• Title/Summary/Keyword: Nano gas sensors

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Advancement in fabrication of sensors using nanotechnology: A bibliographic review and future research scope

  • Ujwala A. Kshirsagar;Devank C. Joshi
    • Advances in nano research
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    • v.14 no.5
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    • pp.399-407
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    • 2023
  • As Sensor plays an important part in day-to-day life. Sensors are used almost in each domain wherein humans are not able to sense or measure some parameters. Say from sensing a real-time activity of a person to sensing the tiny molecules of any gas or structures. Now sensors combined with advanced fabrication techniques with nanotechnology can be said as a game-changing combination. As the modern world is evolving every minute, the size of the components, instruments, and different equipment is shrinking rapidly. For example, the sensor or any other element which was used 10 years ago is reduced up to 5 times its original size and all of this is possible because of continuous advancement done in the manufacturing and fabrication techniques that are being used nowadays. Apart from this, it is not necessary that the term nano should only justify the size of the sensor. Nanotechnologically fabricated, refers to a sensor or any other element which may be large enough as compared to the regular one but they may be structured using some nano-particles.

Highly Sensitive MEMS-Type Micro Sensor for Hydrogen Gas Detection by Modifying the Surface Morphology of Pd Catalytic Metal (Pd 촉매금속의 표면형상 변형에 의한 고감도 MEMS 형 마이크로 수소가스 센서 제조공정)

  • Kim, Jung-Sik;Kim, Bum-Joon
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.532-537
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    • 2014
  • In this study, highly sensitive hydrogen micro gas sensors of the multi-layer and micro-heater type were designed and fabricated using the micro electro mechanical system (MEMS) process and palladium catalytic metal. The dimensions of the fabricated hydrogen gas sensor were about $5mm{\times}4mm$ and the sensing layer of palladium metal was deposited in the middle of the device. The sensing palladium films were modified to be nano-honeycomb and nano-hemisphere structures using an anodic aluminum oxide (AAO) template and nano-sized polystyrene beads, respectively. The sensitivities (Rs), which are the ratio of the relative resistance were significantly improved and reached levels of 0.783% and 1.045 % with 2,000 ppm H2 at $70^{\circ}C$ for nano-honeycomb and nano-hemisphere structured Pd films, respectively, on the other hand, the sensitivity was 0.638% for the plain Pd thin film. The improvement of sensitivities for the nano-honeycomb and nano-hemisphere structured Pd films with respect to the plain Pd-thin film was thought to be due to the nanoporous surface topographies of AAO and nano-sized polystyrene beads.

Catalytic combustion type hydrogen micro gas sensor using thin film heater and nano crystalline SnO2 (나노 결정 SnO2와 백금 박막히터를 이용한 접촉연소식 마이크로 가스센서의 감응특성 연구)

  • Han, Sang-Do;Hong, Dae-Ung;Han, Chi-Hwan;Chun, Il-Soo
    • Journal of Sensor Science and Technology
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    • v.17 no.3
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    • pp.178-182
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    • 2008
  • Planar type micro catalytic combustible gas sensor was developed by using nano crystalline $SnO_2$ Pt thin film as micro heater was deposited by thermal evaporation method on the alumina substrate. The thickness of the Pt heater was around 160 nm. The sensor showed high reliability with prominent selectivity against various gases(Co, $C_3H_8,\;CH_4$) at low operating temperature($156^{\circ}C$). The sensor with nano crystalline $SnO_2$ showed higher sensitivity than that without nano crystalline $SnO_2$. This can be explained by more active adsorption and oxidation of hydrogen by nano crystalline $SnO_2$ particles. The present planar-type catalytic combustible hydrogen sensor with nano crystalline $SnO_2$ is a good candidate for detection of hydrogen leaks.

