• Title/Summary/Keyword: Nano-Mechanics

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Electromechanical Properties of Conductive MWCNT Film Deposited on Flexible Substrate Affected by Concentration of Dispersing Agent (분산제 농도에 따른 MWCNT 전도성 유연필름의 전기-기계적 특성)

  • HwangBo, Yun;Kang, Yong-Pil;Kim, Jae-Hyun;Kim, Duck-Jong;Lee, Hak-Joo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.517-521
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    • 2012
  • Carbon nanotubes (CNTs) have been regarded as a promising material for the fabrication of flexible conductors such as transparent electrodes, flexible heaters, and transparent speakers. In this study, a multiwalled carbon nanotube (MWCNT) film was deposited on a polyethylene terephthalate (PET) substrate using a spraying technique. MWCNTs were dispersed in water using sodium dodecyl sulfate (SDS). To evaluate the effect of the weight ratio between SDS and MWCNTs on the electromechanical properties of the film, direct tensile tests and optical strain measurement were conducted. It was found that the CNT film hardly affected the mechanical behavior of CNT/PET composite films, while the electrical behavior of the CNT film was strongly affected by the SDS concentration in the CNT film. The electrical resistance of CNT/PET films gradually increased with the strain applied to the PET substrate, even up to a large strain that ruptured the substrate.

High Concentrated Silver Nano Ink Formulation for the Inkjet Applications (잉크젯 응용기술을 위한 고농도 은 나노 잉크 배합)

  • Kim, Tae-Hoon;Cho, Hye-Jin;Joung, Jae-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.559-560
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    • 2006
  • Inkjet Printing is very attractive method for direct patterns with no masks, In order to Achieve direct printing with nano metal, It is often necessary to print them with highly concentrated Ink We research the High Concentrated silver nano ink. Formulation which has a good thermal stability and storage stability and jet stability using a ethylene glycol ether. Normally Alcohol-based inks can be sensitive But High boiling point ethylene glycol ether base Ink is creating a stable meniscus and minimum maintenance issues. We are reaching a 50~60wt% high Silver Ink using a Hydrophilic Ag Nano powder. (30~50nm)

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Nano-Mechanics 분석을 통한 질화 텅스텐 확산방지막의 질소 유량에 따른 박막내 응력 변화 연구

  • Gwon, Gu-Eun;Kim, Su-In;Lee, Chang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.386-386
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    • 2013
  • 반도체 소자의 소형화, 고집적화로 박막의 다층화 및 선폭의 감소 등의 복잡한 제조 공정이 불가피하고, 따라서 공정 중 실리콘 웨이퍼와 금속 박막사이의 확산을 방지하기 위한 많은 연구가 이루어지고 있다. 하지만 현재까지의 연구는 확산방지막의 nano-mechanics 특성 분석에 대한 연구는 전무하다. 본 논문에서 tungsten (W)을 주 물질로, nitrogen (N)을 첨가한 확산방지막을 질소 유량을 2.5, 5, 7.5, 10 sccm으로 변화시켜가면서 rf magnetron sputter 방법으로 tungsten-nitride (W-N) 박막을 증착하였다. 박막의 기본 물성인 증착율, 비저항 및 결정학적 특성을 ${\beta}$-ray, 4-point probe, X-ray diffraction (XRD)를 이용하여 측정하였고, 측정결과 증착 중 질소 유량이 증가할수록 W-N 박막의 비저항은 증가하였고 반대로 증착율과 결정성은 감소하였다. 이는 기존의 연구 결과와 비교하여 일치한 결과로 증착된 박막이 신뢰성을 가짐을 확인하였다. 이후 가장 관심사인 nano-mechanics 특성은 nano-indenter를 이용하여 측정하였다. 측정 결과 시료는 증착 중 질소 유량이 2.5 sccm인 시료를 기준으로 5 sccm 포함된 박막에서 load force-depth 그래프가 급격히 변화하는 경향을 나타내었고, 표면강도(surface hardness)는 10.07 GPa에서 15.55 GPa로 증가하였다. 이후 질소 유량이 7.5 sccm과 10 sccm에서는 12.65 GPa와 12.77 GPa로 질소 유량이 5 sccm 포함된 박막보다 상대적으로 감소하였다. 이는 박막내 결정상으로 존재하는 질소와 비정질 상태로 존재하는 질소의 비율에 의한 것이고, 압축력에 기인하는 스트레스 증가로 판단된다.

