• Title/Summary/Keyword: NaCl 입자

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Preparation and Characterization of Porous Polycaprolactone Membrane for Tissue Engineering (조직공학용 다공성 Polycaprolactone 멤브레인의 제조 및 특성)

  • Kim, Jin-Tae;Kim, Tae-Hyung;Choi, Jae Ha
    • Membrane Journal
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    • v.26 no.1
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    • pp.26-31
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    • 2016
  • Polycaprolactone (PCL) has been fabricated into the membrane type scaffolds of 3 dimensional pore network for the tissue engineering applications by the blade method of salt (NaCl) leaching and solution casting. In this study, the experimental designs have each conditions of drying temperature, salt particle size, salt content. The modified dispensing pump connected up to homogenizing mixer system is used for mixing the $PCL/CHCl_3$ solution and NaCl particles. The membrane fabricated use by the film applicator to poured mixed solution on the glass plate. The great pore by NaCl particles and the small pore by the evaporated $CHCl_3$ in the frame wall of great pores are multiply formed in membrane scaffolds.

An experiment of the particle deposition on a circular cylinder in a laminar flow (원관 주위 유하 액막에 의한 관 외벽에서의 입자 부착에 대한 실험)

  • 정종수;이윤표;정기만;박찬우
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.2
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    • pp.113-119
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    • 2000
  • An experimental study has been carried out in order to investigate on a particle deposition on a circular cylinder surface. The present study is focused on the particulate fouling occurring in a heat exchanger for a seawater desalinization, in a laminar flow over circular cylindrical tubes. The objective is to investigate how NaCl concentration influences the $SiO2$ particle deposition on the surface of a glass circular cylinder. The NaCl concentration was changed from 0 g/L to 40 g/L. As the experimental results of $SiO2$ particle which is deposited on the glass circular cylinder surface showed, particle deposition rate per unit time increases rapidly with the increase of NaCl concentration between 0 g/L and 15 g/L. After the maximum of particle deposition rate was found at the NaCl concentration of 15 g/L, particle deposition rate remains unchanged or decreases gradually with the NaCl concentration from 15 g/L to 40 g/L. Also the $SiO2$ deposition rate of particles does not have serious variations with the position at present glass surface.

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An Experiment on Particle Collection Characteristics of a Duct-type Wet Scrubber (덕트형 세정집진기의 입자포집 특성실험)

  • Yoo, Kyung-Hoon;Yeo, Kuk-Hyun;Son, Seung-Woo;Hwang, Kwang-Ho;Jung, Jin-Won;Kim, Yoon-Shin
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1795-1800
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    • 2004
  • DOS and NaCl aerosol particles with geometric mean diameter of $0.1{\sim}3.0{\mu}m$ geometric standard deviation of $1.1{\sim}1.8$ and total number concentration of $450{\sim}400$ $particles/cm^3$ were used to determine collection efficiencies of a duct-type wet scrubber with respect to particle size. The tested operating variables included air velocity and water injection rate. It was shown from the experimental results that the collection efficiencies increased with increasing water injection rate and decreasing air velocity. It was also seen that the collection efficiency of the Duct-type wet scrubber is mainly governed by the mechanism of inertial impaction.

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Fractional efficiency of Nanomaterials for the High efficiency respiratory filters (고효율 호흡보호구의 나노물질 입경별 제거 효율)

  • Lee, Gwang-Jae;Ji, Jun-Ho;Kim, Won-Geun;Yook, Se-Jin;Kim, Jong-Kyo;Kim, Jung-Ho
    • Particle and aerosol research
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    • v.12 no.3
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    • pp.95-102
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    • 2016
  • Controlling exposures to occupational hazards is important for protecting workers. Certified facepiece respirators are recommended when engineering controls do not adequately prevent exposures to airborne nanomaterials. The objective of this study is to carry out the experimental performance test to investigate the fractional efficiencies of the filter media for two grades of facepiece respirators. Experimental performance evaluations were carried out for the test NaCl particles and silver nanoparticles. For media of respirator filter, the penetration of NaCl particles was less than 5% and the most penetrating particle size occurred at about 40 nm. For silver nanoparticles, the most penetrating particle size was about 20nm with higher efficiency than those of NaCl particles. Charge characteristics of airborne nanoparticles is important because the media of respirator filter is made by the electret filter media.

