• Title/Summary/Keyword: Nature gas

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Transition temperatures and upper critical fields of NbN thin films fabricated at room temperature

  • Hwang, T.J.;Kim, D.H.
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.3
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    • pp.9-12
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    • 2015
  • NbN thin films were deposited on thermally oxidized Si substrate at room temperature by using reactive magnetron sputtering in an $Ar-N_2$ gas mixture. Total sputtering gas pressure was fixed while varying $N_2$ flow rate from 1.4 sccm to 2.9 sccm. X-ray diffraction pattern analysis revealed dominant NbN(200) orientation in the low $N_2$ flow rate but emerging of (111) orientation with diminishing (200) orientation at higher flow rate. The dependences of the superconducting properties on the $N_2$ gas flow rate were investigated. All the NbN thin films showed a small negative temperature coefficient of resistance with resistivity ratio between 300 K and 20 K in the range from 0.98 to 0.89 as the $N_2$ flow rate is increased. Transition temperature showed non-monotonic dependence on $N_2$ flow rate reaching as high as 11.12 K determined by the mid-point temperature of the transition with transition width of 0.3 K. On the other hand, the upper critical field showed roughly linear increase with $N_2$ flow rate up to 2.7 sccm. The highest upper critical field extrapolated to 0 K was 17.4 T with corresponding coherence length of 4.3 nm. Our results are discussed with the granular nature of NbN thin films.

Gas and Solute Compositions of Fluid Inclusions in Quartz from Some Base-metal ore Deposits, South Korea (남한의 주용 금속광상산 석영내의 유체포유물의 가스성분과 용존성분의 화학조성)

  • Kim, Gyu-Han;Jeong, Hae-Ran
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.421-434
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    • 1999
  • Gas and chemical compositions of fluid inclusions in quartz some of Au-Ag, Pb-Zn-Cu and W-Mo mineral deposits in South Kores were analyzed to interpret the sources of ore fluid and the depositional condition of ore minerals in base-metal ore deposits. Fluid inclusions in quartz from the gold and silver mines are characterized by $CO_2$ rich fluids which have a wide range in $CH_4 \;and\; CO_2$ contents ($CH_4/CO_2$=0.001-0.225). The $CO_2$ rich but $CH_4$-poor nature of the fluid reflects the high fo2 condition during the mineral precipitation. The C2H6 is detected in hydrothermal quartz vines in metasedimentary rocks from the Jeonjoo-il, Youngbokari and Taechang mines. The $CH_4 /CO_2$ rations in W-Mo bearing quartz veins range from 0.005 to 0.214, which is similar with those in Au-Ag mines. However, skarn formation stage. Fluid inclusions, A relatively good correlation between Na and Cl contentrations reflects varible salinity in the fluid inclusion, it is suggested that the chemistry of promary magmatic hydrothermal fluids has changed during post-magmatic alteration and/or wall rock alteration processes. The content of gas compositions also depends on the kinds of country rocks, supporting above conclusion.

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Characterization of the Effect of the Inlet Operating Conditions on the Performance of Lean Premixed Gas Turbine Combustors

  • Samperio, J.L.;Santavicca, D.A.;Lee, J.G.
    • Journal of the Korean Society of Combustion
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    • v.9 no.3
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    • pp.10-18
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    • 2004
  • An experimental study of the effect of operating conditions on the behavior of a lean premixed laboratory combustor operating on natural gas has been conducted. Measurements were made characterizing the pressure fluctuations in the combustor and the flame structure over a range of inlet temperatures, inlet velocities and equivalence ratios. In addition the fuel distribution at the inlet to the combustor was varied such that it was an independent parameter in the experiment. Inlet temperature, inlet velocity and equivalence ratio were all found to have an effect on the stability characteristics of the combustor. The nature of this effect, however, depended on the fuel distribution. For example, with one fuel distribution the combustor would become unstable when the temperature was increased, whereas with a different fuel distribution the combustor would become unstable when the temperature was decreased. Similarly, the operating conditions had an effect on the flame structure. For example the intensity-weighted center of mass of the flame was found to move closer to the center body as either the temperature or equivalence ratio increased. It was interesting and somewhat surprising to note, however, that as the location of the center of mass changed with operating conditions it did so by moving along a line of constant flame angle.