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Evaluation of MWCNT Exposure and the Wear Characteristics of MWCNT-containing PC/ABS Composites (다중벽 탄소나노튜브를 함유한 PC/ABS 복합재의 마모 특성 및 다중벽 탄소나노튜브의 유출 평가)

  • Lee, Hyun-Woo;Kim, Kyung-Shik;Lee, Jae-Hyeok;Kim, Hyo-Sop;Kim, Jae-Ho;Oh, Dong-Hoon;Ryu, Sang-Hyo;Jang, Young-Chan;Kim, Jae-Hyun;Lee, Hak-Joo;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.30 no.5
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    • pp.278-283
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    • 2014
  • Carbon nanotubes (CNTs) are used in various composite materials to enhance electrical, thermal and mechanical properties of composite materials. In this study, we investigate the wear characteristics of polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) blends containing multi-walled carbon nanotubes (MWCNTs). PC/ABS blends are commonly used in many industrial applications such as cellular phones and display cases and MWCNTs have been added to the PC/ABS blends to improve their electromagnetic interference shielding (EMS). We performed wear tests on PC/ABS blends containing MWCNTs under reciprocating linear sliding conditions with chrome steel balls as a counterpart material. The normal loads were 10, 30, 50, 70, 100 N, the sliding speed was 10 mm/s, the stroke length was 15 mm, and the tests lasted 900 s. The MWCNTs included in the PC/ABS blends lower the wear volume and friction coefficient of the composites. We analyzed the wear debris collected from the composites during the tests in terms of the MWCNT concentration using inductively coupled plasma optical emission spectroscopy. The results show that the quantity of MWCNTs in the debris is proportional to the concentration of MWCNTs in the composite, indicating that the exposure of the MWCNTs to environments by wear could be increased with their concentration in the composite.

Thermal, electrical and mechanical buckling loads of sandwich nano-beams made of FG-CNTRC resting on Pasternak's foundation based on higher order shear deformation theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad;Arani, M.R. Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.69 no.4
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    • pp.439-455
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    • 2019
  • This research deals with thermo-electro-mechanical buckling analysis of the sandwich nano-beams with face-sheets made of functionally graded carbon nano-tubes reinforcement composite (FG-CNTRC) based on the nonlocal strain gradient elasticity theory (NSGET) considering various higher-order shear deformation beam theories (HSDBT). The sandwich nano-beam with FG-CNTRC face-sheets is subjected to thermal and electrical loads while is resting on Pasternak's foundation. It is assumed that the material properties of the face-sheets change continuously along the thickness direction according to different patterns for CNTs distribution. In order to include coupling of strain and electrical field in equation of motion, the nonlocal non-classical nano-beam model contains piezoelectric effect. The governing equations of motion are derived using Hamilton principle based on HSDBTs and NSGET. The differential quadrature method (DQM) is used to calculate the mechanical buckling loads of sandwich nano-beam as well as critical voltage and temperature rising. After verification with validated reference, comprehensive numerical results are presented to investigate the influence of important parameters such as various HSDBTs, length scale parameter (strain gradient parameter), the nonlocal parameter, the CNTs volume fraction, Pasternak's foundation coefficients, various boundary conditions, the CNTs efficiency parameter and geometric dimensions on the buckling behaviors of FG sandwich nano-beam. The numerical results indicate that, the amounts of the mechanical critical load calculated by PSDBT and TSDBT approximately have same values as well as ESDBT and ASDBT. Also, it is worthy noted that buckling load calculated by aforementioned theories is nearly smaller than buckling load estimated by FSDBT. Also, similar aforementioned structure is used to building the nano/micro oscillators.

Effects of mixed contents of carbon nanoreinforcements on the impact resistance of epoxy-based nanocomposites

  • Ayatollahi, M.R.;Naeemi, A.R.;Alishahi, E.
    • Structural Engineering and Mechanics
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    • v.56 no.2
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    • pp.157-167
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    • 2015
  • The impact behavior of epoxy-based nanocomposites reinforced with carbon nano tube (CNT), carbon nano fiber (CNF) and mixed contents of these nanoparticles was investigated using Izod impact test. The results showed that while the impact strength of nanocomposites containing 1 wt% of CNT and 1 wt% of CNF increased 19% and 13% respectively, addition of mixed contents of these nanofillers (0.5-0.5 wt%) demonstrated higher improvement (21%) in the impact resistance. The trend of the results is explained on the basis of different fracture mechanisms of nanocomposites. Furthermore, the fracture surface of specimens and the dispersion state of nanoenhancers have been studied using scanning electron microscopy (SEM) photographs.

Nonlinear forced vibration of sandwich plate with considering FG core and CNTs reinforced nano-composite face sheets

  • Rostami, Rasoul;Rahaghi, Mohsen Irani;Mohammadimehr, Mehdi
    • Smart Structures and Systems
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    • v.26 no.2
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    • pp.185-193
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    • 2020
  • Nonlinear vibration of sandwich plate with functionally graded material (FGM) core and carbon nano tubes reinforced (CNTs) nano-composite layers by considering temperature-dependent material properties are studied in this paper. Base on Classical plate theory (CPT), the governing partial differential equations of motion for sandwich plate are derived using Hamilton principle. The Galerkin procedure and multiple scales perturbation method are used to find relation between nonlinear frequency and amplitude of vibration response. The dynamic responses of the sandwich plate are also investigated in both time and frequency domains. Then, the effects of nonlinearity, excitation, power law index of FG core, volume fraction of carbon nanotube, the function of material variations of FG core, temperature changes, scale transformation parameter and damping factor on the frequency responses are investigated.