One-Pot Synthesis of Alkyl-Terminated Silicon Nanoparticles by Solution Reduction (표면 알킬기를 갖는 실리콘 나노입자의 One-Pot 용액환원 합성)

  • Yoon, Taegyun;Cho, Mikyung;Sun, Yang-Kook;Lee, Jung Kyoo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.577-581
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    • 2011
  • Silicon nanoparticles have attracted a great deal of scientific interests due to its intense photoluminescence in the visible spectral region and its potential applications in biological fluorescence maker, RGB (red, green, blue) display, photonics and photovoltaics etc. Practical applications making use of optical and physicochemical properties of Si nanoparticles requires an efficient synthetic method which allows easy modulation of their size, size distribution as well as surface functionalities etc. In this study, a one-pot solution reduction scheme is attempted to prepare alkyl-terminated Si nanoparticles (<10 nm) with Si precursors, (Octyl)$SiCl_3$ or mixture of (Octyl)$SiCl_3$ and $SiCl_4$, containing alkyl-groups using Na(naphthalide) as reducing agent. The surface capping of Si nanoparticles with octyl-groups as well as Si nanoparticle formation was achieved in one-pot reaction. The hexane soluble Si nanoparticles with octyl-termination were in the range of 2-10 nm by TEM and some oxide groups (Si-O-Si) was present on the surface by EDS/FTIR analyses. The optical properties of Si nanoparticles measured by UV-vis and PL evidenced that photoluminescent Si nanoparticles with alkyl-termination was successfully synthesized by solution reduction of alkyl-containing Si precursors in one-pot reaction.

The effect of osmotic pressure in W/O/W multiple emulsion (다상 에멀전 형성에 있어 삼투 현상이 미치는 영향)

  • 신중진;이근수;강기춘;표형배
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.139-148
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    • 2000
  • The osmotic pressure is a one of the most important factor affecting stabilization of multiple emulsion in a law hours after experiment. To understand and decrease osmotic pressure between Wl phase and W2 phase, a kinds of humectants were introduced in outer water phase. As a result, Betaine and Glucose had an excellent effect reducing osmotic pressure and NaCl made W/O/W emulsion more stable than MgSO4 did when introduced in inner water phase.

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Bio-mediated Flocculation by Extracellular Polymeric Substances in Cohesive Sediment Suspensions: Experimental Study (생체고분자물질이 부유사 응집에 미치는 영향 연구)

  • Baek, Seung-Ryong;Kim, Jae-In;O, Min-Ji;Lee, Byeong-Jun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.107-107
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    • 2015
  • 최근 기후변화로 인한 강우강도 증대, 산업화에 따른 토지개발 등으로 인하여 다량의 점착성 부유사(Cohesive Sediments)가 하천, 호소 등 수자원 환경으로 유입되고 있다. 점착성 부유사는 하천, 호소의 난류 조건에 따라 부유하거나 혹은 응집, 침전하여 하상 저니층을 형성한다. 부유사, 미생물 및 각종 유기입자가 포함된 하상 저니층은 검은색으로 외관상 보기 좋지 않을 뿐 아니라, 혐기성상태에서 부패하여 수생태계의 건강성을 해치게 된다. 또한 미세 부유사 및 미생물 입자는 각종 중금속, 유기오염물질을 흡착하고, 조건에 따라 재용출할 수 있는 저장매체로 작용하기 때문에 수자원환경에 미치는 영향이 아주 크다. 특히, 수중 미생물(조류) 작용에 의해 생성되는 EPS (Extracellular Polymeric Substances)는 부유사 및 미생물 입자들을 서로 엉겨 붙게 하여, 부유사-미생물 혼합 응집체 및 저니층 형성을 가속화하게 된다. 본 연구에서는 EPS가 부유사 응집에 미치는 영향을 파악하기 위하여, Xanthan Gum (Sigma-Aldrich, USA)을 EPS의 지표 물질로 사용하고, Kaolinite(Sigma-Aldrich, USA)를 수자원환경에 존재하는 대표적인 부유사로 사용하여 응집실험(Jar Test)을 수행하였다. 이온농도가 응집에 미치는 영향을 파악하기 위하여 수체 이온농도를 0.0001M NaCl, 0.001M NaCl, 0.01M NaCl, 그리고 0.001M NaCl + 0.1mg/L $Ca^{2+}$, 0.001M NaCl + 0.5mg/L $Ca^{2+}$, 0.001M NaCl + 1.0 mg/L $Ca^{2+}$으로 보정하여 응집실험을 수행하였다. 250 rpm 급속 교반 1븐, 50 rpm 완속교반 5시간, 침잔 1시간 후 응집체를 채취하여 응집체 이미지 분석을 통해 응집체 크기 및 형상을 측정하였고, 수표면 2 cm 지점에서 상등액을 채수하여 잔류 고형물 농도 분석을 실시하였다. 응집실험을 통하여 다음과 같은 결과를 도출하였다.. 낮은 이온농도의 경우, EPS가 큰 고분자 구조체에 부유 입자들이 엮어 응집되는 Sweeping Flocculation의 특징을 나타내었다. 하지만, 이온농도가 높아질수록 경우, EPS 고분자 구조체 내부 반발력이 감소하여 크기가 축소되고, 이에 따라 부유 입자 표면에 패치 형태로 흡착되었다. EPS가 패치형태로 입자에 흡착한 경우, 응집제 농도 증가에 따라 응집능 최적점이 형성되고, 이후 표면하전 역전이나 Steric Stabilization에 의해 응집능이 저감되는 형태를 나타낸다. 따라서,수중이온농도가 EPS의 사슬형 고분자 응집제의 크기, 형태(Morphology)를 결정하고, 더 나아가 응집능을 결정하는 중요한 인자로 나타났다. 따라서, 후속 연구를 통하여 생체고분자물질의 크기 및 형태 변화, 이에 따른 응집능변화를 면밀히 연구하고자 한다.

