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Oxidation-Reduction Titration Curve Both Half Reactions Homogeneous in Coefficient (산화-환원 적정 곡선)

  • Choi, Q-Won
    • Journal of the Korean Chemical Society
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    • v.11 no.4
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    • pp.159-164
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    • 1967
  • An exact expression of the titration fraction as a function of the potential is derived for the cases where the coefficients of the both half reactions involved in the titration are homogeneous. It shows that the potential is independent of the concentration of the reagents not only at the equivalence point but also at all titration fractions. The sharpness of the end point detection by potentiometric method is shown to depend not only on the difference of the normal potentials involved but also strongly on the number of electrons transferred in each half reaction. The inflexion point of the potentiometric titration curve is shown to be slightly off from the equivalence point, including the cases where the number of electrons involved are equal. Completeness of the reaction in the course of titration is analyzed, too, mostly in terms of equilibrium constant, thus most of the results are applicable to any type of equilibrium in a single phase with particular relationship of coefficients of chemical equation.

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Interdecadal Changes in the Number of Days on Which Temperatures are not Higher Than -5℃ in Winter in Seoul (서울에서 겨울철 기온이 -5℃ 이하인 날 수의 십년간 변동 특성)

  • Choi, Jae-Won;Cha, Yumi;Kim, Jeoung-Yun;Park, Cheol-Hong
    • Journal of Climate Change Research
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    • v.7 no.1
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    • pp.49-57
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    • 2016
  • In the present study, the time series of the number of days on which temperatures were not higher than $-5^{\circ}C$ in winter in Seoul was analyzed. The results showed a decreasing tendency until recently. Statistical change-point analysis was conducted to examine whether climate regime shifts existed in this time series. According to the results, the number of days on which temperatures were not higher than $-5^{\circ}C$ in winter in Seoul drastically decreased since 1988. Therefore, to find out the reason for the recent decrease in the number of days, differences between the means of large-scale environments in winder during 1988~2010 and those during 1974~1987 were analyzed. In all layers of the troposphere, anomalous anticyclones developed in regions around the Korean Peninsula and thus the Korean Peninsula was affected by westerlies or south-westerlies. This was associated with the recent a little further northward development of western North Pacific subtropical high. Therefore, environments good for warm and humid air to flow into the Korean Peninsula were formed. To examine whether relatively warm and humid air actually flowed into the Korean Peninsula recently, temperatures and specific humidity in all layers in the troposphere were analyzed and according to the results the Korean Peninsula showed warm and humid anomalies. In the analyses of sensible heat net flux and maximum temperatures at a height of 2 m that can be felt by humans, the East Asia Continent including the Korean Peninsula showed positive anomalies.

A boundary radial point interpolation method (BRPIM) for 2-D structural analyses

  • Gu, Y.T.;Liu, G.R.
    • Structural Engineering and Mechanics
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    • v.15 no.5
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    • pp.535-550
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    • 2003
  • In this paper, a boundary-type meshfree method, the boundary radial point interpolation method (BRPIM), is presented for solving boundary value problems of two-dimensional solid mechanics. In the BRPIM, the boundary of a problem domain is represented by a set of properly scattered nodes. A technique is proposed to construct shape functions using radial functions as basis functions. The shape functions so formulated are proven to possess both delta function property and partitions of unity property. Boundary conditions can be easily implemented as in the conventional Boundary Element Method (BEM). The Boundary Integral Equation (BIE) for 2-D elastostatics is discretized using the radial basis point interpolation. Some important parameters on the performance of the BRPIM are investigated thoroughly. Validity and efficiency of the present BRPIM are demonstrated through a number of numerical examples.

Urban Stormwater Capture Curve using 3-Parameter Mixed Exponential Probability Density Function (3변수 혼합 지수 확률밀도함수를 이용한 도시 강우 유출수 포착곡선의 작성)

  • Han, Suhee;Park, Moo Jong;Kim, Sangdan
    • Journal of Korean Society on Water Environment
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    • v.24 no.4
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    • pp.430-435
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    • 2008
  • In order to design Non-point source management, the aspect of statistical features of the entire precipitation data should be focused since non-point source discharge is driven by continuous rainfall runoffs. 3-parameter mixed exponential probability density function is used to establish urban stormwater capture curve instead of previous single-parameter exponential PDF. Then, recent 10-year data in Busan are applied to establish the curve. The result shows that 3-parameter mixed PDF gives better resolution.