NO Gas Sensing Properties of ZnO-Carbon Nanotube Composites (산화아연-탄소나노튜브 복합체의 일산화질소 가스 감지 특성)

  • Park, Seong-Yong;Jung, Hoon-Chul;Ahn, Eun-Seong;Nguyen, Le Hung;Kang, Youn-Jin;Kim, Hyo-Jin;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.18 no.12
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    • pp.655-659
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    • 2008
  • The NO gas sensing properties of ZnO-carbon nanotube (ZnO-CNT) composites fabricated by the coaxial coating of single-walled CNTs with ZnO were investigated using pulsed laser deposition. Upon examination, the morphology and crystallinity of the ZnO-CNT composites showed that CNTs were uniformly coated with polycrystalline ZnO with a grain size as small as 5-10 nm. Gas sensing measurements clearly indicated a remarkable enhancement of the sensitivity of ZnO-CNT composites for NO gas compared to that of ZnO films while maintaining the strong sensing stability of the composites, properties that CNT-based sensing materials do not have. The enhanced gas sensing properties of the ZnO-CNT composites are attributed to an increase in the surface adsorption area of the ZnO layer via the coating by CNTs of a high surface-to-volume ratio structure. These results suggest that the ZnO-CNT composite is a promising template for novel solid-state semiconducting gas sensors.

Micro toluene gas sensor of SWNTs-PtOx system using the vacuum filtering deposition method (진공여과증착법을 이용한 SWNT-PtOx계 마이크로 톨루엔 가스센서)

  • Kim, Il-Jin;Jeon, Young-Zip;Choi, Chang-Kyu;Lee, Young-Uk;Choi, Si-Young;Han, Chang-Soo;Han, Sang-Do
    • Journal of Sensor Science and Technology
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    • v.18 no.2
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    • pp.179-183
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    • 2009
  • Toluene($C_6H_5CH_3$) gas sensors were fabricated using $PtO_x$ loaded with SWNTs by a new deposition method. The nanoparticle powders of SWNTs-$PtO_x$ composite were deposited on Si wafer substrates by a vacuum filtering deposition method. The fabricated sensors were tested against toluene gas which is a kind of the Volatile Organic Compounds. The composition ratio that exhibited the highest response to toluene gases was SWNTs : $PtO_x\;=\;99:1$ in wt% ratio at operating temperature of about $150^{\circ}C$. The response and recovery times of the sensors were as short as less than 1 min., respectively.

Effect of Crystal Structures on the Sensing Properties of Nanophase $SnO_2$ Gas Sensor (나노상 $SnO_2$ 가스센서에서 센서검지특성에 미치는 결정구조의 영향)

  • 안재평;김선호;박종구;허무영
    • Journal of Powder Materials
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    • v.8 no.2
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    • pp.98-103
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    • 2001
  • Metallic tin powder with diameter less than 50 nm was synthesized by inert gas condensation method and subsequently oxidized to tin oxide ($SnO_2$) along the two heat-treatment routes. The $SnO_2$ powder of single phase with a tetragonal structure was obtained by the heat-treatment route with intermediate annealing step-wise oxidation, whereas the $SnO_2$ powder with mixture of orthorhombic and tetragonal phases was obtained by the heat-treatment route without intermediate annealing (direct oxidation). $SnO_2$ gas sensors fabricated from the nano-phase $SnO_2$ powders were investigated by structural observations as well as measurement of electrical resistance. The $SnO_2$ gas sensors fabricated from the mixed-phase powder exhibited much lower sensitivity against $H_2$ gas than those fabricated from the powder of tetragonal phase. Reduced sensitivity of gas sensors with the new orthorhombic phase was attributed to detrimental effects of phase boundaries between orthorhombic and tetragonal phases and many twin boundaries on the charge mobility.

