• Journal of the Korean Society of Clothing and Textiles
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• v.45 no.1
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• pp.106-122
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• 2021

This study confirmed the mechanical properties of an auxetic re-entrant pattern prepared using 3D printing technology and its composite fabric with neoprene for the production of functional auxetic patterns/textiles for safety shoes. Samples were prepared by the tilt angle of a re-entrant pattern of 0°, 30°, 45°, 60° and 90°, and then analyzed using Poisson's ratio, bending, compression, and tensile properties. A 3D printed auxetic re-entrant pattern (3DP-RE) and its composite fabric (3DP-RE/NP) showed a negative Poisson's ratio in all tilting angles that indicated auxetic properties. The results of the bending property shown that strength of 3DP-RE/NP was 1.5 times lower than NP, but the strain improved 2.0 times. It was confirmed that the deformation of 3DP-RE/NP is possible with a low load. Each sample type of compression behavior indicated similar regardless of the tilting angles; in addition, the compression toughness of 3DP-RE/NP increased 1.2 times compared with NP. In the case of tensile properties, 3DP-RE and 3DP-RE/NP were affected by the tilting angle, samples with 90° (the opposite of load direction) showed best tensile property and toughness. 3DP-RE/NP indicated improved bending, compression, and tensile properties.

• Textile Coloration and Finishing
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• v.12 no.1
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• pp.68-75
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• 2000

In this study, polyester DTY faille(yoryu) and N/NP microfiber fabrics were pretreated (desizing, scouring and shrinking) by Continuous Scouring and Shringking Equipment with rota-drum and conveyor type in which types were different with retaining method. The results were as follows. The shrinkage ratio of wp/wf direction of DTY fabrics scoured by conveyor type was 1.5/23% higher than those by rota-drum type at $97^\circ{C}$ with 10min. treatment. In this case, The shrinkage ratio of wp/wf direction by those types was about 15/27%, respectively. The shrinkage ratio of wp/wf direction of N/NP microfiber fabrics scoured by conveyor type was 1.5/23% higher than that by rota-drum type at $97^\circ{C}$ with 10min. treatment. The size add-on of DTY fabrics scoured at $97^\circ{C}$ with 10min. treatment by conveyor type and by rota-drum type were 0.15% and 0.42%, respectively. The size add-on of DTY fabric treated by rota-drum type decreased until 9min. of treated time, but increased after 9min. The size add-on of N/NP microfiber fabrics treated by conveyor type was decreased by increasing temperature and treated time, while the size add-on of that treated by rota-drum type was decreased until 6min. treated time and increased after 6min. The size add-on of N/NP microfiber fabrics treated by conveyor type at $97^\circ{C}$ for 10min. was 0.3% lower than that by rota-drum type.

• Archives of Pharmacal Research
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• v.29 no.9
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• pp.795-799
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• 2006

Peptides, although high efficacy and specificity in their physiological function, usually have low therapeutical activities due to their poor bioavailability when administrated orally. Nanoparticles have been regarded as a useful vector for targeted drug delivery system because they can protect drug from being degraded quickly and pass the gastrointestinal barriers. Here we described a novel oral N-trimethyl chitosan nanoparticles formulation containing thymopentin (Tp5-TMC-NP). N-trimethyl chitosan (TMC) was synthesized and then used to prepare Tp5-TMC-NP by ionotropic gelation. A three-factor, five-level CCD (Central Composite Design) design was used in the optimization procedure, with HPLC as the analyzing method. The resulting Tp5-TMC-NP had a regular spherical surface and a narrow particle size range with a mean diameter of 110.6 nm. The average entrapment efficiency was 78.8%. The lyophilized Tp5-TMC-NP formulation was stable in $4^{\circ}C\;or\;-20^{\circ}C$ after storage of 3 months without obvious changes in morphology, particle size, pH and entrapment ratio. The results of the flow cytometer determination showed that the ratio of $CD4^+/CD8^+$ of Wistar female rat given Tp5-TMC-NP (ig) was 2.59 time that of the group given Tp5 (ig).

