• Title/Summary/Keyword: Nano-colloid

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A Study on the Effects of CNC Addition on Electrochemical Properties of Lead-acid Battery (CNC 첨가에 따른 납축전지의 전기화학적 특성연구)

  • Kim, Jee-Hoon;Mun, Jun-Ho;Moon, Seong-Yong;Ku, Bon-Keun;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.279-285
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    • 2008
  • CNC (Carbon Nano Colloid) was used as an additive to the positive electrode to improve the discharge performance of sealed lead-acid batteries, The cathode active material ($PbO_2$) has a relatively low utility of less than 60 % compared with other kind of batteries, such as Ni-MH and Lithium ion, In this study, to overcome the above-mentioned problem we investigated the effects of CNC addition on the enhancement of electrical connection with not-utilized $PbO_2$ and resultantly electrical conductivity of electrode, We examined low rate discharge capacities, high rate discharge capacities and internal resistances of the batteries containing various amounts of CNC. From these results, we found out that the addition of CNC into the positive electrode made a significant improvement in high rate discharge capacity, We also suggested the optimum content of CNC material in positive electrode.

Study of the Application of Gel Electrolyte in the Reference Electrode of $Cu/CuSO_4$

  • Lin, Cunguo;Xu, Likun;Liu, Yang
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.179-181
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    • 2008
  • With nano-$SiO_2$ and sulphate acid, a kind of colloid electrolyte is synthesized by sol-gel method. It is placed outside the reference electrode as a layer of gel electrolyte so as to decrease the leaching of $Cu^{2+}$ and increase the life of the reference electrode. The performance of the gel electrode in simulating soil solution is measured as follows: the potential of the electrodes ranging from 60 mV to 80 mV (vs. SCE) with potential variation no more than $\pm10mV$, enough resistance to polarization. The $Cu^{2+}$ effusion rate of the reference electrode without gel electrolyte is 3 times that with colloid electrolyte, which means that gel electrolyte can extend the life of the reference electrode significantly.

Surface Chemistry in Biocompatible Nanocolloidal Particles (생체 적합한 나노입자와 계면화학)

  • Kim Jong-Duk;Jung Jae Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.295-305
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    • 2004
  • Colloid and surface chemistry have been focused on surface area and surface energy. Local surface properties such as surface density, interaction, molecular orientation and reactivity have been one of interesting subjects. Systems of such surface energy being important would be listed as association colloid, emulsion, particle dispersion, foam, and 2-D surface and film. Such nanoparticle systems would be applied to drug delivery systems and functional cosmetics with biocompatible and degradable materials, while nanoparticles having its size of several nm to micron, and wide surface area, have been accepted as a possible drug carrier because their preparation, characteristics and drug loading have been inves-tigated. The biocompatible carriers were also used for the solubilization of insoluble drugs, the enhancement of skin absorption, the block out of UV radiation, the chemical stabilization and controlled release. Nano/micro emulstion system is classified into nano/microsphere, nano/microcapsule, nano/microemulsion, polymeric micelle, liposome according to its prep-aration method and size. Specially, the preparation method and industrial applications have been introduced for polymeric micelles self-assembled in aqueous solution, nano/microapsules controlling the concentration and activity of high concen-tration and activity materials, and monolayer or multilayer liposomes carrying bioactive ingredients.

Synthesis of metallic copper nanoparticles and metal-metal bonding process using them

  • Kobayashi, Yoshio;Nakazawa, Hiroaki;Maeda, Takafumi;Yasuda, Yusuke;Morita, Toshiaki
    • Advances in nano research
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    • v.5 no.4
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    • pp.359-372
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    • 2017
  • Metallic copper nanoparticles were synthesised by reduction of copper ions in aqueous solution, and metal-metal bonding by using the nanoparticles was studied. A colloid solution of metallic copper nanoparticles was prepared by mixing an aqueous solution of $CuCl_2$ (0.01 M) and an aqueous solution of hydrazine (reductant) (0.2-1.0 M) in the presence of 0.0005 M of citric acid and 0.005 M of n-hexadecyltrimethylammonium bromide (stabilizers) at reduction temperature of $30-80^{\circ}C$. Copper-particle size varied (in the range of ca. 80-165 nm) with varying hydrazine concentration and reduction temperature. These dependences of particle size are explained by changes in number of metallic-copper-particle nuclei (determined by reduction rate) and changes in collision frequency of particles (based on movement of particles in accordance with temperature). The main component in the nanoparticles is metallic copper, and the metallic-copper particles are polycrystalline. Metallic-copper discs were successfully bonded by annealing at $400^{\circ}C$ and pressure of 1.2 MPa for 5 min in hydrogen gas with the help of the metalli-ccopper particles. Shear strength of the bonded copper discs was then measured. Dependences of shear strength on hydrazine concentration and reduction temperature were explained in terms of progress state of reduction, amount of impurity and particle size. Highest shear strength of 40.0 MPa was recorded for a colloid solution prepared at hydrazine concentration of 0.8 M and reduction temperature of $50^{\circ}C$.

