• Title/Summary/Keyword: NaTPB

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Precipitation behaviors of Cs and Re(/Tc) by NaTPB and TPPCl from a simulated fission products-$(Na_2CO_3-NaHCO_3)-H_2O_2$ solution (모의 FP-$(Na_2CO_3-NaHCO_3)-H_2O_2$ 용액으로부터 NaTPB 및 TPPCl에 의한 Cs 및 Re(/Tc)의 침전 거동)

  • Lee, Eil-Hee;Lim, Jae-Gwan;Chung, Dong-Yong;Yang, Han-Beum;Kim, Kwang-Wook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.2
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    • pp.115-122
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    • 2010
  • In this study, the removal of Cs and Tc from a simulated fission products (FP) solution which were co-dissolved with U during the oxidative-dissolution of spent fuel in a mixed carbonate solution of $(Na_2CO_3-NaHCO_3)-H_2O_2$ was investigated by using a selective precipitation method. As Cs and Tc might cause an unstable behavior due to the high decay heat emission of Cs as well as the fast migration of Tc when disposed of underground, it is one of the important issues to removal them in views of the increase of disposal safety. The precipitation of Cs and Re (as a surrogate for Tc) was examined by introducing sodium tetraphenylborate (NaTPB) and tetraphenylphosponium chloride (TPPCl), respectively. Precipitation of Cs by NaTPB and that of Re by TPPCl were completed within 5 minutes. Their precipitation rates were not influenced so much by the temperature and stirring speed even if they were increased by up to $50^{\circ}C$ and 1,000 rpm. However, the pH of the solution was found to have a great influence on the precipitation with NaTPB and TPPCl. Since Mo tends to co-precipitate with Re at a lower pH, especially, it was effective that a selective precipitation of Re by TPPCl was carried out at pH of above 9 without co-precipitation of Mo and Re. Over 99% of Cs was precipitated when the ratio of [NaTPB]/[Cs]>1 and more than 99% of Re, likewise, was precipitated when the ratio of [TPPCl]/[Re]>1.

A hydrogen ion-selective membrane electrode based on N,N,N,N-Tetrabenzylethylenediamine as neutral carrier (N,N,N,N-Tetrabenzylethylenediamine 중성운반체를 이용한 수소 이온 선택성 막전극)

  • Jeong, Seong-Suk;Park, Myon-Yong;Chung, Koo-Chun;Cho, Dong-Hoe;Lee, Kyeong-Jae;Kim, Jae-Woo
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.187-193
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    • 1995
  • A PVC membrane ion-selective electrodes based on N,N,N,N-tetrabenzylethylenediamine as neutral carrier has been prepared by addition of plasticizers such as phthalates and sebacate and liphophillic additives such as NaTPB. The membrane electrodes were investigated to the electric resistance, response range to hydrogen ion and the interfering effect of alkali and alkline earth metals. A electric resistance hardly had on effect of plasticizers. In case of 0.7% NaTPB added to membrane, response of the electrodes were shown the values near to theoretical Nernstian slope and interferences by alkali and alkaline earth metal were few influenced. The performances of pH-selective electrodes were shown linerality to hydrogen ion between pH 2 and 10 in the presense of alkali and alkaline earth ions. Reproducibility and stability tests were shown good results in the same pH range.

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Development and Evaluation of Dietary Education Program Focused on Slow Life in School Children (슬로라이프를 기반으로 한 식생활교육 프로그램의 개발과 효과성 검증)

