• Membrane and Water Treatment
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• v.9 no.5
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• pp.335-342
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• 2018

Micelle-Enhanced Ultrafiltration (MEUF) is a membrane separation processes that improving ultrafiltration process with the formation of micelles of the surface active agents. Surface active agents are widely used to improve membrane processes due to the ability to trap organic compounds and metals in the treatment of industrial waste water. In this study, surface active agents are used to improve micelle-enhanced ultrafiltration (MEUF) to reduce chemical oxygen demand (COD), total dissolved solid (TDS), turbidity and clogging the membrane in dairy wastewater treatment. Three important operational factors (anionic surface active agent concentration, pressure and pH) and these interactions were investigated by using response surface methodology (RSM) and Box-Behnken design. Results show that due to the concentration polarization layer and increase the number of Micelles; the anionic surface active agent concentration has a negative effect on the flux and has a positive effect on the elimination of contamination indices. pH, and the pressure have the greatest effect on flux. On the other hand, it could be stated that these percentages of separation are in the percentages range of Nano-filtration (NF). While MEUF process has higher flux than NF process. The results have been achieved at lower pressure while NF process needs high pressure, thus making MEUF is the replacement for the NF process.

• Journal of the Korean Geosynthetics Society
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• v.5 no.3
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• pp.31-36
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• 2006

In this study, stress relaxation behaviors of nonwoven geotextile and geomembrane which have protection, filtration and drainage, water barrier functions, respectively were examined. 'Theory of transition phenomen' was applied to interpretate the stress relaxation behaviors of two geosynthetics. The initial and later relaxation times for stress relaxation behaviors of geosynthetics were derived from the constitutive equations. The initial relaxation behaviors of these geosynthetics were dependent on the additional strains and were especially faster with temperature. Finally, both relaxation times of geosynthetics were shorter with additional strain and temperature and the reduction of relaxation times of nonwoven geotextile were larger than those of geomembrane.

• Membrane and Water Treatment
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• v.1 no.3
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• pp.193-206
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• 2010

Organic fouling and biofouling pose a significant challenge to the membrane filtration process. Photocatalysis-membrane hybrid system is a novel idea for reducing these membranes fouling however, when $TiO_2 photocatalyst nanoparticles are used in suspension, catalyst recovery is not only imposes an extra step on the process but also significantly contributes to increased membrane resistance and reduced permeate flux. In this study, $TiO_2$ photocatalyst has been immobilized by coating on the microfiltration (MF) membrane surface to minimize organic and microbial fouling. Nano-sized $TiO_2$ was first synthesized by a sol-gel method. The synthesized $TiO_2$ was coated on a Poly Vinyl Difluoride (PVDF) membrane (MF) surface using spray coating and dip coating techniques to obtain hybrid functional composite membrane. The characteristics of the synthesized photocatalyst and a functional composite membrane were studied using numerous instruments in terms of physical, chemical and electrical properties. In comparison to the clean PVDF membrane, the $TiO_2$ coated MF membrane was found more effective in removing methylene blue (20%) and E-coli (99%).

• Membrane and Water Treatment
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• v.11 no.5
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• pp.333-344
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• 2020

Advances in industrial development and waste management over several decades have reduced many of the impacts that previously affected ecosystems, however, there are still processes which discharge hazardous materials into environments. Among industries that produce industrial wastewaters, textile manufacturing processes play a noticeable role. This study was conducted to test a novel continuous combined commercial membrane treatment using polyvinylidene fluoride (PVDF), ultrafiltration (UF), and polyamide (PA) nanofiltration (NF) membranes for textile wastewater treatment. The synthetic textile wastewater used in this study contained sodium silicate, wax, and five various reactive dyes. The results indicate that the removal efficiency for physical particles (wax and resin) was 95% through the UF membrane under optimum conditions. Applying UF and NF hybrid treatment resulted in total effective removal of dye from all synthetic samples. The efficiency of sodium silicate removal was measured to be between 2.5 to 4.5% and 13 to 16% for UF and NF, respectively. The chemical oxygen demand in all samples was reduced by more than 85% after treatment by NF.

• International Journal of Advanced Culture Technology
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• v.5 no.1
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• pp.64-69
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• 2017

The rapid growth of algae occurs can induce the algae bloom when nutrients are supplied from anthropogenic sources such as fertilizer, animal waste or sewage in runoff the water currents or upwelling naturally. The algae blooms creates the human health problem in the environment as well as in the water resource managers including hypoxic dead zones and harmful toxins and pose challenges to water treatment systems. The algal blooms in the source water in water treatment systems affects the drinking water taste & odor while clogging or damaging filtration systems and putting a strain on the systems designed to remove algal toxins from the source water. This paper propose the emerging In-Situ self-diagnosable smart algae sensing device with wireless connectivity for smart remote monitoring and control. In this research, we developed the In-Site Algae diagnosable sensing device with wireless sensor network (WSN) connectivity with Optical Biological Sensor and environmental sensor to monitor the water treatment systems. The proposed system emulated in real-time on the water treatment plant and functional evaluation parameters are presented as part of the conceptual proof to the proposed research.

