• Title/Summary/Keyword: NaCl resistance

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Growth Behavior and Corrosion Damage of Oxide Film According to Anodizing Time of Aluminum 1050 Alloy (알루미늄 1050 합금의 양극산화 시간에 따른 산화피막 성장 거동 및 부식 손상 연구)

  • Choi, Yeji;Jeong, Chanyoung
    • Corrosion Science and Technology
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    • v.21 no.4
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    • pp.282-289
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    • 2022
  • Aluminum 1000 series alloy, a pure aluminum with excellent workability and weldability, is mainly used in the ship field. Aluminum alloy can combine with oxygen in the atmosphere and form a natural oxide film with high corrosion resistance. However, its corrosion resistance and durability are decreased when it is exposed to a harsh environment for a long period of time. For solving this problem, a porous oxide film can be formed on the surface using an anodizing treatment method, a typical surface technique among various methods. In this study, aluminum 1050 alloy was anodized for 2 minutes, 6 minutes, and 10 minutes. The structure and shape of the oxide film were then analyzed to determine the corrosion resistance according to the thickness of the oxide film that changed depending on working condition using 15 wt% NaCl. After it was immersed in NaCl solution for 1, 5, and 10 days, corrosion damage was observed. Results confirmed that the thickness of the oxide film increased as the anodization time became longer. The depth of surface damage due to corrosion became deeper when the film was immersed in the 15 wt% NaCl solution for a longer period of time.

Evaluation of the Deicing Performance and Concrete Structure Effect with Various Deicing Chemicals (제설제 종류에 따른 융빙성능 및 콘크리트에 미치는 영향 평가에 관한 연구)

  • Lee, Byung-Duck;Yun, Byung-Sung;Lee, Joo-Kwang;Chung, Young-Hwan
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.113-123
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    • 2005
  • In this study, calcium chloride$(CaCl_2)$, sodium chloride (NaCl), organic acids-containing deicer(NS 40, NS 100), mixed deicier$(NaCl\;70%+CaCl_2\;30%,\;NS\;40\;70%+CaCl_2\;30%,\;NaCl\;70%+NS\;40\;30%,\;NS\;40\;70%+NaCl\;30%)$ is investigated based on the laboratory test for deicing performance, freez-thaw resistance of concrete, and corrosion rate of metal. Test items for deicing performance were ice melting and ice penetration, freezing point depressions and eutectic point, pH, thermal properties for selected deicing chemicals as well as their compatibility with concrete and metal were experimentally investigated. As a test results, in case of the use chloride-containing deicier in area that concrete structures has subjected to freez-thaw reaction in winter season, it showed that mixed deicing chemicals with optimum ratio has desirable method than use one deicing chemicals when is consider to deicing performance and effects, corrosion of steel materials, and freez-thaw resistance of concrete. When use various deicing chemicals mixed, NS40(70%)+calcium chloride(30%) showed the best effective method.

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Effect of Glucose on Listeria monocytogenes Survival under Sequential Sublethal Stresses of Gamma Irradiation and NaCl

  • Yoon, Yo-Han;Kim, Gyeong-Yeol;Nam, Min-Ji;Shim, Won-Bo;Seo, Eun-Kyoung;Kim, Jae-Hun;Lee, Ju-Woon;Byun, Myung-Woo;Chung, Duck-Hwa
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.162-166
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    • 2009
  • This study evaluated glucose effect on Listeria monocytogenes survival under gamma irradiation and NaCl stress. L. monocytogenes in phosphate buffered saline (PBS) plus glucose (0-4%) was treated with gamma irradiation (0-0.5 kGy), and the samples were then exposed to NaCl (0-9%) in tryptic soy agar plus 0.6% yeast extract. $D_{10}$ and $t_{3D}$ values were determined, and a model for prediction of $D_{10}$ values was developed. Cell counts of L. monocytogenes reduced as irradiation dose increased, and L. monocytogenes in PBS (no glucose) was more sensitive to irradiation and NaCl compared to those in PBS (2 or 4% glucose). $D_{10}$ values were 0.07-0.1, 0.12-0.16, and 0.13-0.15 kGy for 0, 2, and 4% glucose, respectively. The $t_{3D}$ values were 0.22-0.3 (0% glucose), 0.35-0.48 (2% glucose), and 0.40-0.44 (4% glucose). A model performance was acceptable. These results indicate that glucose in foods would increase the resistance of L. monocytogenes to gamma irradiation and NaCl stress.

Effect of Synthetic Hydrotalcite on Salt Water Resistance of Chloroprene rubber Foam (Synthetic Hydrotalcite가 클로로프렌 고무 발포체의 내염수성에 미치는 영향 연구)

  • Park, Eun Young;Seo, Eun Ho;Lim, Sung Wook
    • Textile Coloration and Finishing
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    • v.31 no.3
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    • pp.177-186
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    • 2019
  • In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

Corrosion of Fe-Cr Steels at 600-800℃ in NaCl Salts

  • Lee, Dong Bok;Kim, Min Jung;Yadav, Poonam;Xiao, Xiao
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.354-359
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    • 2018
  • NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.

