• Bulletin of the Korean Chemical Society
• /
• v.31 no.12
• /
• pp.3675-3678
• /
• 2010

In-situ X-ray absorption spectroscopy (XAS) was used to elucidate the structural variation of $\alpha-MoO_3$ electrode upon discharge/charge reaction in a lithium ion battery. According to the XAS analysis, hexavalent Mo atoms in $\alpha-MoO_3$ framework are reduced as the amount of intercalated lithium ions increases. As lithium de-intercalation proceeds, most of pre-edge peaks are restored again. However, according to the Fourier transforms of the extended X-ray absorption fine structure (EXAFS) spectra, lithium de-intercalation reaction is partially irreversible upon the charge reaction, which is one of the main reasons why the capacity of $\alpha-MoO_3$ electrode decreases upon successive discharge/charge cycles.

• Journal of the Korean Society of Industry Convergence
• /
• v.22 no.4
• /
• pp.395-403
• /
• 2019

The excessive need of power is creating an unbalance situation in power sector, where solar energy is one of the best solutions among other energy sources to mitigate this demand. It is globally accepted because of its flexibility and long life compared to others. A lot research is going on to enhance the energy efficiency by introducing photovoltaic (PV) power generation technology, but still irradiation of PV power is the major problem. In this manuscript, we have designed PV module using single diode methodology and also the solar conversion efficiency was boosted with maximum power point tracking (MPPT) by using perturb and observe (P&O) algorithm. The simulation was done for $1000W/m^2$ and $800W/m^2$ at solar irradiance in cell temperature of 25C and 40C degree levels in PSIM tool.

• Current Optics and Photonics
• /
• v.6 no.1
• /
• pp.60-68
• /
• 2022

We report on the design of the secondary and the tertiary mirrors used in lightweight assemblies made entirely of silicon carbide (SiC). The essential design points are weight reduction within the acceptable deformation of the mirror surface by gravity release, temperature change, and vibration during or after space launch. To find a design that achieves the target requirements, we established finite element models for various candidate designs and subjected each one to wave front error analyses along gravity directions and in operation temperatures. We also calculated the natural frequencies of the candidate assemblies. Our study suggested that a triangular cell with bipod flexure support can satisfy the target weight within the requirements.

• Medical Lasers
• /
• v.10 no.1
• /
• pp.1-6
• /
• 2021

Intravital microscopy is a high-resolution imaging technique based on laser-scanning two-photon and confocal microscopy, which allows dynamic 3D cellular-level imaging of various biological processes in a living animal in vivo. This unique capability allows biomedical researchers to directly verify a hypothesis in a natural in vivo microenvironment at the cellular level in a physiological setting. During the last decade, intravital microscopy has become an indispensable technique in several fields of biomedical sciences such as molecular and cell biology, immunology, neuroscience, developmental, and tumor biology. The most distinct advantage of intravital microscopy is its capability to provide a longitudinal view of disease progression at the cellular-level with repeated intravital imaging of a single animal over time by saving the images after each session.

• Journal of the Korean Society for Heat Treatment
• /
• v.36 no.1
• /
• pp.33-39
• /
• 2023

In this study, the effect of mixing condition of raw material powders possessing various particle size and particle size distribution on thermite reaction efficiency was investigated. When fine raw powders are used, rather the reaction yield tends to decrease due to agglomeration. In contrast, coarse raw powders make deteriorate the contact area between raw material powders containing Al reducing agent. To ensure the optimal thermite reaction efficiency, it is required to optimize a mixture condition of raw material powders prior to thermite reaction. From the current experiment, the maximum thermite reaction efficiency is 77%, which came from Nb₂O₅ + NiO +Al mixtures with size distribution from 9.25 to 22.63 ㎛.