  • Lee, Hyowon;Na, Yeseul;Cho, Mi Sook
    • Journal of the Korean Society of Food Culture
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    • v.31 no.2
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    • pp.111-120
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    • 2016
  • The aim of this study was to develop a Dietary Education Program focused on Slow Life (DEPSL) and verified its effectiveness in elementary school children using the extended Theory of Planned Behavior (TPB). The DEPSL was developed effectively according to the systematic program development model, ADDIE. The developed DEPSL was applied to the Education group (EDU), which was total of 130 students aged 12-13 in an elementary school by trained instructors for five weeks. The control group (CON) composed of 100 students of the same age was not given any dietary education. Pre- and post- questionnaires were collected from the students in both groups to compare the change in students' dietary life during educational intervention between EDU and CON. EDU showed significant positive effects in all extended TPB variables (p< .01), but CON showed a significant difference only in the 'knowledge' and 'behavior intention' (p< .05). In addition, the extended TPB model verified its conformity to determine if the effect of education leads to a change in the children's behavior. In conclusion, the DEPSL has a positive impacts on dietary life in school children. Nevertheless, further research will be needed to develop various and specialized dietary education programs with different level of grades in other school areas.

Factors Affecting Practice of COVID-19 Infection Preventive Behaviors in University Students: The Use of the Extended Health Belief Model (HBM) and Theory of Planned Behavior (TPB) (대학생의 코로나19 감염예방행위에 영향을 미치는 요인: 확장된 건강신념모델과 계획된 행위이론의 적용)

  • Na Yeong Seok;Chi Yang Yoon;Mi Suk Lee;Mi Yang Jeon
    • Journal of the Korean Society of School Health
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    • v.36 no.1
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    • pp.9-19
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    • 2023
  • Purpose: The purpose of the study was to identify the factors affecting the practice of COVID-19 infection preventive behaviors in university students focusing on the extended health beliefs model (HBM) and the theory of planned behavior (TPB). Methods: Data was collected from November 1, 2021 to November 30, 2021. The participants were 180 university students at 3 universities. The data was analyzed through the independent t-test, one-way ANOVA, Scheffé test, Pearson's correlation coefficient, and multiple regression by using SPSS/WIN 24.0. Results: In the first stage of hierarchical regression analysis, it was shown that perceived barrier and self-efficacy, among the HBM variables, were significant factors, explaining 18.4% of the infection preventive behaviors (F=7.73, p<.001). In the 2nd stage, it was shown that self-efficacy, among the TPB variables, was a significant factor, explaining 15.3% of the infection preventive behaviors (F=11.80, p<.001). In the 3rd stage, it was shown that perceived barrier and self-efficacy, among the HBM and TPB variables, were significant factors, explaining 18.5% of the infection preventive behaviors (F=6.08, p<.001). Conclusion: When an effective infection preventive behavior program is developed and provided for students to improve their self-efficacy and reduce perceived barrier based on the results, it will contribute to the improvement of infection prevention behaviors among university students.

A Study on the Purchase Intention of Ginseng Products based on the theory of Perceived Value and TPB (인지가치와 계획행위 이론에 기초한 인삼제품 구매의지 연구)

  • Bai, Xiu-Na;Jung, Gi-Young;Kim, Hyung-Ho
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.35-42
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    • 2019
  • The purpose of this study is to make an empirical analysis of the influencing factors of consumer purchase intention of ginseng products, one of the specialties of jilin province in china, on the basis of expanding the theoretical model of planned action at the level of perceived value, so as to better grasp consumer purchase behavior of ginseng products. In this study, a questionnaire survey was conducted among ginseng product consumers living in jilin, and 360 valid samples were statistically analyzed using SPSS 23.0.The analysis results show that behavioral attitude, subjective norms, cognitive behavior control, price value, emotional value and social value have considerable influence on consumers' intention to buy ginseng products, and the influence of perceived value is significantly greater than the three factors of planned action theory. Moreover, the functional value has little influence on consumers' intention to buy ginseng products.

Comparison of Laptop Computer Purchasing Intentions with Different Customer Segments (라이프스타일에 따른 소비자 그룹의 노트북컴퓨터 구매의도 비교연구)

  • Han, You-Na;Shin, Young-Geun;Park, Sang-Sung;Jang, Dong-Sik
    • The Journal of the Korea Contents Association
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    • v.9 no.6
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    • pp.134-144
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    • 2009
  • The purpose of this study was to verify the relationship of laptop purchasing behaviors based of Theory of Planned Behavior. The data collected from the 240 experience to that who used laptop computer, but was analyzed. With the collected data, factor analysis, K-Means analysis, correlation analysis, crosstabs analysis, and structural equation model analysis was performed by SPSSWIN 15.0 and AMOS 7.0. Factor and cluster analyses were used to segment the sample into four clusters. After analyzing the results, various relationships between attitudes, subjective norms, perceived behavioral control, behavioral intention were determined for the different groups.

