• Journal of the Korean Geosynthetics Society
• /
• v.12 no.1
• /
• pp.21-28
• /
• 2013

This study proposed optimum lime contents for clayey soils consisting of representative clay minerals, Kaolinite and Na-Bentonite, according to optimum lime content method (ASTM C 977-22) by means of ground improvement method of clayey soils. As geotechnical properties, the variations of atterberg limits and unconfined compressive strength were analyzed and Ca-ion and micro-structure along elapsed time were observed for lime-added clayey specimens. The test results show that optimum lime content method provides an appropriate methodology for ground improvement of clayey soils and the variation of $Ca^{2+}$ might be a good index to predict the rate of ground improvement for clayey soils with lime addition.

• Journal of the Korean GEO-environmental Society
• /
• v.12 no.2
• /
• pp.15-22
• /
• 2011

In this study, the effect of surface coating on iron-sulfide mineral for preventing the product acid mine drainage(AMD) was progressed by oxidation process of sulfide minerals abandoned mine Area. Three abandoned mines, Yongdong coal mine, Sil Lim mine, and Il Koang mine were selected as a sulfide mineral resource due to higher contamination rate. Six coating agents, apatite, limestone, mangnite, dolomite, bentonite, and cement were used for preventing the AMD with $H_2O_2$ and NaClO as a oxidizing agent helping for oxidizing process on sulfide minerals. Experimental results showed that sulfide mineral surface was coated effectively. Cement has a higher ability of preventing AMD when the ratio of cement to mineralis 1:1 and experimental condition is maintaining 4Days.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.291-291
• /
• 2006

Two different sources of clay, Na-Bentonite (Thai local clay) and Na-Montmorillonite were modified with Hexadodeccyltrimethyl ammonium bromide. The nanocomposites of polypropylene were successfully prepared via melt blending in a co-rotating twin screw extruder by using PP-g-MA as a compatibilizer at various contents of organoclays. The morphology of nanocomposites was investigated by using XRD and SEM. The results showed that the intercalated and exfoliated structures were obtained. The thermal behavior was also studied by using DSC and TGA. The degradation temperature of filled PP was greater than that of unfilled PP by 20%. And, the tensile strength and modulus were improved when a small amount of organoclays were added.

• Journal of the Korean Geotechnical Society
• /
• v.27 no.10
• /
• pp.81-92
• /
• 2011

The rheological properties of Wyoming bentonites are strongly influenced by the size of particles, cation exchangeable capacity, arrangement and morphology of clay mineral. This paper presents the results of rheological investigations on the Wyoming bentonites aqueous dispersions: two types of particle flocculation were considered. For the Wyoming bentonite, 0g/L and 30g/L NaCl equivalent salinity were added in fresh and salt water to examine the rheological behavior. This paper examined the general rheological characteristics, compatibility of rheological models and correlation between soil structure and change in rheological properties of Wyoming bentonite caused by increasing salinity. From flow curves of bentonites hydrated with fresh water and salt water, the observed general flow behavior is very close to shear thinning with yield stress (or ideal Bingham fluid with yield stress and plastic viscosity). However, the change of shear stress at the same shear rate is clear, particularly for lower shear rate. Well-known rheological models are used to fit the data. There is a good agreement between rheological model and data: Carreau, Herschel-Bulkley and power-law for S=0g/L and bilinear, Herschel-Bulkley and power-law for S=30g/L. It may be due to the fact that the internal structural bonding (strong modification of particle-particle interactions from edge-to-edge and/or edge-to-face to face-to-face) in soil matrix is affected from the evolution of rheological properties with different salinities.

• Applied Chemistry for Engineering
• /
• v.10 no.2
• /
• pp.304-309
• /
• 1999

Aluminum-pillared clay was prepared by the intercalation of Al-hydroxy oligomer into domestic bentonite. The solid products are characterized by XRD, nitrogen adsorption/desorption, EDX, and SEM. The solid products show relatively high specific surface areas in the range of $104{\sim}228m^2/g$, and their specific surface area, micropore surface area, and micropore volume increase with increasing the mole ratio of OH/Al. From the results of pore size distribution calculated by BJH equation, it was found that aluminum-pillared clay also contains much mesopore near $40{\AA}$. These results indicate that Al-hydroxy oligomer was intercalated into bentonite, and aluminum oxide was pillared among the layers of bentonite, and micropore and mesopore was finally developed into layers. As OH/Al mole ratio increases, the thermal stability of aluminum-pillared clay increases. This result can be explained by the fact that the density of layers is increased due to the formation of aluminum pillars.