• Animal cells and systems
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• v.14 no.3
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• pp.161-167
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• 2010

This study investigated the estrogenicity of 4-nonylphenol (NP) and diethylstilbestrol (DES) in vitro during oocyte maturation in the marine fish, Tridentiger obscurus, using steroid hormone assays and GVBD assay. Vitellogenic (0.53mm diameter) and fully vitellogenic (0.75mm diameter) oocytes were in vitro exposed to NP (0.045 453.82 nM and DES (0.037 372.62 nM). In vitellogenic oocytes, 45.38 and 453.82nM NP and 3.73 372.62nM DES increas the estradiol-$17{\beta}$ (E2)/testosterone (T) ratio. In fully vitellogenic oocytes, 0.45, 45.38 and 453.82nM NP and 3.73nM DES increased E2/T. In the GVBD assay, 0.45 and 4.54nM NP and 0.037, 3.73 and 37.26nM DES inhibited GVBD. These results suggest that NP and DES have estrogen-agonistic effects in oocyte maturation in T. obscurus. In addition, NP and DES have different sensitivity according to the oocyte developmental stage, and the estrogenagonistic effects of DES were greater than were those of NP.

• Clean Technology
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• v.27 no.3
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• pp.223-231
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• 2021

In order to address many issues associated with large volume changes of silicon, which has very low electrical conductivity but offers about 10 times higher theoretical capacity than graphite (Gr), a silicon nanoparticles/hollow carbon (SiNP/HC) composite having bimodal-mesopores was prepared using silica nanoparticles as a template. A control SiNP/C composite without a hollow structure was also prepared for comparison. The physico-chemical and electrochemical properties of SiNP/HC were analyzed by X-ray diffractometry, X-ray photoelectron spectroscopy, nitrogen adsorption/desorption measurements for surface area and pore size distribution, scanning electron microscopy, transmission electron microscopy, galvanostatic cycling, and cyclic voltammetry tests to compare them with those of the SiNP/C composite. The SiNP/HC composite showed significantly better cycle life and efficiency than the SiNP/C, with minimal increase in electrode thickness after long cycles. A hybrid composite, SiNP/HC@Gr, prepared by physical mixing of the SiNP/HC and Gr at a 50:50 weight ratio, exhibited even better cycle life and efficiency than the SiNP/HC at low capacity. Thus, silicon/carbon composites designed to have hollow spaces capable of accommodating volume expansion were found to be highly effective for long cycle life of silicon-based composites. However, further study is required to improve the low initial coulombic efficiency of SiNP/HC and SiNP/HC@Gr, which is possibly because of their high surface area causing excessive electrolyte decomposition for the formation of solid-electrolyte-interface layers.

• Carbon letters
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• v.26
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• pp.81-87
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• 2018

Morphological differences in multi-layered graphene flakes or graphene nanoplatelets prepared by oxidative (rGO-NP, reduced graphene oxide-nanoplatelets) and non-oxidative (GIC-NP, graphite intercalation compound-nanoplatelets) routes were investigated with various analytical methods. Both types of NPs have similar specific surface areas but very different structural differences. Therefore, this study proposes an effective and simple method to identify structural differences in graphene-like allotropes. The adsorptive potential peaks of rGO-NP attained by the density functional theory method were found to be more scattered over the basal and non-basal regions than those of GIC-NP. Raman spectra and high resolution TEM images showed more distinctive crystallographic defects in the rGO-NP than in the GIC-NP. Because the R-ratio values of the edge and basal plane of the sample were maintained and relatively similar in the rGO-NP (0.944 for edge & 1.026 for basal), the discrepancy between those values in the GIC-NP were found to be much greater (0.918 for edge & 0.164 for basal). The electrical conductivity results showed a remarkable gap between the rGO-NP and GIC-NP attributed to their inherent morphological and crystallographic properties.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.40 no.1
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• pp.16-23
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• 2007