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Effects of Pd Nanoparticles on Single-Walled Carbon Nanotubes as High-Sensitivity Hydrogen Gas Sensors (덴드리머와 팔라듐 나노입자를 이용한 단일벽 탄소나노튜브 고성능수소센서)

  • Lee, Jun Min;Ju, Seonghwa;Joe, Jin Hyoun;Kim, Sung-Jin;Lee, Wooyoung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.342-346
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    • 2010
  • Pd nanoparticles (NPs) were successfully functionalizedon the surfaces of single-walled carbon nanotubes (SWNTs) by dendrimer-mediated synthesis. The hydrogen sensing properties of the Pd NPs functionalized SWNTs were investigated. Pd NPs-dendrimer-SWNTs sensors show much better speedsand superior recovery rates but lower sensitivity compared to Pd NPs-functionalized SWNTs directly fabricated due to the existence of dendrimers. Pyrolysis of the dendrimers by heat treatment resulted in a fast response time and high sensitivity owing to the reduced length of the dendrimers. These results demonstrate that the heat treatment of dendrimers in Pd NPs-dendrimer-SWNTs sensors can enable significant electrical conductance modulation upon exposure to extremely low concentrations (10 ppm) of hydrogen gas ($H_2$) in air.

A Dual Micro Gas Sensor Array with Nano Sized $SnO_2$ Thin Film (나노 박막을 이용한 듀얼 $SnO_2$ 마이크로 가스센서 어레이)

  • Chung Wan-Young
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.10 no.9
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    • pp.1641-1647
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    • 2006
  • A dual micro gas sensor way for detecting reducing gas and bad order was fabricated using nano sized $SnO_2$ thin film fabrication method. To make nano-sized thin gas sensitive $SnO_2$ thin rilm, thin tin metal layer $2500{\AA}$ thick was oxidized between 600 and $800^{\circ}C$ by thermal oxidation. The gas sensing layers such as $SnO_2,\;SnO_2(+Pt)\;and\;SnO_2(+CuO)$ were patterned by metal shadow mask for simple fabrication process on the silicon substrate. The micro gas sensors with $SnO_2(Pt)$ and $SnO_2(+CuO)$ showed good selectivity to CO gas among reducing gases and good sensitivity to $H_2S$ that is main component of bad odor, separately.

The Fabrication and $NO_X$-sensing characteristics of $WO_3$-based semiconductor gas sensor for detecting sub-ppm level of $NO_X$ (초미량의 이산화질소가스 감지를 위한 텅스텐산화물계 반도체 가스 센서의 제조 및 $NO_X$ 감응 특성)

  • 이대식;임준우
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.601-604
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    • 1998
  • NOX detecting gas sensors using TiO2 doped tungsten oxide semiconductor were prepared and their electrical and sensing characteristics have been investigated. In normal air condition, the sensors of WO3, TiO2 doped WO3 show grain boundary heights of 0.34 eV, 0.25 eV, respectively. The grain boundary barrier energy variation was increased by doping TiO2 into large variation of resistance to NOX gases. And doping the TiO2 4 wt.%, the particle size of WO3 polycrystal films showed higher sensitivity and better sorption characteristics to NOX gas than the pure WO3 films material in air at operating temperature of $350^{\circ}C.$ The TiO2 doped WO3 semiconductor gas sensor shows nano-sized particle size and good sensitivity to sub-ppm concentration of NOX.

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Fabrication of a Superhydrophobic Water-Repellent Mesh for Underwater Sensors

  • An, Taechang
    • Journal of Sensor Science and Technology
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    • v.22 no.2
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    • pp.100-104
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    • 2013
  • A superhydrophobic mesh is a unique structure that blocks water, while allowing gases, sound waves, and energy to pass through the holes in the mesh. This mesh is used in various devices, such as gas- and energy-permeable waterproof membranes for underwater sensors and electronic devices. However, it is difficult to fabricate micro- and nano-structures on three-dimensional surfaces, such as the cylindrical surface of a wire mesh. In this research, we successfully produced a superhydrophobic water-repellent mesh with a high contact angle (> $150^{\circ}$) for nanofibrous structures. Conducting polymer (CP) composite nanofibers were evenly coated on a stainless steel mesh surface, to create a superhydrophobic mesh with a pore size of $100{\mu}m$. The nanofiber structure could be controlled by the deposition time. As the deposition time increased, a high-density, hierarchical nanofiber structure was deposited on the mesh. The mesh surface was then coated with Teflon, to reduce the surface energy. The fabricated mesh had a static water contact angle of $163^{\circ}$, and a water-pressure resistance of 1.92 kPa.