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Physio-Ecological Characteristics of Roadside Tree by Difference under Zoning of Urban Districts in Cheong-ju City -Focused on the Ginkgo biloba and Platanus orientalis- (청주시 용도지역별 가로수의 생리.생태학적 특성에 관한 연구 -Ginkgo biloba와 Platanus orientalis를 중심으로-)

  • In, Hyoung-Min;Ju, Jin-Hee;Yoon, Young-Han
    • Journal of Environmental Science International
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    • v.19 no.2
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    • pp.229-236
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    • 2010
  • As air pollution has emerged as one of the most pressing urban environmental concerns, many studies have investigated the influence of air pollutants(ex: $O^3$, $NO^2$, $SO^2$, Acid rain, etc.) on roadside trees and urban grove. In Korea, population density started to increase since the industrialization. Since dense population aggravates our living conditions, it's very important for us to preserve and keep a lively and refreshing nature in order to live with green nature in harmony under the current artificial environment-dominating world. In metropolitan cities, the production of pollutants increases in proportion to population growth. The vehicle exhaust gas and air pollutants from cooling and heating systems have been the major causes of acid rain. Furthermore, tire particles which are naturally produced by tire wearing on roads and other toxic substances in exhaust gas have caused a problem in human health directly and indirectly. In fact, a lot of studies have analyzed air pollution, roadside trees and plants in Korea. However, they are mostly limited to covering the influence of air pollution on the growth of plants. No paper has clearly explained why air pollution-resistant or-vulnerable species has shown different reactions yet. Even though a lot of urban roadside trees have died or stopped to grow from time to time, this kind of problem has not been properly examined. This paper is aimed to comparatively analyze physio-ecological characteristic such as photosynthesis, chlorophyll contents, soil volume water figure out their relationship with environmental factors against the expanding roadside trees in Cheong-ju, and provide basic data for management of roadside trees and elaboration of urban environment preservation policies.

A Study on Forecasting Risk of Gas Accident using Weather Data (기상 데이터를 활용한 가스사고위험 예보에 관한 연구)

  • Oh, Jeong Seok
    • Journal of the Korean Institute of Gas
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    • v.22 no.5
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    • pp.107-113
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    • 2018
  • While accident data are used to show alertness to accidents or to review similar cases, the analysis of nature of accident data its association with surrounding environment is very insufficient. Therefore, it is very necessary to demonstrate the possibility of an accident for a particular region by developing analysis techniques with the related accident data. The purpose of this study is to develop an analysis model and implement a system that produces regional accident probability based on historical weather information data and accident and reporting data. In other words, the system is designed and developed to create models by k-NN and decision tree algorithms with optional user-environment variables based on the probability between weather and accidents about many particular region of Korea. In the future, the models developed in this study are intended to be used to analyze and calculate the risk of a more narrow area.

An Examination on the Dispersion Characteristics of Boil-off Gas in Vent Mast Exit of Membrane Type LNG Carriers (멤브레인형 LNG선박 화물탱크 벤트 마스트 출구에서의 BOG 확산 특성에 관한 연구)

  • Kang, Ho-Keun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.2
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    • pp.225-231
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    • 2013
  • Liquefied gas carriers generally transport cargoes of flammable or toxic nature. Since these cargoes may cause an explosion, fire or human casualty, the accommodation spaces, service spaces and control stations of liquefied gas carriers should be so located as to avoid ingress of gas. For this reason, the paragraph 8.2.9 of IGC Code in IMO requires that the height of vent exits should be not less than B/3 or 6 m whichever is greater, above the weather deck and 6 m above the working area and the fore and aft gangway to prevent any concentration of cargo vapor or gas at such spaces. Besides as known, the LNG market has been growing continually, which has led to LNG carriers becoming larger in size. Under this trend, the height of a vent will have to be raised considerably since the height of a vent pipe is generally decided by a breadth of a corresponding vessel. Accordingly, we have initiated an examination to find an alternative method which can be used to determine the safe height of vent masts, instead of the current rule requirement. This paper describes the dispersion characteristics of boil-off gas spouted from a vent mast under cargo tank cool-down conditions in the membrane type LNG carriers.

Studies on the Biochemical Nature of the Protein Constituents of Panax Ginseng Root (인삼(人蔘) 단백성분의 생화학적성질(生化學的性質)에 관한 연구)

  • Kim, Young-Choong;Chung, Bo-Sup;Lee, Kang-No;Koo, Hyang-Ja;Ahn, Sang-Mee;Huh, Hoon
    • Journal of Nutrition and Health
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    • v.16 no.2
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    • pp.115-124
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    • 1983
  • The biochemical nature of the protein constituents of six year old fresh Panax ginseng root was studied. Total protein constituents were extracted with phosphate buffer of pH 7.4, ionic strength of 0.1 and fractionated by ultrafiltration using four different membranes which cut down the materials of molecular weight of 500, 1,000, 5,000 and 10,000, respectively. Each fraction was subjected to ion exchange chromatography using DEAE - cellulose to isolate component proteins. The protein fraction larger than molecular weight of 10,000 was refractionated by the method of ammonium sulfate precipitation. The electrophoresis of the refractionated protein constituents was performed. The amino acid composition of the protein constituents was determined by gas- liquid chromatography. From the results, it could be summarized that eleven different protein constituents smaller than molecular weight of 10,000 were isolated from the fresh Panax ginseng root. At least eleven different protein constituents larger than molecular weight of 10,000 were identified from the electrophoretic patterns. These protein costituents seem to be compounded of all or some of five different subunits.