SIFT-Like Pose Tracking with LIDAR using Zero Odometry (이동정보를 배제한 위치추정 알고리즘)

  • Kim, Jee-Soo;Kwak, Nojun
    • Journal of Institute of Control, Robotics and Systems
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    • v.22 no.11
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    • pp.883-887
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    • 2016
  • Navigating an unknown environment is a challenging task for a robot, especially when a large number of obstacles exist and the odometry lacks reliability. Pose tracking allows the robot to determine its location relative to its previous location. The ICP (iterative closest point) has been a powerful method for matching two point clouds and determining the transformation matrix between the maps. However, in a situation where odometry is not available and the robot moves far from its original location, the ICP fails to calculate the exact displacement. In this paper, we suggest a method that is able to match two different point clouds taken a long distance apart. Without using any odometry information, it only exploits the features of corner points containing information on the surroundings. The algorithm is fast enough to run in real time.

ROBUST MEASURES OF LOCATION IN WATER-QUALITY DATA

  • Kim, Kyung-Sub;Kim, Bom-Chul;Kim, Jin-Hong
    • Water Engineering Research
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    • v.3 no.3
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    • pp.195-202
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    • 2002
  • The mean is generally used as a point estimator in water-quality data. Unfortunately, the nonnormal and skewed distributions of data hinder the direct application of the mean, which is inappropriate statistics in this case. The use of robust statistics such as L, M, and R-estimators are recommended and become more efficient. The median (L-estimator), the biweight (M-estimator), and the Hodges-Lehmann method (R-estimator) are briefly introduced and applied in this paper. From the actual data analyses, it is known that the median does not guarantee robustness for a small number of data sets, and robust measures of location or the arithmetic mean without outliers are highly recommended if the distribution has tails or outliers. Care must be taken to measure the location because water quality level within a water body can change depending on the selected point estimator.

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A BIFURCATION PROBLEM FOR THE BIHARMONIC OPERATOR

  • Jung, Tacksun;Choi, Q-Heung
    • Korean Journal of Mathematics
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    • v.20 no.2
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    • pp.263-271
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    • 2012
  • We investigate the number of the solutions for the biharmonic boundary value problem with a variable coefficient nonlinear term. We get a theorem which shows the existence of $m$ weak solutions for the biharmonic problem with variable coefficient. We obtain this result by using the critical point theory induced from the invariant function and invariant linear subspace.

HAMILTONIAN SYSTEM WITH THE SUPERQUADRATIC NONLINEARITY AND THE LIMIT RELATIVE CATEGORY THEORY

  • Jung, Tacksun;Choi, Q-Heung
    • Korean Journal of Mathematics
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    • v.22 no.3
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    • pp.471-489
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    • 2014
  • We investigate the number of the weak periodic solutions for the bifurcation problem of the Hamiltonian system with the superquadratic nonlinearity. We get one theorem which shows the existence of at least two weak periodic solutions for this system. We obtain this result by using variational method, critical point theory induced from the limit relative category theory.

Windowed Quaternion Estimator For Gyroless Spacecraft Attitude Determination

  • Kim, Injung
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.167.5-167
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    • 2001
  • Single point attitude determination method provides an optimal attitude minimizing the Wahba loss function. However, for the insufficient number of measurement vectors, the conventional single point methods has no unique solution. Thus, we introduce the sequential method to and an optimal attitude minimizing the windowed loss function. In this paper, this function is de ned as the sum of square errors for all measurement vectors within the axed sliding window. For simple implementation, the proposed algorithm is rewritten as a recursive form. Moreover, the covariance matrix is derived and expressed as a recursive form. Finally, we apply this algorithm to the attitude determination system with three LOS measurement sensors.

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BIFURCATION PROBLEM FOR THE SUPERLINEAR ELLIPTIC OPERATOR

  • Jung, Tacksun;Choi, Q-Heung
    • Korean Journal of Mathematics
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    • v.20 no.3
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    • pp.333-341
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    • 2012
  • We investigate the number of solutions for the superlinear elliptic bifurcation problem with Dirichlet boundary condition. We get a theorem which shows the existence of at least $k$ weak solutions for the superlinear elliptic bifurcation problem with boundary value condition. We obtain this result by using the critical point theory induced from invariant linear subspace and the invariant functional.