• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.819-824
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• 2010

We report the laser-induced formation of peanut-shaped gold nanoparticles (Au nanopeanuts) and gold nanowires (AuNWs), and their morphological properties. Pulsed laser irradiation of citrate-capped gold nanoparticles at 532 nm induces fragmentation, spherical growth, the formation of Au nanopeanuts, and the formation of AuNWs, sequentially. High-resolution transmission electron microscopy images reveal that the Au nanopeanuts are formed by instantaneous fusion of spherical nanoparticles in random orientation by laser heating. Furthermore, Au nanopeanuts are bridged in a linear direction to form AuNWs by an amorphous accumulation of gold atoms in the junction. The laser-produced Au nanopeanuts and AuNWs slowly disintegrate, restoring the spherical shape of the original Au nanoparticles when the laser irradiation is stopped. The addition of citrate effectively prevents them from transforming back to the nanospheres.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.244.1-244.1
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• 2015

The Ag Nanowire is one of the materials that are widely studied as alternatives to ITO and is available for large area, low cost process and the flexible transparent electrode. However, Ag nanowire can have the problem of a lack of stability at high temperatures, making this impossible to form a film. Using a structure of ITO/AgNW/ITO in photodetector device, we improved the properties of the ITO in the IR region and improved the thermal stability of the AgNW. The structure of ITO/AgNW/ITO has a high transmittance value of 89% at a wavelength of 900 nm and provide a good electrical property. The AgNWs embedded ITO film has a high transmittance, this is because of the light scattering from the AgNW. The thermal stability of the developed ITO/AgNWs/ITO films were investigated and found AgNWs embedded ITO films posses considerable high stability compared to the solo AgNWs on the Si surface. The ITO/AgNWs/ITO device showed a improved photo-response ratio compared to those of the conventional TC device in IR region. This is attributed to the high transmittance and low sheet resistance. We suggest an effective design scheme for IR-sensitive photodetection by using an AgNW embedded ITO.

• 마이크로전자및패키징학회지
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• 제21권2호
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• pp.1-11
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• 2014

Flexible transparent conductive electrodes (TCEs) have recently attracted a great deal of attention owing to rapid advances in flexible electronic devices, such as flexible displays, flexible photovoltanics, and e-papers. As the performance and reliability of flexible electronics are critically affected by the quality of TCE films, it is imperative to develop TCE films with low resistivity and high transparency as well as high flexibility. Indium tin oxide (ITO) has been the most dominant transparent conducting material due to its high optical transparency and electrical conductivity. However, ITO is susceptible to cracking and delamination when it is bent or deformed. Therefore, various types of flexible TCEs, such as carbon nanotube, conducting polymers, graphene, metal mesh, Ag nanowires (NWs), and metal mesh have been extensively investigated. Among several options to replace ITO film, Ag NWs and metal mesh have been suggested as the promising candidate for flexible TCEs. In this paper, we focused on Ag NWs and metal mesh, and summarized the current development status of Ag NWs and metal mesh. The several critical issues such as high contact resistance and haze are discussed, and newly developed technologies to resolve these issues are also presented. In particular, the flexibility and durability of Ag NWs and metal mesh was compared with ITO electrode.

• 한국재료학회지
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• 제24권8호
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• pp.423-428
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• 2014

We synthesized Fe-doped $TiO_2/{\alpha}-Fe_2O_3$ core-shell nanowires(NWs) by means of a co-electrospinning method and demonstrated their magnetic properties. To investigate the structural, morphological, chemical, and magnetic properties of the samples, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy were used, as was a vibrating sample magnetometer. The morphology of the nanostructures obtained after calcination at $500^{\circ}C$ exhibited core/shell NWs consisting of $TiO_2$ in the core region and ${\alpha}-Fe_2O_3$ in the shell region. In addition, the XPS results confirmed the formation of Fe-doped $TiO_2$ by the doping effect of $Fe^{3+}$ ions into the $TiO_2$ lattice, which can affect the ferromagnetic properties in the core region. For comparison, pure ${\alpha}-Fe_2O_3$ NWs were also fabricated using an electrospinning method. With regard to the magnetic properties, the Fe-doped $TiO_2/{\alpha}-Fe_2O_3$ core-shell NWs exhibited improved saturation magnetization(Ms) of approximately ~2.96 emu/g, which is approximately 6.1 times larger than that of pure ${\alpha}-Fe_2O_3$ NWs. The performance enhancement can be explained by three main mechanisms: the doping effect of Fe ions into the $TiO_2$ lattice, the size effect of the $Fe_2O3_$ nanoparticles, and the structural effect of the core-shell nanostructures.