• Journal of the Korean Chemical Society
• /
• v.55 no.2
• /
• pp.157-162
• /
• 2011

In the present study, we developed a portable GC module for real-time, quantitative determinations of gas mixtures in air sample. Capillary or packed column was coiled together with a heater wire and thermocouple in a small case. Together with the small and light weight sensors and valves as well as the rechargeable carrier gas canister, which permits collection and separation of samples, this system can determine the components of complex mixtures of air contaminants at low concentrations with a duty cycle of 10 min. When measured the various samples with a FID and TCD, the system showed, for a capillary column, a good resolution (R=8.3), high sensitivity, reproducibility, and linear dynamic range greater than three orders of magnitude. These results indicate that the portable GC module is expected to be used for a wide range of applications, particularly for in situ environmental monitoring, chemical processes, and regulation of contaminant emission.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.2
• /
• pp.1348-1354
• /
• 2015

In this paper, chaotic circuit of the voltage controlled Lorentz system for engineering applications has been designed and implemented in an electronic circuit. The proposed circuit consists of MOS variable resistor, multipliers, capacitors, fixed resistors and operational amplifiers. The circuit was analysed by PSPICE program. PSPICE simulation results show that chaotic dynamics of the circuit can be controlled by the MOS variable resistor through time series analysis, frequency analysis and phase diagrams. Also, we implemented the proposed circuit in an electronic hardware system with discrete elements. Measured results of the circuit showed controllability of the circuit using the MOS resistor.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.6
• /
• pp.239-245
• /
• 2016

In this study, a 12 V PWM boost converter was designed with the optimal values of the external components of the power stage was well as the compensation stage for smart electronic applications powered by a battery device. The 12 V boost PWM converter consisted of several passive elements, such as a resistor, inductor and capacitor with a diode, power MOS switch and control IC chip for the control PWM signal. The devices of the power stage and compensation stage were designed to maintain stable operation under a range of load conditions as well as achieving the highest power efficiency. The results of this study were first verified by a simulation in SPICE from calculations of the values of major external elements comprising the converter. The design was also implemented on the prototype PCBboard using commercial IC LM3481 from Texas Instruments, which has a nominal output voltage of 12 V. The output voltage, ripple voltage, and load regulation with the line regulation were measured using a digital oscilloscope, DMM tester, and DC power supply. By configuring the converter under the same conditions as in the circuit simulation, the experimental results matched the simulation results.

• Membrane Journal
• /
• v.26 no.4
• /
• pp.239-252
• /
• 2016

Two-dimensional materials offer unique characteristics for membrane applications to water technology. With its atomic thickness, availability and stackability, graphene in particular is attracting attention in the research and industrial communities. Here, we present a brief overview of the recent research activities in this rising topic with bringing two membrane architecture into focus. Pristine graphene in single- and polycrystallinity poses a unique diffusion barrier property for most of chemical species at broad ambient conditions. If well designed and controlled, physical and chemical perforation can turn this barrier layer to a thinnest feasible membrane that permits ultimate permeation at given pore sizes. For subcontinuum pores, both molecular dynamics simulations and experiments predict potential salt rejection to envisage a seawater desalination application. Another novel membrane architecture is a stack of individual layers of 2D materials. When graphene-based platelets are chemically modified and stacked, the interplanar spacing forms a narrow transport pathway capable of separation of solvated ions from pure water. Bearing unbeknownst permeance and selectivity, both membrane architecture - ultrathin porous graphene and stacked platelets - offer a promising prospect for new extraordinary membranes for water technology applications.

• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.180-187
• /
• 2014

Nanocomposites including graphene oxide (GO) and conducting polymers (PPy, PANI and PEDOT) were prepared via an in-situ chemical polymerization process, and their characteristic properties depending upon the change of conducting polymer (CP) content were analyzed. A confirmation was made on not only the functional groups formed in GO but also the presence of CP existent in the nanocomposites. The molecular interaction between GO and poly(4-styrene sulfonic acid) (PSSA) or CP in the nanocomposites was proposed. With the increase of PEDOT content in the GOPSS/PEDOT nanocomposite, the estimated value of $I_D/I_G$ regarding the Raman analysis of them was decreased and a major change of their Raman spectra characteristic peaks was observed. In the GO-PSS/PEDOT nanocomposite, PEDOT molecules made an exfoliation of GO-PSSA layers and thus they were intercalated among layers. Such a unique molecular morphology induced the highest electrical conductivity for the GO-PSS/PEDOT nanocomposite among three kinds of nanocomposites prepared in this study. It is also noted that the uniform morphology confirmed in this study helped a thermal stability improvement in the nanocomposite due to the presence of GO or GO-PSSA acting as a thermal barrier.