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1445-1453
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• 2013

$Zn_{(1-x)}Ni_xAl_2O_4$ (x = 0.0-1.0) spinels were prepared at $800^{\circ}C$ by co-precipitation method and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The specific surface area was determined by BET. SEM image showed nano sized spherical particles. XPS confirmed the valence states of the metals, showing moderate Lewis character for the surface of materials. The powders were successfully used as new heterogeneous catalysts of Biginelli's reaction, a one-pot three-component reaction, leading to some dihydropyrimidinones (DHPMs). These new catalysts that produced good yields of DHPMs, were easily recovered by simple filtration and subsequently reused with persistent activity, and they are non-toxic and environmentally friendly. The optimum amount of catalyst is 20% by weight of benzaldehyde derivatives, while the doping amount has been found optimal for x = 0.1.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.3
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• pp.219-222
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• 2019

In this study, we fabricated plate-type shunt resistors with thermal stability by parallelly connecting metal alloy plates with positive temperature coefficient of resistance (TCR) and carbon nanotube (CNT) plates with negative TCR. The metal alloy plates, which were prepared by alloying Cu and Mn with a composition of 91 wt% of Cu and 9 wt% of Mn, showed around $800ppm/^{\circ}C$ of TCR, and the CNT plates prepared from the CNT solution by using the vacuum filtration method showed around $-800ppm/^{\circ}C$ of TCR. The shunt resistor that was fabricated by stacking metal alloy plates and CNT plates in this work showed about $46.93ppm/^{\circ}C$ of TCR. Therefore, we conclude that a shunt resistor with low TCR can be realized by simply adjusting the TCR of the metal alloy only, because the TCR of the CNT plate has an identical value.

• Membrane and Water Treatment
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• v.10 no.4
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• pp.259-264
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• 2019

Cost effective clay adsorptive microfiltration membranes were synthesized to remove Cr (III) from high polluted water. Raw and calcined bentonite were mixed in order to decrease the shrinkage and also increase the porosity; then, 20 wt% of carbonate was added and the samples, named B (without carbonate) and B-Ca20 (with 20 wt% calcium carbonate) were uniaxially pressed and after sufficient drying, fired at $1100^{\circ}C$ for 3 hours. Then, physical and mechanical properties of the samples, their phase analyses and microstructure and also their ability for Cr(III) removal from high polluted water (including 1000 ppm Cr (III) ions) were studied. Results showed that the addition of calcium carbonate lead the porosity to increase to 33.5% while contrary to organic pore formers like starch, due to the formation of wollastonite, the mechanical strength not only didn't collapse but also improved to 36.77 MPa. Besides, sample B-Ca20, due to the presence of wollastonite and anorthite, could remove 99.97% of Cr (III) ions. Hence, a very economic and cost effective combination of membrane filtration and adsorption technology was achieved for water treatment which made microfiltration membranes act even better than nanofiltration ones without using any adsorptive nano particles.

• Membrane and Water Treatment
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• v.13 no.6
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• pp.313-320
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• 2022

Theoretical calculation results are presented for the enhancement of the water mass flow rate through the hydrophobic micro/nano pores in the membrane respectively on the micrometer and nanometer scales. The water-pore wall interfacial slippage is considered. When the pore diameter is critically low (less than 1.82nm), the water flow in the nanopore is non-continuum and described by the nanoscale flow equation; Otherwise, the water flow is essentially multiscale consisting of both the adsorbed boundary layer flow and the intermediate continuum water flow, and it is described by the multiscale flow equation. For no wall slippage, the calculated water flow rate through the pore is very close to the classical hydrodynamic theory calculation if the pore diameter (d) is larger than 1.0nm, however it is considerably smaller than the conventional calculation if d is less than 1.0nm because of the non-continuum effect of the water film. When the driving power loss on the pore is larger than the critical value, the wall slippage occurs, and it results in the different scales of the enhancement of the water flow rate through the pore which are strongly dependent on both the pore diameter and the driving power loss on the pore. Both the pressure drop and the critical power loss on the pore for starting the wall slippage are also strongly dependent on the pore diameter.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.9
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• pp.636-642
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• 2013

In order to overcome drawbacks (i.e., filtration and recovery) of conventional powder type photocatalysts, nano-ZnO/Laponite/PVA (ZLP) photocatalyzed adsorption balls were developed by using in situ mixing of nanoscale ZnO as a photocatalyst, and Laponite as both adsorbent and supporting media in deionized water, followed by the poly vinyl alcohol polymerization with boric acid. The optimum mixing ratio of nano-ZnO:Laponite:PVA:deionized water was found to be 3:1:1:16 (by weight), and the mesh and film produced by PVA polymerization with boric acid might inhibit both swelling of Laponite and detachment of nanoscale ZnO from ZLP balls. Drying ZLP balls with microwave (600 watt) was found to produce ZLP balls with stable structure in water, and various sizes (55~500 ${\mu}m$) of pore were found to be distributed based on SEM and TEM results. In the initial period of reaction (i. e., 40 min), adsorption through ionic interaction between methylene blue and Laponite was the main removal mechanism. After the saturation of methylene blue to available adsorption sites for Laponite, the photocatalytic degradation of methylene blue occurred. The effective removal of methylene blue was attributed to adsorption and photocatalytic degradation. Based on the results from this study, synthesized ZLP photocatalyzed adsorption balls were expected to remove recalcitrant organic compounds effectively through both adsorption and photocatalytic degradation, and the risks of environmental receptors caused by detachment of nanoscale photocatalysts can be reduced.