Characterization of gold nanoparticles on optical fiber for localized surface plasmon resonance sensor (광섬유 국소화 표면 플라즈몬 공명 센서를 위한 광섬유 표면상의 금 나노 입자 특성 분석)

  • Lee, Hoon;Lee, Seung-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.226-233
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    • 2009
  • In this study, the optical properties of localized surface plasmon resonance sensor using optical fiber was analyzed as the variation of a size and surface density of gold nano particles on the etched optical fiber surface. It is shown that a size and surface density of gold nano particles on optical fiber surface are controlled by $Na_3$ citrate quantity and pH of gold colloid solution. To measure the sensitivity, peak wavelength of absorbance spectrum was detected as the reflective index of the solution. The sensor sensitivity is linearly dependent on the size and surface densities of gold nano particles from the results of optical experiments.

Array-based Nano-amplification Technique Was Applied in Detection of Hepatitis E Virus

  • Liu, Hui-Hui;Cao, Xuan;Yang, Yong;Liu, Ming-Gui;Wang, Ye-Fu
    • BMB Reports
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    • v.39 no.3
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    • pp.247-252
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    • 2006
  • A rapid method for the detection of Hepatitis E Virus (HEV) was developed by utilizing nano-gold labeled oligonucleotide probes, silver stain enhancement and the microarray technique. The 5'-end -$NH_2$ modified oligonucleotide probes were immobilized on the surface of the chip base as the capture probe. The detection probe was made of the 3'-end -SH modified oligonucleotide probe and nano-gold colloid. The optimal concentrations of these two probes were determined. To test the detection sensitivity and specificity of this technique, a conservative fragment of the virus RNA was amplified by the RT-PCR/PCR one step amplification. The cDNA was hybridized with the capture probes and the detection probes on microarray. The detection signal was amplified by silver stain enhancement and could be identified by naked eyes. 100 fM of amplicon could be detected out on the microarray. As the results, preparation of nano-gold was improved and faster. Development time also was shortened to 2 min. Thus, considering high efficiency, low cost, good specificity and high sensitivity, this technique is alternative for the detection of HEV.

Improved Electrical Conductivity of CFRP by Conductive Nano-Particles Coating for lightning Strike Protection (낙뢰손상방지를 위한 전도성 나노입자 코팅에 의한 탄소섬유 복합재료의 전기전도도 향상 연구)

  • Ha, Min-Seok;Kwon, Oh-Yang;Choi, Heung-Soap
    • Composites Research
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    • v.23 no.1
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    • pp.31-36
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    • 2010
  • The improvement of electrical conductivity of carbon-fiber reinforced plastics (CFRP) has been investigated by silver nano-particles coating for the purpose of lightning strike protection. Silver nano-particles in colloid were sprayed on the surface of carbon fibers, which were then impregnated by epoxy resin to form a CFRP specimen. Electrical resistance was measured by contact resistance meter which utilize the principles of the AC 4-terminal method. Electrical resistance value was then converted to electrical conductivity. The coated silver nano-particles on the carbon fibers were verified by SEM and EDS. The electrical conductivity was increased by three times of the ordinary CFRP.

