• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.3.2-3.2
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• 2011

Nanofibers, one of various one-dimensional nanomaterials such as nanorods, nanowires and nanotubes have been successfully synthesized by many groups in recent years and their applications to chemical sensors, catalytic filters and biomedicine, etc. are extensively tested. In particular, there is a possibility that chemical sensors based on oxide nanofibers can overcome the shortcomings of chemical sensors based on single nanowires. In order to prepare oxide nanofibers, the electrospinning method is most widely used. In this work, we synthesized various oxide nanofibers including ZnO, SnO2 and CuO by employing an electrospinning method and various shapes of nanofibers including core-shell nanofibers and hollow nanofibers as well. The response properties of the various nanofibers to oxidizing and reducing gaseous species have been investigated systematically. The normal oxide nanofibers showed high sensitivity and quite fast response time to many gaseous species. Furthermore, derivatives of normal nanofibers including hollow nanofibers, core-shell nanofibers and heterostructured nanofibers display much superior sensing properties. These results hold promise for the practical application of oxide nanofibers to chemical sensors. In addition, the sensing mechanisms operated in the nanofibers will be discussed in detail.

• 한국재료학회지
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• 제28권6호
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• pp.343-348
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• 2018

Recently, the properties of nanostructured materials as advanced engineering materials have received great attention. These properties include fracture toughness and a high degree of hardness. To hinder grain growth during sintering, it is necessary to fabricate nanostructured materials. In this respect, a high-frequency induction-heated sintering method has been presented as an effective technique for making nanostructured materials at a lower temperature in a very short heating period. Nanopowders of W and $Al_2O_3$ are synthesized from $WO_3$ and Al powders during high-energy ball milling. Highly dense nanostructured $W-Al_2O_3$ composites are made within three minutes by high-frequency induction-heated sintering method and materials are evaluated in terms of hardness, fracture toughness, and microstructure. The hardness and fracture toughness of the composite are $1364kg/mm^2$ and $7.1MPa{\cdot}m^{1/2}$, respectively. Fracture toughness of nanostructured $W-Al_2O_3$ is higher than that of monolithic $Al_2O_3$. The hardness of this composite is higher than that of monolithic W.

• Journal of Microbiology and Biotechnology
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• 제26권9호
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• pp.1505-1516
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• 2016

The detection of food pathogens is an important aspect of food safety. A range of detection systems and new analytical materials have been developed to achieve fast, sensitive, and accurate monitoring of target pathogens. In this review, we summarize the characteristics of selected nanomaterials and their applications in food, and place focus on the monitoring of biological and chemical contaminants in food. The unique optical and electrical properties of nanomaterials, such as gold nanoparticles, nanorods, quantum dots, carbon nanotubes, graphenes, nanopores, and polydiacetylene nanovesicles, are closely associated with their dimensions, which are comparable in scale to those of targeted biomolecules. Furthermore, their optical and electrical properties are highly dependent on local environments, which make them promising materials for sensor development. The specificity and selectivity of analytical nanomaterials for target contaminants can be achieved by combining them with various biological entities, such as antibodies, oligonucleotides, aptamers, membrane proteins, and biological ligands. Examples of nanomaterial-based analytical systems are presented together with their limitations and associated developmental issues.

• Computers and Concrete
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• 제14권2호
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• pp.175-191
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• 2014

In recent years, the emergence of nanotechnology and nanomaterial has created hopes to improve various properties of concrete. Nano silica as one of these materials has been introduced as a cement replacement material for concrete mixture in construction applications. It can modify the properties of concrete, due to high pozzolanic reactions and also making a denser microstructure. On the other hand, it is well recognized that the use of mineral admixtures such as silica fume affects the mechanical properties and durability of cementitious materials. In addition, the superior performance of self-consolidating concrete (SCC) and self-consolidating mortars (SCM) over conventional concrete is generally related to their ingredients. This study investigates the effect of nano silica and silica fume on the compressive strength and chloride permeability of self-consolidating mortars. Tests include compressive strength, rapid chloride permeability test, water permeability, capillary water absorption, and surface electrical resistance, which carried out on twenty mortar mixtures containing zero to 6 percent of nano silica and silica fume. Results show that SCMs incorporating nano silica had higher compressive strength at various ages. In addition, results show that nano silica has enhanced the durability SCMs and reduced the chloride permeability.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.10.2-10.2
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• 2011

The design and synthesis of protein-like polymers is a fundamental challenge in materials science. A biomimetic approach is to explore the impact of monomer sequence on non-natural polymer structure and function. We present the aqueous self-assembly of two peptoid polymers into extremely thin two-dimensional (2D) crystalline sheets directed by periodic amphiphilicity, electrostatic recognition and aromatic interactions. Peptoids are sequence-specific, oligo-N-substituted glycine polymers designed to mimic the structure and functionality of proteins. Mixing a 1:1 ratio of two oppositely charged peptoid 36 mers of a specific sequence in aqueous solution results in the formation of giant, free-floating sheets with only 2.7 nm thickness. Direct visualization of aligned individual peptoid chains in the sheet structure was achieved using aberration-corrected transmission electron microscopy. Specific binding of a protein to ligand-functionalized sheets was also demonstrated. The synthetic flexibility and biocompatibility of peptoids provide a flexible and robust platform for integrating functionality into defined 2D nanostructures. In the later part of my talk, we describe the use of metal ions to construct two-dimensional hybrid films that have the ability to self-heal. Incubation of biomimetic peptoid polymers with specific divalent metal ions results in the spontaneous formation of uniform multilayers at the air-water interface. We anticipate that ease of synthesis and transfer of these two-dimensional materials may have many potential applications in catalysis, gas storage and sensing, optics, nanomaterial synthesis, and environmentally responsive scaffolds.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.52.2-52.2
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• 2011