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Biosurfactant Production from Novel Air Isolate NITT6L: Screening, Characterization and Optimization of Media

  • Vanavil, B.;Perumalsamy, M.;Rao, A. Seshagiri
    • Journal of Microbiology and Biotechnology
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    • v.23 no.9
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    • pp.1229-1243
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    • 2013
  • In this paper, an air isolate (NITT6L) has been screened based on hemolytic activity, emulsification activity, drop collapsing test, and oil displacement test, as well as lipase activity. It was found that strain NITT6L was able to reduce the surface tension of the medium from 61.5 to 39.83 mN/m and could form stable emulsions with tested vegetable oils. Morphological, biochemical, 16S rRNA sequencing analyses, and fatty acid methyl ester analysis using gas chromatography confirmed that the air isolate under study was Pseudomonas aeruginosa. Characterization of the biosurfactant using agar double diffusion assay revealed that the biosurfactant was anionic in nature, and CTAB-methylene blue assay and Molisch test revealed its glycolipid nature. The FT-IR spectrum confirmed that the crude biosurfactant was a rhamnolipid. Using unoptimized medium containing sucrose as the carbon source, the isolate was found to produce 0.3 mg/ml of rhamnolipid in batch cultivation (shake flask) at $37^{\circ}C$ and pH 7. Optimization of the medium components was carried out using design of experiments and the yield of rhamnolipid has been enhanced to 4.6 mg/ml in 72 h of fermentation.

A Study on the Restoration of Neunggil Village Forests in Jinan (마을숲 복원에 관한 연구 - 전북 진안군 동향면 능금리 능길 마을을 사례로 -)

  • Park, Jee-Chul;Kim, Byung-Sup;Yun, Sung-Ho;Park, Sun-Mi
    • Journal of Korean Society of Rural Planning
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    • v.10 no.3 s.24
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    • pp.27-32
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    • 2004
  • The purpose of this study is on identifying the restoration guidelines of supplementary village grove and villageside forest in case of Neunggil village in Jinan county of Korea. These forests were managed very well before industrialization by village residents in order to obtain fuels and organic fertilizers traditionally. But recently, these forests were abandoned by using natural gas, oil and chemical fertilizer. Therefore, species diversity of these forests was downward and traditional rural landscape was lost. Accordingly, this study suggested the restoration guidelines of these forests through restoring the relationship between man and nature. For this, vegetation map was made by quadrat method. And management guidelines of these forests were suggested by the analysis of vegetation map. Also, for the restoration of supplementary village grove, Miyawiki professor's method of Yokohama university through introducing potential natural vegetation was suggested.

Self-healing Anticorrosion Coatings for Gas Pipelines and Storage Tanks

  • Luckachan, G.E.;Mittal, V.
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.209-216
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    • 2016
  • In the present study, chitosan based self-healing anticorrosion coatings were prepared by layer by layer (lbl) addition of chitosan (Ch) and polyvinyl butyral (PVB) on mild carbon steel substrate. Chitosan coatings exhibited enhanced coating stability and corrosion resistance in aggressive environments by the application of a PVB top layer. Chitosan layer in the lbl coatings have been modified by using glutaraldehyde (Glu) and silica ($SiO_2$). Performance of different coatings was tested using electrochemical impedance spectroscopy and immersion test. The best anticorrosion performance was observed in case of 10 % Ch_$SiO_2$_PVB coatings, which withstand immersion test over 25 days in 0.5 M salt solution without visible corrosion. 10 % Ch_$SiO_2$ coatings without the PVB top layer didn't last more than 3days. Application of PVB top layer sealed the defects in the chitosan pre-layer and improved its hydrophobic nature as well. Raman spectra and SEM of steel surfaces after corrosion study and removal of PVB_Ch/Glu_PVB coatings showed a passive layer of iron oxide, attributing to the self-healing nature of these coatings. Conducting particle like graphene reinforcement of chitosan in the lbl coatings enhanced corrosion resistance of chitosan coatings.