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Characterization of Heterogeneous NaCl-Na$_2$SO$_4$ Particles Using Low-Z Electron Probe X-ray Microanalysis (Low-Z Electron Probe X-ray Microanalysis를 이용한 불균일 NaCl-Na$_2$SO$_4$ 입자의 분석)

  • 구희준;안용훈;김혜경;노철언
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.394-395
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    • 2003
  • 대기 중의 황산염 입자는 인체 건강에 좋지 않은 영향을 미칠 뿐 아니라, 지구에 유입되는 빛을 산란시키고 구름을 생성하는 핵으로 작용함으로서 직ㆍ간접적으로 햇빛을 차단하여 전지구적 기후 변화에 상당한 역할을 하는 것으로 알려져 있다. 황산염 입자는 대기 중 SO$_2$의 산화에 의해 주로 생성되는데, 지금까지의 대기 모델을 활용한 연구에 의하면 대기 중의 SO$_2$의 양에 비해 황산염의 양은 과소 평가되고 있다. 이는 대기 중 황산염의 생성에 대한 대기 화학 반응기전이 제대로 파악되지 않아서 global scale의 예측이 불확실하기 때문이다. (중략)

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Removal of Red Tide Organisms -2. Flocculation of Red Tide Organisms by Using Loess- (적조생물의 구제 -2. 황토에 의한 적조생물의 응집제거-)

  • KIM Sung-Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.5
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    • pp.455-462
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    • 2000
  • The objective of this study was to examine the physicochemical characteristics of coagulation reaction between loess and red tide organisms (RTO) and its feasibility, in developing a technology for the removal of RTO bloom in coastal sea. The physicochemical characteristics of loess were examined for a particle size distribution, surface characteristics by scanning electron microscope, zeta potential, and alkalinity and pH variations in sea water. Two kinds of RTO that were used in this study, Cylindrothen closterium and Skeietonema costatum, were sampled in Masan bay and were cultured in laboratory. Coagulation experiments were conducted using various concentrations of loess, RTO, and a jar tester. The supernatant and RTO culture solution were analyzed for pH, alkalinity, RTO cell number. A negative zeta potential of loess increased with increasing pH at $10^(-3)M$ NaCl solution and had -71.3 mV at pH 9.36. Loess had a positive zeta potential of +1,8 mV at pH 1.98, which resulted in a characteristic of material having an amphoteric surface charge. In NaCl and $CaCl_2$, solutions, loess had a decreasing negative zeta potential with increasing $Na^+\;and\;Ca^(+2)$ ion concentration and then didn't result in a charge reversal due to not occurring specific adsorption for $Na^+$ ion while resulted in a charge reversal due to occurring specific adsorption for $Ca^(+2)$ ion. In sea water, loess and RTO showed the similar zeta potential values of -112,1 and -9.2 mV, respectively and sea sand powder showed the highest zeta potential value of -25.7 mV in the clays. EDLs (electrical double-layers) of loess and RTO were extremely compressed due to high concentration of salts included in sea water, As a result, there didn't almost exist EDL repulsive force between loess and RTO approaching each other and then LVDW (London-yan der Waals) attractive force was always larger than EDL repulsive force to easily form a floe. Removal rates of RTO exponentially increased with increasing a loess concentration. The removal rates steeply increased until $800 mg/l$ of loess, and reached $100{\%}$ at 6,400 mg/l of loess. Removal rates of RTO exponentially increased with increasing a G-value. This indicated that mixing (i.e., collision among particles) was very important for a coagulation reaction. Loess showed the highest RTO removal rates in the clays.

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