Nonylphenol (NP) is an estrogen-mimicking compound or xenoestrogen. This study investigated the effects of nonylphenol on the reproductive status of the equilateral venus Gomphina veneriformis. The experiment lasted 24 weeks, Experimental groups consisted of a control and three nonylphenol exposures ($1.0,\;2.5,\;and\;5.0\;{\mu}g\;NP/L$). Mortality did not differ significantly between the control and the exposure groups. The sex ratio (F:M) was 1:1 in nature and 1:1.03 in the control group. However, it changed to 1:3.5 with $5.0\;{\mu}g\;NP/L$ exposure. Gonad maturity in females was higher in the nonylphenol exposure groups than in the control group. By contrast, in males, it was lower in the nonylphenol exposure groups. Intersex individuals constituted 0% in nature, 3.08% in the control group, and 23.6% in the group exposed to nonylphenol, with female characteristics more prevalent than male. As the concentration of nonylphenol increased, the accumulation of lipofuscin increased in the mid-gut gland.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.7
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• pp.1549-1555
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• 2009

The Relay node placement problem is one of the most important requirements for many wireless sensor networks because the lifetime of sensor networks is closely related with the placement of relay nodes which receive sensed data from sensor nodes and forward them to the base station. Relay node placement problem has focused at minimization of dissipated total energy of the sensor nodes in whole networks. However, minimum total energy causes the unbalance of consumed energy in sensor nodes due to different distances between relay nodes and sensor nodes. This paper proposes the concept of energy balance ratio and finds the locations of relay nodes using objective functions which maximize the energy balance ratio. Maximizing this ratio results in maximizing the network lifetime by minimizing the energy consumption of large-scale sensor networks. However, finding a solution to relay node placement problem is NP-hard and it is very difficult to get exact solutions. Therefore, we get approximate solutions to EBR-RNP problem which considers both energy balance ratio and relay node placement using constraint programming.

• The Journal of Internal Korean Medicine
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• v.28 no.3
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• pp.586-596
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• 2007

Objectives : This study aimed to investigate the underlying protective mechanism of Rhizoma Arisaematis(RA) on 3-NP-induced Cytotoxicity in rat C6 glial cells. Methods : We investigated treatment ofC6 cells with 20mM 3-NP and pretreatment with RA to cause loss of cell viability. and morphological change. which was associated with elevation of ROS level. increase in Bax/Bcl2 ratio and HIF-a protein expression Results : RA inhibited 3-NP-induced cell death in C6 glial cells and inhibited the changes of the : MMPT (mitochondria membrane potential transition) and inhibited the decrease of mitochondria complex II activity and 3-NP-induced ROS generation in C6 cells. And RA decreased the activity of HIF-a and Bax. and increased the activity of $Bcl_2$ in C6 glial cells Conclusions : RA markedly protects C6 glial cells from 3-NP-induced oxidative injury.

• Analytical Science and Technology
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• v.17 no.5
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• pp.423-433
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• 2004

This study was examined occurrence of bisphenol A (BPA) and nonylphenol (NP) in waterworks system of Seoul, Korea from September 2002 to December 2003. The levels of BPA and NP in Han-river and its tributaries were as followed: Paldang-dam, ND(not detected)${\sim}0.033{\mu}g/L$ and $ND{\sim}0.823{\mu}g/L$; Kyungahn-creek, $ND{\sim}0.659{\mu}g/L$ and $ND{\sim}3.827{\mu}g/L$; Whangsuk-creek, $ND{\sim}0.528{\mu}g/L$ and $ND{\sim}12.724{\mu}g/L$, respectively. In water of 6 intake-station, the contents of NP and BPA were detected $0.122{\sim}2.724{\mu}g/L$, and $ND{\sim}0.260{\mu}g/L$, respectively. In the finished- and tap-water of three drinking water treatment plants (DWTPs) around Whangsuk-creek, BPA was not detected in all samples, while NP was in ppt levels in whole. Through the process of DWTP, also, the removal ratio of NP was above 80% in all this. Therefore, this result was suggested that levels of BPA and NP in waterworks system depended on non-point contaminants and swage treatment plants in the Han-river shed.