A Study on the Effect of copyright Publicity on copyright protection intention (저작권 홍보가 저작권 보호 의도에 미치는 영향에 관한 연구)

  • Lee, Bo-Na;Gim, Gwang-Yong
    • 한국IT서비스학회:학술대회논문집
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    • 2009.05a
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    • pp.209-212
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    • 2009
  • 본 연구는 저작권 보호를 위한 홍보를 본 수용자들의 저작권에 관한 인지도와 저작권 침해가 줄어드는 효과가 있는지 알아보는데 목적이 있다. 최근 인터넷의 일상화에 따른 온라인에서의 저작권자와 수용자들 간에 법적 공방이 잦아지고 있고, 디지털 상품의 유통의 경로가 확대되고 있다. 이는 국내 뿐 만아니라 국외에서도 마찬가지로 저작권에 관하여 많은 사회적 이슈가 되고 있다. 이에 따라 저작권 보호를 위한 캠페인과 광고를 각종 매체에서 다양한 형태로 홍보를 하고 있다. 하지만 현실상 수용자들은 저작권 침해를 빈번하게 하고 있으며, 저작권법에 대하여 무지한 상태에서 저작권법 위반으로 고소되는 경우가 생겨나고, 강력해진 법적조치에 따른 반감을 사고 있다. 이에 관하여 저작권 보호를 위한 홍보의 현황을 알아보고, 계획적 행동이론(TPB)에 적용하여 저작권 보호를 위한 홍보가 저작권 보호 의도에 미치는 영향을 알아보고, 홍보 매체에 따른 차이가 있는지 알아본다.

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Evaluation of Na2CO3-H2O2 Carbonate Solution Stability (Na2CO3-H2O2 탄산염 용액의 안정성 평가)

  • Lee, Eil-Hee;Lim, Jae-Gwan;Chung, Dong-Yong;Yang, Han-Beum;Kim, Kwang-Wook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.3
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    • pp.131-139
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    • 2011
  • This study was carried out to examine the stability of $Na_2CO_3-H_2O_2$ carbonate solution with aging time in the dissolving solution after oxidative dissolution of U by a carbonate solution, the Cs/Re filtrate after selective precipitation of Cs and Re (as a surrogate for Tc), and the acidification filtrate after precipitation of U by acidification, respectively. The compositions of dissolving solution were not changed with ageing time, and the selective precipitation of Re and Cs was also not affected without regard to the aging time of dissolving solution. The successive removal of Cs and Re from a carbonate dissolving solution was possible. However, the recovery yield of U by acidification was decreased with increasing the aging time of the dissolving solution and the Cs/Re-filtrate, respectively, because U was converted from the uranyl peroxocarbonato complex to the uranyltricarbonate in the solution aged for a long time. Accordingly, it is effective that a dissolving solution and a Cs/Re filtrate are treated within the aging of 7 days, respectively, in order to recover U more than 99%. On the other hand, the recovery of U was carried out in order of the oxidative dissolution of U selective precipitation of Re and Cs precipitation of U by acidification. Almost all of U and a part of FP were co-dissolved in oxidative dissolution step. Over 99% of Re and Cs from the FP co-dissolved with U could be removed by a TPPCl (tetraphenylphosphonium chloride) and a NaTPB (sodium tetraphenylborate), respectively. U was precipitated nearly 100% by acidification to pH 4. Therefore, it was confirmed that the validity of recovery of U by precipitation methods from a SF (spent fuel) in the $Na_2CO_3-H_2O_2$ solution.