature that can accelerate the radial hydride nucleation and growth.

Effect of $Li_2O$ Addition on Piezoelectric Properties of NKN-5LT Ceramics

  • Kim, Min-Soo;Lee, Dae-Su;Park, Eon-Cheol;Jeong, Soon-Jong;Kim, In-Sung;Song, Jae-Sung
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.694-695
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    • 2006
  • As a candidate for lead-free piezoelectric materials, dense $95(Na_{0.5}K_{0.5})NbO_3-5LiTaO_3$ (NKN-5LT) ceramics were developed by conventional sintering process. Sintering temperature was lowered by adding $Li_2O$ as a sintering aid. The electrical properties of NKN-5LT ceramics were investigated as a function of $Li_2O$ concentration. At the addition of 1 mol% $Li_2O$, electromechanical coupling factor $(k_P)$ and piezoelectric coefficient $(d_{33})$ of NKN-5LT ceramics were found to reach the highest values of 0.37 and 250 pC/N, respectively.

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발아약콩가루를 첨가한 생면의 제조 및 특성연구 (Preparation and Characterization of Wet Noodle Containing Germinated Small Black Bean Flour)

  • 한성미;한정아
    • 한국식품과학회지
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    • 제43권5호
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    • pp.597-602
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    • 2011
  • 약콩을 재료로 가장 높은 이소플라본 함량을 갖는 발아조건을 찾고(본 연구에서는 48시간), 발아시킨 약콩을 열처리 하지 않은 군과 20분 끓이기 처리를 한 군으로 나누어 밀가루양의 각 15%, 20%를 대체하여 면을 제조하고 그 특성을 평가하였다. 대조군은 수분흡수량이나 부피증가율 및 조리 후 당용출이 가장 높게 측정되었으나 발아콩가루 첨가량이 많을수록 수치가 낮아지는 결과를 보았다. 특히 끓인 발아콩가루 15% 첨가군은 당용출이 가장 낮게 측정되었다. 조직감 특성에 있어서, 대조군은 가장 높은 견고성을 나타내었으며 조리 후 1시간 까지 크게 증가함을 보였다. 발아콩 분말의 함량이 증가할수록 경도가 감소하는 경향을 보였으며, 끓인 콩의 경우 동일비율의 열처리 하지 않은 콩에 비해 상대적으로 견고성의 감소폭이 크게 나타났다. 특히 열처리한 발아콩가루를 15% 수준으로 첨가했을 때 경도는 대조군보다 낮았으나, 탄력성은 대조군보다 높게, 점착성은 대조군보다 낮게 측정되어 바람직한 제면의 특성을 보였다. 관능검사 결과 15% 발아콩가루 첨가면은 외관상에서 높은 점수를 얻었으나, 20% 첨가 면은 색이 짙고 열처리하지 않은 콩가루 첨가면은 콩비린내가 감지되었기 때문에 appearance 와 flavor면에서 낮게 측정되었다. 건강에 관한 관심이 높아지면서 밀가루만으로 만든 국수보다는 발아콩가루를 넣은 면이 외관, 조직감을 비롯하여 전체적인 선호도에서도 높은 점수를 얻었으며, 특히 열처리한 콩가루 15% 첨가면이 가장 높은 선호도를 보였다.