• 대한토목학회논문집
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• 제28권1B호
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• pp.1-9
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• 2008

소양강댐 유역의 관측유입량과 융설 모의의 포함 유무에 따른 모의 결과를 비교함으로써 적설 및 융설 모형의 필요성을 분석하였다. 사용한 융설 모형은 Sugawara 등의 개념적 융설 모형이고, 강우-유출 모형은 NWS-PC를 사용하였다. 모형의 매개변수는 다단계 자동보정법에 의해 추정하였고, 각 단계별로 SCE-UA 알고리즘에 의해 최적화되었다. 매개변수 추정시와 검증 모의에서 RMSE, PBIAS, NSE, PME 통계량은 융설을 포함한 모의가 그렇지 않은 모의보다 좋은 결과를 나타내었다. 소양강댐의 관측유입량은 약 두 달 이상의 자기상관성을 나타내었고, 융설을 포함하지 않은 경우에 모의된 유량시계열은 20일 정도의 자기상관성을 나타내었다. 융설을 포함한 경우의 모의유량 시계열은 관측 유량시계열과 유사하게 약 두 달 이상의 자기상관성을 나타내었다. 이와 같은 결과로 소양강댐 유역의 강우-유출 모의시 적설 및 융설 모형을 포함하여야 모형의 정확성을 향상시킬 수 있다.

• 한국물환경학회지
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• 제22권6호
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• pp.1088-1093
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• 2006

In this study, the method of annual sediment estimation for reservoir long-term operation is proposed. Long-term daily precipitation and evaporation are predicted by Markov Chain. Using these values, reservoir inflow is simulated by NWS-PC model. Reservoir sediment load is estimated by sediment rating relation curve which is observed. From the simulation results, it was found that each simulated value by Markov Chain and NWS-PC was well compared to the observed ones and also estimated reservoir sediment was appropriate to the compared values using empirical equations. It is thought that the proposed method for estimation of reservoir sediment can be useful used to operate the reservoir.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.25-26
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• 2009

We design and demonstrate the controlled morphologies of Ag-dpped ZnO nanowires (NWs) adopting self-contrived hot-walled pulsed laser deposition (HW-PLD). p-type Ag-doping is ensuired by low temperature photoluminescence (PL) spectrum to find the AoX peak at 3.349 eV. Morphology of grown NWs are controlled by changing the kinetic energy and flux of the ablated particles with adjusting the target - substrate (T-S) distance. The analysis on the resultant NWs is presented.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.5-6
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• 2005

ZnO nanowlres (NWs) were fabricated using Au as catalyst for a method combining laser ablation cluster formation and vapor-liquid-solid (VLS) growth. The target used in synthesis was pure ZnO ceramics. Two different substrates were used; (0001)-oriented sapphires and Au-coated sapphires. The Au thin film was deposited by thermal evaporation and the thickness was about 50 ${\AA}$. ZnO NWs were only formed in case of that used catalyst metal. Field effect scanning electron microscopic (FESEM) investigation showed that the average diameter of ZnO NWs was about 70 nm and the typical lengths varied from $3{\sim}4{\mu}m$.

• 한국생산제조학회지
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• 제21권6호
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• pp.855-859
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• 2012

Silicon nanowires (SiNWs) were fabricated by a metal-assisted chemical etching of Si and the porous structure on their surfaces was controlled by changing the volume ratio of the etching solution composed of hydrofluoric acid, hydrogen peroxide, and deionized water. The concentration of hydrogen peroxide as the oxidant was varied for controlling the porosity of SiNWs. The optical properties of porous SiNWs were unique and very different from those of single-crystalline Si, as characterized by measuring their photoluminescence and Raman spectra for different porosities.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 Techno-Fair 및 추계학술대회 논문집 전기물성,응용부문
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• pp.112-113
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• 2007

We synthesize ZnO nanowires (NWs) doped with 3 wt% Ga on sapphire substrate using a hot-walled pulsed laser deposition (PLD) system named PLD in Furnace. A proprietary target rotating system is employed in the furnace to ensure the homogeneity of the deposition. The kinetic energy of the laser-ablazed ZnO is controlled for the optimization of NW formation. The physical properties of the resultant NWs are presented.