• Geotechnical Engineering
• /
• v.12 no.3
• /
• pp.109-126
• /
• 1996

In this study, the chemical fluid considered is sodium chloride sloutions. The concentrations for the sodium chloride solutions are varied from 0 to 20%. A series of lab oratory triaxial tests are performed on the cylindrical specimens of sand bentonite mixture with different (5, 10, 15%) sodium chloride content solutions. Deformation(elastic modulus, E) and strength (cohesion, c', and angle of friction, f') parameters are obtained from the triaxial tests and they are expressed as functions of conf'ming pressure and sodium chloride solution concentrations. The stress-strain-strength behavior based on the above strength parameters is introduced to the finite element method with a residual flow procedure (RFP). By integrating a slope stability (limit equilibrium) procedure in the finite element method, factors of safety with time are computed.

• Journal of the Korean Geotechnical Society
• /
• v.20 no.7
• /
• pp.141-158
• /
• 2004

The dependency of criteria used to terminate compatibility tests on the prehydration and quality of bentonite in geosynthetic clay liners (GCLs) is evaluated based on permeation with chemical solutions containing 5, 10, 20, 50, and 100 mM calcium chloride ($CaCl_2$). The hydraulic conductivity tests are not terminated before chemical equilibrium between the effluent and the influent chemistry has been established, resulting in test durations ranging from < 1 day to > 900 days, with longer test durations associated with lower $CaCl_2$ concentrations. The evaluation includes both physical termination criteria (i.e., volumetric flow ratio and steady hydraulic conductivity based on ASTM D 5084, ${\ge}2$ pore volumes of flow, constant thickness of specimen) and chemical termination criteria requiring equilibrium between influent and effluent chemistry (viz., electrical conductivity, pH, and $Ca^{2+}\;and\;Cl^-$ concentrations). For specimens permeated with 5, 10, and 20 mM $CaCl_2$ solutions, only the criterion based on chemical equilibrium in $Ca^{2+}$ concentration correlates well with equilibrium in hydraulic conductivity, regardless of prehydration or quality of bentonite. However, all of the termination criteria, except for the volumetric flow ratio and 2 pore volumes of flow for the prehydrated specimens, correlate well with equilibrium in hydraulic conductivity regardless of prehydration or quality of bentonite when permeated with 50 and 100 mM $CaCl_2$ solutions. The results illustrate the uniqueness of the termination criterion based on solute concentration equilibrium between the effluent and the influent with respect to both prehydration and quality of bentonite in the GCLs.

• Journal of Soil and Groundwater Environment
• /
• v.14 no.4
• /
• pp.10-14
• /
• 2009

Objective of this study was to examine the effects of grouts and temperature change on microorganisms in geothermal heat pump. Groundwater samples were obtained from wells in the heat pump system during installation (Oriental medicine hospital) and in the heat pump system under operation (Business incubation center). Grouts are the volclay sodium bentonite. Real-time PCR was used to evaluate total bacterial number and 16S rDNA. The results showed that total bacterial number of groundwater in the heat pump operation was greater than that of non-operation case, which indicates a temperature effect on the bacterial culture. In addition, high concentration of grout showed an elevated bacteria number. In the mean time, a long-term field monitoring is essentially required to confirm the effects of the grouts and the temperature changes.

• Journal of Korea Foundry Society
• /
• v.7 no.3
• /
• pp.199-206
• /
• 1987

This paper presents experimental data for the computerization of green sand control. The results can be summarized as follows: 1. To obtain the proper compactability at the mixer, the addtion of moisture is far more efficient than the control of mixing time or addtion of clay. 2. The log R(% clay/% moisture) vs. log compactability curve moves upward as the amount of clay increases and moves downward as the amount of seacoal, dead bentonite or coked seacoal increases. 3. The ratio of dead to initial clay amount or coked to initial seacoal amount is changed according to sand to metal ratio, mainly, and according to pouring temperature, partly, at a shake out time of 12hrs.

• Journal of Radiation Protection and Research
• /
• v.15 no.2
• /
• pp.7-16
• /
• 1990

The sorption of radioactive cobalt and ruthenium on alumina, silica gel, zeolite 3A, kaolin and Na-bentonite has been studied as a function of pH. nuclide concentration and ionic strength. Retardation factor for cobalt and ruthenium on soil minerals was determined through porosity measurement. Hydrolysed species, cobalt and ruthenium interact with solid surfaces by physical adsorption processes. Freundlich sorption isotherms for cobalt and ruthenium are effectively linear. The sorption decreases with increasing ionic strength for cobalt and ruthenium. The effect of increasing porosity on the retardation factor countered the effect of a significant increase in the distribution coefficient.