Performance Evaluation of Substitution Radiopharmaceutical according to Restriction of the Radiocolloids in Lymphoscintigraphy (Lymphoscintigraphy에 이용되는 방사성의약품의 사용제한으로 인한 대체 방사성의약품의 성능평가)

  • Seo, Young-Deok;Jeong, Jae-Hun;Moon, Jong-Woon;Yun, Sang-Hyeok;Kim, Yeong-Seok;Kang, Se-Hun;Won, Woo-Jae;Kim, Seok-Ki
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.1
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    • pp.25-29
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    • 2009
  • Purpose: Several radioactive agents were used for lymphoscintigraphy in breast cancer. But recently, due to the change of local radiopharmaceutical licensing policy and discontinuation of supplies from manufacturer, we could not use many radiocolloids such as $^{99m}Tc$-Antimony Trisulfide Colloid, $^{99m}Tc$-Tin Colloid, $^{99m}Tc$-Human Serum Albumin. So it is necessary to use the substitution radiopharmaceutical. Therefore, this study aims to evaluate the performance of substitution radiopharmaceutical ($^{99m}Tc$-Phytate) including the existing radiocolloids and to set up of the appropriate protocol in lymphoscintigraphy. Materials and Methods: For each radiocolloids ($^{99m}Tc$-Antimony Trisulfide Colloid (ASC), $^{99m}Tc$-Tin Colloid (TC), $^{99m}Tc$-Human Serum Albumin (HSA), $^{99m}Tc$-Phytate) were performed the particle size by Zeta Sizer (Nano-ZS) and we compared the radiolabeling time, procedure and acquisition time for each of the radiocolloids (total 200 patients). For the last time, we made an analysis of image for each of the radiocolloids with our previous report (SJ Jang et al, Korean Nucl Med Mol imaging Vol.41, No.6, Dec 2007). Results: The particle size of each radiocolloids showed A.S.C (50 nm), T.C (310 nm), H.S.A (10.8 nm), $^{99m}Tc$-Phytate (499 nm). The labeling and acquisition time for each of the radiocolloids showed no substantial difference. But there is difference of the labeling time for the A.S.C. because the ASC procedure need to boiling process. There were no significant differences among those radiocolloids (p>0.005) in the identification rate (IR), false negative rate (FNR), and negative predictive value (NPV). Conclusions: $^{99m}Tc$-labeled radiocolloids showed equivalent results in lymphoscintigraphy. Therefore, in this exam of each radiocolloids could be applied appropriate protocol in lymphoscintigraphy.

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Reduction of Odor Emission from Swine Excreta using Silver Nano Colloid (은 나노 콜로이드를 이용한 돼지분뇨의 악취 저감 효과)

  • Kim, Koo-Pil;Choi, Young-Soo;Oh, Kwang-Hyun;Koo, Kyung-Bon;Suh, Sang-Ryong;Yoo, Soo-Nam;Lee, Kyeong-Hwan
    • Journal of Biosystems Engineering
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    • v.36 no.5
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    • pp.342-347
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    • 2011
  • The effect of SNC(silver nano colloid) on the emission reduction of odors such as ammonia ($NH_3$), hydrogen sulfide ($H_2S$), and methane ($CH_4$) from swine excreta was studied. Silver has been used as an universal antibiotic substance and can reduce the emission of some gases by sterilizing action. Therefore, an apparatus which produces SNC was developed and was conducted its performance test. Also, the SNC made by the apparatus was applied to swine excreta sampled from a piggery in oder to find the effect on the reduction of odor emission. An electrolysis apparatus was developed to produce SNC and its capacity was 0.024 ppm/$hr{\cdot}L$. The effects of SNC on the reduction of odor emission from swine excreta were tested for bad smell gases of ammonia ($NH_3$), hydrogen sulfide ($H_2S$) and methane ($CH_4$). For ammonia gas, factorial experiments were conducted to find the effects of concentration and application rate of SNC. The test results for the different concentrations of 20 ppm, 50 ppm, and 100 ppm showed that the more concentration of SNC was increased, the more emission reduction of ammonia gas increased. From the test results about the effect of application rate, the more SNC was applied, the more emission reduction of $NH_3$ increased. In order to reduce the concentration of $NH_3$ below 5 ppm, SNC of 50 ppm is recommended to be applied at an interval of 6 hours, and is mixed with swine excreta in the volumetric ratio of 4:1. For hydrogen sulfide gas, the concentration was decreased as time went by and was reduced rapidly in the first stage of the tests for all applied concentrations of SNC (20 ppm, 50 ppm, and 100 ppm). Especially, when 100 ml of SNC with 100 ppm was applied, emission of hydrogen sulfide gas was reduced rapidly during early 4 hours after the application of SNC. And, concentration of hydrogen sulfide gas was maintained below 20 ppm after 12 hours. For methane gas, t-test showed that there was no significance on the effect of its application for all applied concentrations of SNC. Therefore, it was concluded that the application of SNC on swine excreta had no effect on the emission reduction of $CH_4$.