Bond Strength and Corrosion Resistance of Coated Reinforcing Bar Using Hybrid-Type Polymer Cement Slurry (Hybrid형 폴리머 시멘트 슬러리로 도장한 철근의 부착강도와 부식저항성)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.93-99
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    • 2008
  • The purpose of this study is to evaluate the bond strength and corrosion resistance of coated reinforcing bar using hybrid-type polymer cement slurry(PCS). PCS coated steels, which is made from two types of polymer dispersions such as St/BA and EVA are prepared, and tested for bond strength and various corrosion resistances such as autoclaved cure, carbonation and H2SO4 solution. From the test results, the bond strength of PCS coated reinforcing bar using ordinary portland cement at 1-5, 2-1 and 4-5 of mixes is higher than that of uncoated regular steel. However, bond strength of almost PCS coated reinforcing bars using ultra rapid high strength cement is higher than that of epoxy coated bar, is also in ranges of 102% to 123% compared to that of uncoated regular steel. In autoclaved accelerating test, the ratio of corrosion of uncoated regular steel is increased with the increase in NaCl content, but the corrosion of PCS coated steel was very small. In the acceleration test for carbonation, increasing the amount of NaCl the corrosion of coated steel did not produce. The corrosion of uncoated regular steel is increased with the increase in the amount of NaCl. It can be seen that the NaCl following the acceleration test for carbonation can lower the corrosion resistance of concrete. As a result, the corrosion of steel largely is affected by the acceleration curing, chloride ion penetration and carbonation and shown more severe corrosion by applying complex factors. These corrosions of steel can be suppressed by the coating of PCS.

Effect of Chloride-containing Deicer on the Thermal Charateristics and Skid Resistance of Concrete (염화물을 함유한 제설제가 콘크리트의 열 특성과 미끄럼저항성에 미치는 영향에 관한 연구)

  • Lee, Byung-Duck;Yun, Byung-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.509-512
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    • 2004
  • This research is targeting that estimate the effect on cement concrete pavement with type of chloride deicers. In order to this study objective, when chloride deicers were spread on road surface, thermal characteristics test was conducted. Also, skid resistance test according to types and concentration of chloride deicier, road surface conditions were investigated. As a test results, thermal characteristics with kind of chloride deicier could know that sodium chloride(NaCl) is exothermic reactive material, calcium chloride$(CaCl_2)$ is endothermic reactive material. And, in case of mixed salt of the calcium and sodium chloride, it could know that can change to the exothermic or endothermic reaction according to dosage ratios. Skid value by British Pendulum Tester(BPT) has shown that it is seldom difference between the types($CaCl_2$, NaCl, mixed salt) and solution concentrations(0.5, 0.8, 1.0, 4.0, $10\%$) of chloride deicier comparing with tap water except mixed salt($10\%$ solution concentration).

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Corrosion Behavior and Surface Coating of Muffler Materials by Using EB-PVD (전자빔 진공증착기를 이용한 muffler재료의 표면코팅과 내식특성)

  • 최한철
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.39-48
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    • 2001
  • Fe-Cr-Al alloy has been studied for application in automobile muffler materials due to good corrosion and oxidation resistance. In order to develop the automobile muffler materials, corrosion behaviors of electron beam physical vapor deposition (EB-PVD) coated surface of muffler matericls of muffler materials were investigated using potentiostat. For 0.1M NaCl solution, corrosion potential and pitting potential of Fe-20Cr-10Al was higher than that of Fe-5Cr- 10Al samples. Especially, in the case of Ti and Nb coated samples, pitting potential increased remarkably compared with non-coated samples. For 0.1M $CaCl_2$ solution, Ti-coated Fe-20Cr-10Al showed remarkably improved pitting corrosion resistance in comparison with non-coated Fe-20Cr-10Al and Fe-5Cr-10Al. The number and size of pits were decreased in the case of Ti coated samples in the 0.1M NaCl and 0.1M $CaCl_2$ solution.

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Studies on the Thermal Stability and Color of Free Drip released from Pork Muscle with pH, Concentration of NaCl and Phosphate (pH, NaCl 및 phosphate 첨가에 따른 돈육 드립의 열안정성 및 색에 관한 연구)

  • Kim, Cheon-Jei;Lee, Chang-Hyun;Song, Min-Seok;Lee, Eui-Soo;Cho, Jin-Kook
    • Korean Journal of Food Science and Technology
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    • v.32 no.6
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    • pp.1285-1290
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    • 2000
  • The objective of this study was to evaluate the characteristics on the thermal denaturation of free drip released from pork loin during chilled storage using DSC (differential scanning calorimetry) with pH, concentration of NaCl and phosphate. The increasing of pH stabilized the heat resistance of the proteins in drip. A $T_1$ greatly increased of $T_{max}$ by $6.33^{\circ}C$ incline from pH 5.5 to 6.5. And increasing the concentration of NaCl destabilized the heat resistance of drip. $T_1$ showed the greatest reduction of $T_{max}\;(9.41^{\circ}C)$ in the presence of 5% NaCl. The presence of STPP (Sodium Tripolyphosphate) enchanced the thermal stability of pork drip by $5.84^{\circ}C$ in the presence of 0.5% STPP. As temperature increased from 40 to $100^{\circ}C$, lightness $(L^*)$ increased from 41.1 to 69.5, while redness $(a^*)$ decreased from 26.70 to 5.40. Particularly, both values of $L^*-$ and $a^*-$ greatly changed by 78% from 40 to $60^{\circ}C$.

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