Flat form technology for constructing anticancer loaded multi-walled carbon nanotubes (mwCNTs) was introduced in this study. Conventional anticancer drugs, such as MTX (Methotrexate), cisplatin, DOX (Doxorubicin hydrochloride), DAU (Daunorubicin) and EPI (epirubicin) were bio-conjugated with folic acid (FA) for selective targeting tumor cells. Loading efficiencies of the used anticancer drugs on mwCNTs have shown different order of bindings depending on the molecular bind affinity of NH (amine) formation on mwCNTs. MTT assays have shown increased selective target efficiency of FA conjugated mwCNTs on breast cancer cell growth inhibition. All results collectively indicated promising application of mwCNTs as a smart inorganic nanomaterial for selective targeting drug delivery vehicle at tumor tissues.

• Safety and Health at Work
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• 제2권1호
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• pp.65-69
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• 2011

Objectives: Carbon nanotubes are an important new class of technological materials that have numerous novel and useful properties. Multi-walled carbon nanotubes (MWCNTs), which is a nanomaterial, is now in mass production because of its excellent mechanical and electrical properties. Although MWCNTs appear to have great industrial and medical potential, there is little information regarding their toxicological effects on researchers and workers who could be exposed to them by inhalation during the handling of MWCNTs. Methods: The generation of an untangled MWCNT aerosol with a consistent concentration without using surfactants that was designed to be tested in in vivo inhalation toxicity testing was attempted. To do this, MWCNTs were dispersed in deionized water without the addition of any surfactant. To facilitate the dispersion of MWCNTs in deionized water, the water was heated to $40^{\circ}C$, $60^{\circ}C$, and $80^{\circ}C$ depending on the sample with ultrasonic sonication. Then the dispersed MWCNTs were atomized to generate the MWCNT aerosol. After aerosolization of the MWCNTs, the shapes of the NTs were examined by transmission electron microscopy. Results: The aerosolized MWCNTs exhibited an untangled shape and the MWCNT generation rate was about 50 $mg/m^3$. Conclusion: Our method provided sufficient concentration and dispersion of MWNCTs to be used for inhalation toxicity testing.

• Korean Chemical Engineering Research
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• 제53권1호
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• pp.39-45
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• 2015

We produced magnetite nanoparticles (MNPs) and a Mg-rich solution as a nano-adsorbent and a coagulant for water treatment, respectively, using a low-grade iron ore. The ore was leached with aqueous hydrochloric acid and its impurities were removed by solvent extraction of the leachate using tri-n-butyl phosphate as an extractant. The content of Si and Mg, which inhibit the formation of MNPs, was reduced from 10.3 wt% and 15.5 wt% to 28.1 mg/L and < 1.4 mg/L, respectively. Consequently, the Fe content increased from 68.6 wt% to 99.8 wt%. The high-purity $Fe^{3+}$ solution recovered was used to prepare 5-15-nm MNPs by coprecipitation. The wastewater produced contained a large amount of $Mg^{2+}$ and can be used to precipitate struvite in sewage treatment. This process helps reduce the cost of both sewage and iron-orewastewater treatments, as well as in the economic production of the nano-adsorbent.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.248-259
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• 2008

There are several well-known materials for the hydrogen storage such as metallic alloy, carbon nanomaterials, non-carbon nanomaterials, and compounds etc. Efficient and inexpensive hydrogen storage methods are an essential prerequisite for the utilization of hydrogen, one of the new and clean energy sources. Many researches have been widely performed for the hydrogen storage techniques and materials to improve the high storage capacity and stability. In this paper, the patents concerning the non-carbon nanomaterial hydrogen storage method were collected and analyzed. The search range was limited in the open patents of Korea(KR), Japan(JP), USA(US) and European Union(EP) from 1996 to 2007. Patents were collected by using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies. and technologies.

• Carbon letters
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• 제14권4호
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• pp.210-217
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• 2013

The synthesis of carbon nanomaterials (CNMs) by a chemical vapor deposition method using three different plant oils as precursors is presented. Because there are four parameters involved in the synthesis of CNM (i.e., the precursor, reaction temperature of the furnace, catalysts, and the carrier gas), each having three variables, it was decided to use the Taguchi optimization method with the 'the larger the better' concept. The best parameter regarding the yield of carbon varied for each type of precursor oil. It was a temperature of $900^{\circ}C$ + Ni as a catalyst for neem oil; $700^{\circ}C$ + Co for karanja oil and $500^{\circ}C$ + Zn as a catalyst for castor oil. The morphology of the nanocarbon produced was also impacted by different parameters. Neem oil and castor oil produced carbon nanotube (CNT) at $900^{\circ}C$; at lower temperatures, sphere-like structures developed. In contrast, karanja oil produced CNTs at all the assessed temperatures. X-ray diffraction and Raman diffraction analyses confirmed that the nanocarbon (both carbon nano beads and CNTs) produced were graphitic in nature.