Effects of Multi-walled Carbon Nanotubes on Electrical and Wear Characteristics of High Impact Polystyrene Composites (HIPS 복합재의 전기적 및 마모 특성에 미치는 다중벽 탄소나노튜브의 영향)

  • Jeong, Yeon-Woo;Kim, Kyung-Shik;Lee, Hyun-Woo;Jeong, Man-Woo;Lee, Jae-Hyeok;Kim, Jae-Hyun;Lee, Hak-Joo;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.31 no.3
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    • pp.95-101
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    • 2015
  • Carbon nanotubes (CNTs) are widely used in polymer composites as filler materials to enhance various characteristics of the composites because of their remarkable mechanical, electrical, and thermal properties. In this study, we investigate the effects of MWCNTs on the electrical and wear characteristics of high-impact polystyrene (HIPS) composites, and compare the results with the effects of carbon black (CB). The HIPS composites are classified as Bare-HIPS, MWCNT-HIPS composites containing 2, 3, 4, and 5 wt% MWCNTs, and CB-HIPS containing 17 wt% CB. Electrical characteristics are evaluated by measuring the surface resistance using a 4-point probe. Wear characteristics are evaluated using the reciprocating wear test, and a chrome steel ball with a curvature of 6.3 mm is used as the counterpart. The results show that the addition of MWCNTs or CB can improve the electrical and wear characteristics of HIPS composites. In the case of MWCNT-HIPS composites, surface resistance, friction coefficient, and specific wear rate decrease as the concentrations of MWCNTs increase. Moreover, the addition of MWCNTs is more effective in improving the electrical and wear characteristics of HIPS composites compared to the addition of CB. To fabricate the HIPS composite with appropriate electrical and wear characteristics, more than 4 wt% MWCNTs is added to HIPS.

A new mindlin FG plate model incorporating microstructure and surface energy effects

  • Mahmoud, F.F.;Shaat, M.
    • Structural Engineering and Mechanics
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    • v.53 no.1
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    • pp.105-130
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    • 2015
  • In this paper, the classical continuum mechanics is adopted and modified to be consistent with the unique behavior of micro/nano solids. At first, some kinematical principles are discussed to illustrate the effect of the discrete nature of the microstructure of micro/nano solids. The fundamental equations and relations of the modified couple stress theory are derived to illustrate the microstructural effects on nanostructures. Moreover, the effect of the material surface energy is incorporated into the modified continuum theory. Due to the reduced coordination of the surface atoms a residual stress field, namely surface pretension, is generated in the bulk structure of the continuum. The essential kinematical and kinetically relations of nano-continuums are derived and discussed. These essential relations are used to derive a size-dependent model for Mindlin functionally graded (FG) nano-plates. An analytical solution is derived to show the feasibility of the proposed size-dependent model. A parametric study is provided to express the effect of surface parameters and the effect of the microstructure couple stress on the bending behavior of a simply supported FG nano plate.

Stability Assessment of Lead Sulfide Colloidal Quantum Dot Based Schottky Solar Cell

  • Song, Jung-Hoon;Kim, Jun-Kwan;An, Hye-Jin;Choi, Hye-Kyoung;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.413-413
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    • 2012
  • Lead sulfide (PbS) Colloidal quantum dots (CQDs) are promising material for the photovoltaic device due to its various outstanding properties such as tunable band-gap, solution processability, and infrared absorption. More importantly, PbS CQDs have large exciton Bohr radius of 20 nm due to the uniquely large dielectric constants that result in the strong quantum confinement. To exploit desirable properties in photovoltaic device, it is essential to fabricate a device exhibiting stable performance. Unfortunately, the performance of PbS NQDs based Schottky solar cell is considerably degraded according to the exposure in the air. The air-exposed degradation originates on the oxidation of interface between PbS NQDS layer and metal electrode. Therefore, it is necessary to enhance the stability of Schottky junction device by inserting a passivation layer. We investigate the effect of insertion of passivation layer on the performance of Schottky junction solar cells using PbS NQDs with band-gap of 1.3 eV. Schottky solar cell is the simple photovoltaic device with junction between semiconducting layer and metal electrode which a significant built-in-potential is established due to the workfunction difference between two materials. Although the device without passivation layer significantly degraded in several hours, considerable enhancement of stability can be obtained by inserting the very thin LiF layer (<1 nm) as a passivation layer. In this study, LiF layer is inserted between PbS NQDs layer and metal as an interface passivation layer. From the results, we can conclude that employment of very thin LiF layer is effective to enhance the stability of Schottky junction solar cells. We believe that this passivation layer is applicable not only to the PbS NQDs based solar cell, but also the various NQDs materials in order to enhance the stability of the device.

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